Sorption Behaviors of Cotton, Kapok, and Rayon Fibers in Heavy Metal Solutions

면, 케폭, 레이온 섬유의 중금속 흡탈착 거동

  • Received : 2011.08.26
  • Accepted : 2011.12.10
  • Published : 2011.12.31

Abstract

In the study, the sorption behaviors of three different cellulose fibers were investigated using heavy metal solutions(Pb(II) and Cd(II)). The sorption dose during the adsorption and desorption was measured using an inductively coupled plasma spectrometer. The initial sorption by cotton was greater than that of the other fibers, while the total adsorption dose of rayon was larger than that of the others. The desorption dose of heavy metal ions from the fiber was negligibly small, indicating that the ions are very strongly physic-ochemically attached to the fiber.

Keywords

Acknowledgement

Supported by : Ministry of Health & Welfare

References

  1. J. Y. K. Twu and S. L. Wang, "Preparation and Sorption Activity of Chitosan/Cellulose Blend Beads", Carbohydr Polym, 2003, 54, 425-430. https://doi.org/10.1016/j.carbpol.2003.03.001
  2. W. S. W. Ngaha and M. A. K. M. Hanafiah, "Adsorption of Dyes and Heavy Metal Ions by Chitosan Composites: A Review", Carbohydr Polym, 2011, 83, 1446-1456. https://doi.org/10.1016/j.carbpol.2010.11.004
  3. D. Zhou and S. Guo, "Cellulose/chitin Beads for Adsorption of Heavy Metals in Aqueous Solution", Water Res, 2004, 38, 2643-2650. https://doi.org/10.1016/j.watres.2004.03.026
  4. C. S. Ki and Y. H. Park, "Nanofibrous Membrane of Wool Keratose/Silk Fibroin Blend for Heavy Metal Ion Adsorption", J Memb Sci, 2007, 302, 20-26. https://doi.org/10.1016/j.memsci.2007.06.003
  5. A. K. Meena, "Removal of Heavy Metal Ions from Aqueous Solutions Using Carbon Aerogel as an Adsorbent", J Hazard Mater, 2005, 122, 161-170. https://doi.org/10.1016/j.jhazmat.2005.03.024
  6. C. O. Ijagbemi, "Montmorillonite Surface Properties and Sorption Characteristics for Heavy Metal Removal from Aqueous Solutions", J Hazard Mater, 2009, 166, 538-546. https://doi.org/10.1016/j.jhazmat.2008.11.085
  7. L. Svecova and E. Guibal, "Cadmium, Lead and Mercury Biosorption on Waste Fungal Biomass Issued from Fermentation Industry. I. Equilibrium Studies", Sep Purif Technol, 2006, 52, 142-153. https://doi.org/10.1016/j.seppur.2006.03.024
  8. S. Ridvan and M. Yakup Arica, "Biosorption of Cadmium (II), Lead(II) and Copper(II) with the Filamentous Fungus Phanerochaete Chrysosporium", Bioresour Technol, 2011, 76, 67-70.
  9. A. Sari and M. Tuzen, "Biosorption of Pb(II) and Cd(II) from Aqueous Solution Using Green Alga (Ulva lactuca) Biomass", J Hazard Mater, 2008, 152, 302-308. https://doi.org/10.1016/j.jhazmat.2007.06.097
  10. A. Seker and M. C. Dalay, "Equilibrium, Thermodynamic and Kinetic Studies for the Biosorption of Aqueous Lead(II), Cadmium(II) and Nickel(II) Ions on Spirulina Platensis", J Hazard Mater, 2008, 154, 973-980. https://doi.org/10.1016/j.jhazmat.2007.11.007
  11. V. K. Gupta and A. Rastogi, "Biosorption of Lead from Aqueous Solutions by Green Algae Spirogyra Species: Kinetics and Equilibrium Studies", J Hazard Mater, 2008, 152, 407-414. https://doi.org/10.1016/j.jhazmat.2007.07.028
