Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
권호 표지
DOI QR코드

DOI QR Code

Synthesis of Sr3Al2O6 Phosphors by Solid State Reaction and Its Luminescent Properties

고상법에 의한 Sr3Al2O6 형광체의 분말합성 및 발광특성

  • Kim, Sue-Jin (Department of Materials Science and Engineering, Chungnam National University) ;
  • Won, Hyung-Il (Rapidly Solidified Materials Research Center(RASOM)) ;
  • Won, Chang-Whan (Department of Materials Science and Engineering, Chungnam National University) ;
  • Nersisyan, Hayk (Rapidly Solidified Materials Research Center(RASOM))
  • 김수진 (충남대학교 신소재공학과) ;
  • 원형일 (급속응고신소재연구소) ;
  • 원창환 (충남대학교 신소재공학과) ;
  • Received : 2011.02.11
  • Accepted : 2011.05.11
  • Published : 2011.05.31
Download PDF
⟨ Previous Next ⟩

Abstract

A red strontium aluminate phosphor ($Sr_3Al_2O_6:Eu^{3+},Eu^{2+}$) is synthesized using a solid state reaction method in air and reducing atmosphere. The investigation of firing temperature indicates that a single phase of $Sr_3Al_2O_6$ is formed when the firing temperature is higher than $1300^{\circ}C$. The effect of firing temperature and doping concentration on luminescent properties are investigated. $Sr_3Al_2O_6$ phosphor exhibits the typical red luminescent properties of $Eu^{3+}$ and $Eu^{2+}$.

