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뉴칼레도니아 니켈 라테라이트 광석 내 가니어라이트의 광물학적 특징

Mineralogy of Garnierite from New Caledonian Ni Lateritic Ore

  • 조현구 (경상대학교 지구환경과학과 및 기초과학연구소) ;
  • 김순오 (경상대학교 지구환경과학과 및 기초과학연구소) ;
  • 김상배 (한국지질자원연구원 광물자원연구본부)
  • Cho, Hyen-Goo (Department of Earth and Environmental Sciences and Research Institute of Natural Science, Gyeongsang National University) ;
  • Kim, Soon-Oh (Department of Earth and Environmental Sciences and Research Institute of Natural Science, Gyeongsang National University) ;
  • Kim, Sang-Bae (Mineral Resources Research Division, Korea Institute of Geoscience and Mineral Resources)
  • 투고 : 2011.11.09
  • 심사 : 2011.11.24
  • 발행 : 2011.12.31

초록

뉴칼레도니아 Nakety, Kouaoua, Ouaco 니켈 라테라이트 광상에서 수입하는 가니어라이트 광석의 광물학적 특성을 광학현미경 관찰, X-선 회절 분석과 전자현미분석에 의하여 연구하였다. 녹색 가니어라이트 광석은 교질상, 세포상, boxwork 조직 등 지표 부근의 저온에서 침전에 의한 조직을 잘 나타낸다. 이 광석의 니켈 광석광물은 대부분 니켈 함유 활석~윌렘사이트 계열 광물이며, 일부 리자다이트가 포함되어 있다. 니켈 함유 활석~윌렘사이트 계열 광물 내 NiO의 함량은 Ouaco (평균 40.63%), Nakety (평균 28.58%), Kouaoua (평균 24.90%) 순이며, Mg를 치환하는 Ni 백분율은 43.5~85.0%이다. 암갈색 가니어라이트 광석은 세포상이나 boxwork 조직을 가지며, 주 니켈 광석광물은 리자다이트~니켈 리자다이트 계열 광물에 일부 니켈 함유 활석~윌렘사이트 계열 광물로 구성된다. 리자다이트~니켈 리자다이트 계열 광물 내 NiO의 함량은 1.14~4.06 wt. %이며, Ni/(Mg+Ni) 백분율은 1.7~6.8%인데, 니켈의 함량이 낮은 이유는 팔면체 자리에서 Mg를 치환하는 Fe의 함량이 많은 것에 기인한다.

Mineralogical characteristics of garnierite ores from the Nakety, Kouaoua, and Ouaco Ni laterite deposits in New Caledonia are investigated using optical microscopy, powder X-ray diffractometer, and electron proble microanalyzer. Green garnierite ores have colloform, cellular, and boxwork texture, which are formed by precipitation under low temperature surface environment. They are mainly composed of Ni-bearing talc~willemseite series mineral and partly of lizardite. In Ni-bearing talc~willemseite series mineral, NiO contents are Ouaco (average 40.63%), Nakety (average 28.58%), and Kouaoua (average 24.90%), in descending order. Ni atomic percentage replacing Mg in octahedral site are 43.5~85.0%. Dark brown garnierite ores show cellular or boxwork texture, and consist of lizardite~Ni lizardite with some Ni-bearing talc~willemseite series mineral. Ni contents in lizardite~Ni lizardite are 1.14~4.06 wt. % and Ni atomic percentage replacing Mg in octahedral site 1.7~6.8%. Low NiO content in dark brown garnierite attributes to high Fe content replacing Mg in octahedral site.