  12. M. Sassi, "Removal of Heavy Metal Ions from Aqueous Solutions by a Local Dairy Sludge as a Biosorbant", Desalination, 262, 243-250.
  13. C. Jeon and K.Y. Hwang, "Adsorption of Heavy Metals Using Magnetically Modified Alginic Acid", Hydrometallurgy, 2007, 86, 140-146. https://doi.org/10.1016/j.hydromet.2006.11.010
  14. C. Septhum and V. Rattanaphani, "An Adsorption Study of Al(III) Ions onto Chitosan", J Hazard Mater, 2007, 72, 88- 96.
  15. H. Du Ozsoy and H. Kumbur, "Adsorption of Cu(II) Ions on Cotton Boll", J Hazard Mater, 2006, 136, 911-916. https://doi.org/10.1016/j.jhazmat.2006.01.035
  16. S. R. Shukla and R. S. Pai, "Adsorption of Cu(II), Ni(II) and Zn(II) on Modified Jute Fibres", Bioresour Technol, 2005, 96, 1430-1438. https://doi.org/10.1016/j.biortech.2004.12.010
  17. L. V. A. Gurgel and L. F. Gil, "Adsorption of Cu(II), Cd(II), and Pb(II) from Aqueous Single Metal Solutions by Cellulose and Mercerized Cellulose Chemically Modified with Succinic Anhydride", Bioresour Technol, 2008, 99, 3077- 3083. https://doi.org/10.1016/j.biortech.2007.05.072
  18. L. V. A. Gurgel and L. F. Gil, "Adsorption of Cu(II), Cd(II), and Pb(II) from Aqueous Single Metal Solutions by Succinylated Mercerized Cellulose Modified with Triethylene- Tetramine", Carbohydr Polym, 2009, 77, 922-929.
  19. M. J. Zohuriaan-Mehr, A. Pourjavadi, M. Salehi-Rad, "Modified CMC. 2. Novel Carboxymethylcellulose-based Poly (amidoxime) Chelating Resin with High Metal Sorption Capacity", React Funct Polym, 2004, 61 23-31. https://doi.org/10.1016/j.reactfunctpolym.2004.03.006
  20. H. Yan and R. Cheng "Sorption of Methylene Blue by Car- Boxymethyl Cellulose and Reuse Process in a Secondary Sorption", Colloids Surf A Physicochem Eng Asp, 2011, 380, 143-151. https://doi.org/10.1016/j.colsurfa.2011.02.045
  21. F. Christa and B. Thomas, "Sorption of Alkaline Earth Metal Ions $Ca^{2+}$ and $Mg^{2+}$+ on Lyocell Fibres", Carbohydr Polym, 2009, 76, 123-128. https://doi.org/10.1016/j.carbpol.2008.10.010
  22. S. Chen and H. Wang, "Carboxymethylated-bacterial Cellulose for Copper and Lead Ion Removal", J Hazard Mater, 2009, 161, 1355-1359. https://doi.org/10.1016/j.jhazmat.2008.04.098
  23. W. Shen and H. Wang, "Adsorption of Cu(II) and Pb(II) onto Diethylenetriamine-bacterial Cellulose", Carbohydr Polym, 2009, 75, 110-114. https://doi.org/10.1016/j.carbpol.2008.07.006
  24. Y. Z. Wan and X. L. Li, "Mechanical, Moisture Absorption, and Biodegradation Behaviours of Bacterial Cellulose Fibrereinforced Starch Biocomposites", Compos Sci Technol, 2009, 69, 1212-1217. https://doi.org/10.1016/j.compscitech.2009.02.024
  25. E. Lord, "Airflow through Plugs of Textile Fibres. Part 1 - General Flow Relations", J Text Inst, 1955, 46, 191-213. https://doi.org/10.1080/19447027.1955.10750307
  26. K. Hasiao and C. Lu, "Analysis of Physical Properties of PET/CD-PET Polyblend Hollow Fiber and Its Kinetics of Alkaline Hydrolysis", J Appl Polym Sci, 2002, 86, 3601- 3610. https://doi.org/10.1002/app.11226
  27. A. D. Khasbaatar and U. S. Choi, "Adsorption and Equi- Librium Adsorption Modeling of Bivalent Metal Cations on Viscose Rayon Succinate at Different pHs", React Funct Polym, 2007, 67, 312-321. https://doi.org/10.1016/j.reactfunctpolym.2007.01.003