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열중량분석기에서 석탄과 산소공여입자의 반응 특성

Reaction Characteristics of Coal and Oxygen Carrier Particle in a Thermogravimetric Analyzer

  • 투고 : 2011.02.15
  • 심사 : 2011.04.22
  • 발행 : 2011.04.30

초록

To check adaptability of low ash coal(hyper coal) to chemical looping combustion, reaction characteristics of two coals (Roto and Hyper coal) with two oxygen carriers (NiO/bentonite, OCN703-1100) have been investigated in a thermogravimetric analyzer. Hyper coal represented low combustion rate and high ignition temperature, high volatile content and high devolatilization rate, and therefore, showed worse oxygen transfer during successive 10 cycle reduction-oxidation test than Roto coal. Finally we selected Roto coal as the candidate coal for chemical looping combustion. For Roto coal, OCN703-1100 particle showed better oxygen transfer than NiO/bentonite particle. During 10 cycle reduction oxidation test, change of the extent of oxidation (Wo) was negligible and we could conclude that both oxygen carriers have sufficient regeneration ability.

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참고문헌

  1. H. J. Ryu, "$CO_{2}-NO_{x}$ free chemical-looping combustion technology", KOSEN report, http://www.kosen21.org, 2003.
  2. H. J. Ryu, K. S. Kim, Y. S. Park, and M. H. Park, "Reduction Characteristics of Oxygen Carrier Particle for Chemical-looping Combustor with Different Fuels", Trans. of the Korean Hydrogen and New Energy Society, Vol. 20, No. 1, 2009, pp. 45-54.
  3. H. J. Ryu, Y. C. Park, S. Y. Lee, and H. K. Kim, "Development of Solid Separator for Selective Solid Circulation in Two-interconnected Fluidized Beds System", Korean Chem. Eng. Res., Vol. 47, No. 2, 2009, pp. 195-202.
  4. H. J. Ryu, and G. T. Jin, "Reactivity and Attrition Resistance of Three Oxygen Carrier Particles for Chemical-Looping Combustor", Trans. of the Korean Hydrogen and New Energy Society, Vol. 15, No. 3, 2004, pp. 208-219.
  5. H. J. Ryu, K. S. Kim, Y. S. Park, and M. H. Park, "Natural Gas Combustion Characteristics of Mass Produced Oxygen Carrier Particles for Chemical-Looping Combustor in a Batch Type Fluidized Bed Reactor", Trans. of the Korean Hydrogen and New Energy Society, Vol. 20, No. 2, 2009, pp. 151-160.
  6. H. J. Ryu, S. Y. Lee, H. K. Kim, and M. H. Park, "Effect of $CO_{2}$ concentration on Reduction Reactivity of Oxygen Carriers for Chemicallooping Combustor", Trans. of the Korean Hydrogen and New Energy Society, Vol. 20, No. 3, 2009, pp. 245-255.
  7. A. Lyngfelt, "Oxygen Carriers For Chemical- Looping Combuction-Operational Experience", 1st International Conference on Chemical Looping, March 17-19, IFP-Lyon, France, Available on CD, 2010.
  8. L. S. Fan, "Chemical Looping Processes", 1st International Conference on Chemical Looping, March 17-19, IFP-Lyon, France, Available on CD, 2010.
  9. J. Adanez, "Oxygen Carrier Materials for Chemicallooping Processes-Fundamentals", 1st International Conference on Chemical Looping, March 17-19, IFP-Lyon, France, Available on CD, 2010.
  10. H. J. Ryu, G. T. Jin, D. H. Bae, and H. K. Kim, "Effects of Operating Variables on Solid Separation Rate in Two-interconnected Fluidized Beds System for Selective Solid Circulation", Korean Chem. Eng. Res., Vol. 47, No. 3, 2009, pp. 355-361.
  11. S. D. Kim, K. J. Woo, S. K. Jeong, Y. J. Rhim, and S. H. Lee, "Production of Low Ash Coal by Thermal Extraction with N-methyl-2-pyrrolidinone", Korean J. Chem. Eng., Vol. 25, No. 4, 2008, pp. 758-763. https://doi.org/10.1007/s11814-008-0124-0
  12. S. D. Kim and S. H. Lee, "Technology for the Preparation of Ash-free Coal from Low Rank Coal(LRC)", Korean Chem. Eng. Res., Vol. 46, No. 3, 2008, pp. 443-450.