Transactions on Electrical and Electronic Materials

  • 제12권2호
  • /
  • Pages.64-67
  • /
  • 2011
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  • 1229-7607(pISSN)
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  • 2092-7592(eISSN)
한국전기전자재료학회 (The Korean Institute of Electrical and Electronic Material Engineers)
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Effect of Ta-Substitution on the Ferroelectric and Piezoelectric Properties of Bi0.5/(Na0.82K0.18)0.5TiO3 Ceramics

  • Do, Nam-Binh (School of Materials Science and Engineering, University of Ulsan) ;
  • Lee, Han-Bok (School of Materials Science and Engineering, University of Ulsan) ;
  • Yoon, Chang-Ho (School of Materials Science and Engineering, University of Ulsan) ;
  • Kang, Jin-Kyu (School of Materials Science and Engineering, University of Ulsan) ;
  • Lee, Jae-Shin (School of Materials Science and Engineering, University of Ulsan) ;
  • Kim, Ill-Won (Department of Physics, University of Ulsan)
  • 투고 : 2011.01.24
  • 심사 : 2011.03.16
  • 발행 : 2011.04.25
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초록

The effect of Ta substitution on the crystal structure, ferroelectric, and piezoelectric properties of $Bi_{0.5}(Na_{0.82}K_{0.18})_{0.5}Ti_{1-x}Ta_xO_3$ ceramics has been investigated. The Ta doping resulted in a transition from coexistence of ferroelectric tetragonal and rhombohedral phases to an electrostrictive pseudocubic phase, leading to degradations of the remnant polarization, coercive field, and piezoelectric coefficient $d_{33}$. However, the electricfield-induced strain was significantly enhanced by the Ta substitution-induced phase transition and reached a highest value of $S_{max}/E_{max}$ = 566 pm/V under an applied electric field 6 kV/mm when 2% Ta was substituted on Ti sites. The abnormal enhancement in strain was attributed to the pseudocubic phase with high electrostrictive constants.

키워드

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