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Effect of Adding SiO2 and Al2O3 on Mechanical Properties of Zircon

SiO2와 Al2O3 첨가가 지르콘의 기계적 특성에 미치는 영향

  • Cho, Bum-Rae (Department of Advanced Materials Engineering, Keimyung University)
  • 조범래 (계명대학교 신소재공학과)
  • Received : 2011.02.23
  • Accepted : 2011.03.16
  • Published : 2011.04.27

Abstract

Zircon has excellent thermal, chemical, and mechanical properties, but it is hard to make a dense sintered product because of dissociation during the sintering process. This study analyzes how the addition of $SiO_2$ and $Al_2O_3$ affects the mechanical properties of sintered zircon, particularly in regards to reducing the thermal dissociation and improving the mechanical properties of $ZrSiO_4$. Zircon specimens containing different amounts of $SiO_2$ and $Al_2O_3$ were prepared and sintered to observe how the mechanical properties of $ZrSiO_4$ changed according to the differing amount of $SiO_2$ and $Al_2O_3$. The $ZrSiO_4$ that was used for the starting material was ground by ball mill to an average particle size of 3 ${\mu}m$. The $SiO_2$ and $Al_2O_3$ that was used for additives were ground to an average particle size of 3 ${\mu}m$ and 0.5 ${\mu}m$, respectively. Adding $SiO_2$ resulted in transformation in the liquid phase at high temperatures, which had little effect on suppressing the thermal dissociation but enhanced the mechanical properties of $ZrSiO_4$. When $Al_2O_3$ was added, the mechanical properties of $ZrSiO_4$ decreased due to the formation of pores and abnormal grains in the microstructure of the sintered zircon.

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References

  1. C. J. R. Gonzales-Oliver, M. Schneider, K. Nawata and H.Kusano, J. Non-Crystalline Solids, 100, 274 (1983).
  2. R. N. Singh, J. Am. Ceram. Soc., 73, 2399 (1990). https://doi.org/10.1111/j.1151-2916.1990.tb07604.x
  3. T. Mori, H. Yamamura, H. Kobayashi and T. Mitamura., J. Am. Ceram. Soc., 75, 2420 (1992). https://doi.org/10.1111/j.1151-2916.1992.tb05594.x
  4. R. N. Singh, Am. Ceram. Soc. Bull., 70(1), 117 (1994).
  5. Y. Shi, X. Huang and D. Yan, Ceram. Int., 24(5), 393 (1998). https://doi.org/10.1016/S0272-8842(97)00027-8
  6. J. K. Lee, J. Y. Kim, Y. L. Baeg, J. S. Lee and D. W. Sin,Ceramics Raw Materials, 13, 234 (2000).
  7. L. B. Garrido and E. F. Aglietti, J. Eur. Ceram. Soc., 21(12),2259 (2001). https://doi.org/10.1016/S0955-2219(00)00311-3