Keywords

References

  1. T. Mukai, M. Yamada, and S. Nakamura, “Current and Temperature Dependence of Electroluminescence of InGaNbased UV/Blue/Green Light-emitting Diodes,” Jpn. J. Appl. Phys., 37 [11B] L1358-61 (1995).
  2. S. Nakamura, M. Senob, N. lwasa, and S. Nagahama, “High-power InGaN Single-quantum-well-structure Blue and Violet Light-Emitting Diodes,” Appl. Phys. Lett., 67 [13] 1868-70 (1995). https://doi.org/10.1063/1.114359
  3. S. Nakamura, “The Role of Structural Imperfections in InGaN-based Blue Light-emitting Diodes and Laser Diodes,” Science, 281 956-61 (1998). https://doi.org/10.1126/science.281.5379.956
  4. P. Schlotter, R. Schmidt, and J. Schneider, “Luminescence Conversion of Blue Light Emitting Diodes,” Appl. Phys., A. 64 [4] 417-18 (1997). https://doi.org/10.1007/s003390050498
  5. Y.D. Huh, Y.S. Cho, and Y. R. Do, “The Optical Properties of $(Y_{1-x}Gd_x)_{3-z}(Al_{1-y}Ga_y)_5O_{12}:Ce_z$ Phosphors for White LED,” Bull. Kor. Chem. Soc., 23 [10] 1435-38 (2002). https://doi.org/10.5012/bkcs.2002.23.10.1435
  6. Y. Hu, W. Zhuang, H. Ye, S. Zhang, Y. Fanga, and X. Huanga, “Preparation and Luminescent Properties of $(Ca_{1-x},Sr_x)S:Eu^{2+}$ Red-emitting Phosphor for White LED,” J. Lumin., 111 [3] 139-45 (2005). https://doi.org/10.1016/j.jlumin.2004.07.005
  7. C. Guo, D. Hunag, and Q. Sum, “Methods to Improve the Fluorescence Intensity of CaS:$Eu^{2+}$ Red-emitting Phosphor for White LED,” Mater. Sci. & Eng. B., 130 [1-3] 189-93 (2006). https://doi.org/10.1016/j.mseb.2006.03.008
  8. K. S’\'wiatk K. Karpin’ska, M. Godlewski, L. Niinisto, and M. Leskela, “Influence of Eu Concentration on Recombination Processes in CaS: $Eu^{2+}$ Thin Films,” J. Lumin., 60-61 923-25 (1994). https://doi.org/10.1016/0022-2313(94)90313-1
  9. N. Yamashita, O. Harada, and K, Nakamura, “Photoluminescence Spectra of $Eu^{2+}$ Centers in Ca(S,Se):Eu and Sr(S,Se):Eu,” Jpn. J. Appl. Phys., 34 5539-45 (1995). https://doi.org/10.1143/JJAP.34.5539
  10. D. Ravichandran, S.T. Johnson, S. Erdei, R. Roy, and W. B. White, “Crystal Chemistry and Luminescence of the $Eu^{2+}$ Activated Alkaline Earth Aluminate Phosphor,” Display., 19 [7] 197-203 (1999). https://doi.org/10.1016/S0141-9382(98)00050-X
  11. G. Blasse and B. C. Grabmaier, “Luminescent Materials,” pp. 33-70, Springer-Verlag, Berlin, 1994.
  12. T. Katsumata, K. Sasajima, T. Nabae, S. Kumuro, and T. Morikawa, “Characteristics of Strontium Aluminate Crystals Used for Long-duration Phosphors,” J. Am. Ceram. Soc., 81 [2] 413-16 (1996).
  13. Y. Pan, H. sung, H. Wu, J. Wang, X. Yang, M. Wu, and Q. Su, “Variable Geometry Effects on the Scramjet Ignition and Combustion,” Mater. Res. Bull., 27 [3] 225-29 (2006).
  14. Y. Liu and C. N. Xu, “Influence of Calcining Temperature on Photoluminescence and Triboluminescence of Europiumdoped Strontium Aluminate Particles Prepared by Sol-Gel Process,” J. Phys. Chem., B 107 [17] 3991-95 (2003).
  15. M. Akiyama, C. N. Xu, K. Nonaka, and T. Watanabe, “Intense Visible Light Emission from $Sr_3Al_2O_6$: Eu,Dy,” Apply. Phys. Lett., 73 [21] 3046-48 (1998). https://doi.org/10.1063/1.122667
  16. P. Zhang, L. X. Li, M. X. Xu, and L. Liu, “The New Red Luminescent $Sr_3Al_2O_6:Eu^{2+}$ Phosphor Powders Synthesized via Sol- Gel Route by Microwave-assisted,” J. Alloy Compd., 456 [1-2] 216-19 (2008). https://doi.org/10.1016/j.jallcom.2007.02.004
  17. P. Zhang, M. X. Xu, Z. T. Zheng, B. Sun, and Y. H. Zhang, “Rapid Formation of Red Long Afterglow Phosphor $Sr_3Al_2O_6:Eu^{2+},\;Dy^{3+}$ by Microwave Irradiation,” Mater. Sci. Eng. B., 136 [2-3] 159-64 (2007). https://doi.org/10.1016/j.mseb.2006.09.018
  18. G. Liu, J. H. Liang, Z. H. Deng, and Y. D. Li, “Synthesis and Photoluminescence Research of Novel Red-fluorescent $Sr_3Al_2O_6$ Powders,” Chin. J. Inorg. Chem., 18 [11] 1135-37 (2002).
  19. X. Ye, W. Zhuang, J. Wang, W. Yuan, and Z. Qiao, “Thermodynamic Description of $SrO-Al_2O_3$ System and Comparison with Similar Systems,” J. Phase Equilib Diff., 28 [4] 362-68 (2007). https://doi.org/10.1007/s11669-007-9086-x
  20. R. Y. Wang, “Distribution of $Eu^{3+}$ Ion in $LaPO_4$Nanocrystals,” J. Lumin., 106 [3-4] 211-17 (2004). https://doi.org/10.1016/j.jlumin.2003.10.001
  21. S. Shionoya and W. Yen, “Phosphor Handbook,” pp. 190,CRC Press, New York, 1999.
  22. R. Jagannathan, T.R.N. Kutty, M. Kottaisamy, and P. Jeyagopal, “Defects Induced Enhancement of $Eu^{3+}$ Emission in Yttria($Y_2O_3:Eu^{3+}$),” Jpn. J. Appl. Phys., 33 [11] 6207-12 (1994). https://doi.org/10.1143/JJAP.33.6207
  23. D. R. Vij, “Luminescence of Solids,” p. 122, Pleum Press, New York, 1998.
  24. S.H. Poort, W.P. Blokpoel, and G. Blasse, “Luminescence of $Eu^{2+}$ in Barium and Strontium Aluminate and Gallate,” Chem. Mater., 7 [8] 1547-51 (1995). https://doi.org/10.1021/cm00056a022

Cited by

  1. Ions vol.51, pp.1, 2014, https://doi.org/10.4191/kcers.2014.51.1.037