DOI QR코드

DOI QR Code

THE FAST PYROLYSIS CHARACTERISTICS OF LIGNOCELLULOSIC BIOMASS IN A BUBBLING FLUIDIZED BED REACTOR

기포 유동층 반응기내 목질계 바이오매스의 급속열분해 특성

  • 최항석 (한국기계연구원, 그린환경기계연구본부)
  • Received : 2011.04.18
  • Accepted : 2011.05.17
  • Published : 2011.06.30

Abstract

The fast pyrolysis characteristics of lignocellulosic biomass are investigated for a bubbling fluidized bed reactor by means of computational fluid dynamics (CFD). To simulate multiphase reacting flows for gases and solids, an Eulerian-Eulerian approach is applied. Attention is paid for the primary and secondary reactions affected by gas-solid flow field. From the result, it is scrutinized that fast pyrolysis reaction is promoted by chaotic bubbling motion of the multiphase flow enhancing the mixing of solid particles. In particular, vortical flow motions around gas bubbles play an important role for solid mixing and consequent fast pyrolysis reaction. Discussion is made for the time-averaged pyrolysis reaction rates together with time-averaged flow quantities which show peculiar characteristics according to local transverse location in a bubbling fluidized bed reactor.

Keywords

References

  1. 1991, Kunii, D. and Levenspiel, O., Fluidization Engineering, Butterworth-Heinemann, Newton.
  2. 2009, Wu, C. et al., "Operation characteristics of a 1.2-MW biomass gasification and power generation plant," Biotechnology Advances, Vol.27, pp.588-592. https://doi.org/10.1016/j.biotechadv.2009.04.020
  3. 2009, Dahl, O. et al., "Comparison of the characteristics of bottom ash and fly ash from a medium-size (32 MW) municipal district heating plant incinerating forest residues and peat in a fluidized-bed boiler," Fuel Processing Technology, Vol.90, pp.871-878. https://doi.org/10.1016/j.fuproc.2009.04.013
  4. 1999, Meier, D. and faix. O., "State of the art of applied fast pyrolysis of lignocellulosic materials-a review," Bioresource Technology, Vol.68, pp.71-77. https://doi.org/10.1016/S0960-8524(98)00086-8
  5. 2006, Brammer, J.G. et al., "Opportunities for biomass-derived "bio-oil" in European heat and power markets," Energy Policy, Vol.34, pp.2871-2880. https://doi.org/10.1016/j.enpol.2005.05.005
  6. 2008, Park, H. et al., "Influence of reaction conditions and the char separation system on the production of bio-oil from radiate pine sawdust by fast pyrolysis," Fuel Processing Technology, Vol.89, pp.797-802. https://doi.org/10.1016/j.fuproc.2008.01.003
  7. 2008, Velden, M. et al., "Modeling CFB biomass pyrolysis reactors,"Biomass and Bioenergy, Vol.32, pp.128-139. https://doi.org/10.1016/j.biombioe.2007.08.001
  8. 2001, Wachem, B.G.M. et al., "Comparative analysis of CFD models of dense gas-solid systems," AIChE Journal, Vol.47, pp.1035-1051. https://doi.org/10.1002/aic.690470510
  9. 1988, Syamlal, M. and O'Brien, T.J., "Simulation of granular layer inversion in liquid fluidized beds," Int. J. Multiphase Flow, Vol.14, pp.473-481. https://doi.org/10.1016/0301-9322(88)90023-7
  10. 1993, Syamlal, M. et al., "MFIX documentation theory guide," Technical Note, DOE/METC-94/1004, NTIS/DE94000087, U.S. Department of Energy, Office of Fossil Energy, Morgantown Energy Technology Center Morgantown, WV, National Technical Information Service, Springfield, VA.
  11. 2005, Hulme, I. et al., "CFD modeling and validation of bubble properties for a bubbling fluidized bed," Ind. Eng. Chem. Res., Vol.44, pp.4254-4266. https://doi.org/10.1021/ie049837j
  12. 1985, Chan, W.R. et al., "Modeling and experimental verification of pyrolysis and chemical processes during pyrolysis of large biomass particle," Fuel, Vol.64, pp.1505-1513. https://doi.org/10.1016/0016-2361(85)90364-3
  13. 1996, Blasi, C.B., "Heat, momentum and mass transport through a shrinking biomass particle exposed to thermal radiation," Chemical Engineering Science, Vol.51, pp.1121-1132. https://doi.org/10.1016/S0009-2509(96)80011-X
  14. 2010, 최항석, "바이오매스 급속열분해 반응기내 열전달 특성," 한국전산유체공학회지, Vol.15, pp.9-16.