키워드

참고문헌

  1. 서울대학교 (1998) 니켈-코발트 광상. 서울대학교 대학원 지질과학과 광상학 연구실(편), 한국의 광상. 박희인 교수 정년퇴임기념논문집. 143-145.
  2. 이현구, 문희수, 오민수 (2007) 한국의 광상. 니켈 광상.아카넷, 398-401.
  3. 지식경제부 (2010) 2009년 광산물 수급현황.
  4. Alcock, R.A. (1988) The character and occurrence of primary resources available to the nickel industry. In: Tyroler, G.P. and Landolt, C.A. (eds.), Extractive metallurgy of copper, nickel and cobalt, Metallurgical Society, 117th TMS Annual Meeting Proceedings, Phoenix, Arizona, 67-89.
  5. Brand, N.W., Butt, C.R.M., and Elias, M. (1998) Nickel laterites: classification and features. AGSO J. Aust. Geol. Geophys., 17, 81-88.
  6. Brindley, G.W. and Hang, P.T. (1973) The nature of garnierites - I structures, chemical compositions and color characteristics. Clays Clay Minerals, 21, 27-40. https://doi.org/10.1346/CCMN.1973.0210106
  7. Brindley, G.W. and Wan, H.M. (1975) Compositions, structures, and thermal behaviour of nickel-containing minerals in the lizardite-nepouite series. Am. Mineral., 60, 863-871.
  8. Dalvi, A.D., Bacon, W.G., and Osborne, R.C. (2004) The past and the future of nickel laterites. In: PDAC 2004 International Convention, Trade Show & Investors Exchange, March 7-10, 1-27.
  9. De Waal, S.A. (1970) Nickel minerals from Barnerton, South Africa: III. Willemseite, A nickel-rich talc. Amer. Mineral., 55, 31-42.
  10. Elias, M. (2002) Nickel laterite deposits - geological overview, resources and exploitation. In: Cooke, D.R. and Pongratz, J. (eds.), Giant ore deposits: characteristics, genesis and exploration, CODES Special Publication 4, Centre for Ore Deposit Research, University of Tasmania, 205-220.
  11. Evans, A.M. (1987) Introduction to Ore Geology (2nd Ed.). Blackwell Publishing, 358p.
  12. Freyssinet, P., Butt, C.R.M., Morris, R.C., and Piantone, P. (2005) Ore-forming processes related to laterite weathering. Economic Geology 100th Anniversary Volume, 681-722.
  13. Gali, S., Soler, J.M., Proenza, J.A., Lewis, F., Tauler, E., and Labrador, M. (2009) Stability of "garnierites" in the Falcondo nickel lateritic deposit, Dominican Republic. Macla, 11, 89-90.
  14. Gleeson, S.A., Butt, C.R.M., and Elias, M. (2003) Nickel laterites: a review. Society of Economic Geologists Newsletter, 54, 9-16.
  15. Golightly, J.P. (1979) Nickeliferous laterites: a general description. In: Evans D.J.I. et al. (eds.), International Laterite Symposium, American Institute of Mining, Metallurgical and Petroleum Engineers Inc., 3-23.
  16. Golightly, J.P. (1981) Nickeliferous laterite deposits. Economic Geology 75th Anniversary Volume, 710-735.
  17. Guilbert, J.M. and Park, Jr., C.F. (1986) The geology of Ore Deposits. W.H. Freeman & Company, New York, 985p.
  18. Kuhnel, R.A., Roorda, H.J., and Steensma, J.J.S. (1978) Distribution and partitioning of elements in nickeliferous laterites. In: Colloquium on the mineralogy, geochemistry and geology of lateritic nickel-bearing minerals and ores, Orleans. Bull. BRGM (2), 3, 191-206.
  19. Llorca, S. and Monchoux, P. (1991) Supergene cobalt minerals from New Caledonia. Can. Mineral., 29, 149-161.
  20. Manceau, A. and Calas, G. (1985) Heterogeneous distribution of nickel in hydrous silicates from New Caledonian ore deposits. Am. Mineral., 70, 549-558.
  21. Moon, C.J., Whateley, M.K.G., and Evans, A.M. (2006) Introduction to Mineral Exploration (2nd Ed.). Blackwell Publishing, 481p.
  22. Proenza, J.A., Lewis, J.F., Gali, S., Tauler, E., Labrador, M., Melgarejo, J.C., Longo, F., and Bloise, G. (2008) Garnierite mineralization from Falcondo Ni-laterite deposit (Dominican Republic). Macla, 9, 197-198.
  23. Proenza, J.A., Garcia-Casco, A., Lewis, J.F., Gali, S., Tauler, E., Labrador, M., Melgarejo, J.C., Longo, F., and Bloise, G. (2009) Textural relations and mineral compositions of garnierite ores using X-ray images. Macla, 11, 155-156.
  24. Schellman, W. (1983) Geochemical principles of lateritic nickel ore formation. In: Melfi, A.J. and Carvalho, A. (eds.), Proceedings of the II International Seminar on Lateritisation Processes, Sao Paulo, Brazil, 1982, 119-135.
  25. Tauler, E., Proenza, J.A., Gali, S., Lewis, J.F., Labrador, M., Garcia-Romero, E., Suarez, M., Longo, F., and Bloise, D.G. (2009) Ni-sepiolite-falcondoite in garnierite mineralization from the Falcondo Ni-laterite deposit, Dominican Republic. Clay Minerals, 44, 435-454. https://doi.org/10.1180/claymin.2009.044.4.435
  26. Troly, G., Esterle, M., Pelletier, B., and Reibell, W. (1979) Nickel deposits in New Caledonia, some factors influencing their formation. In: Evans, D.J.I. et al. (eds.), International Laterite Symposium, New Orleans, Louisiana, 19-21 February, New York, Society of Mining Engineers, 85-119.
  27. Wells, M.A., Ramanaidou, E.R., Verrall, M., and Tessarolo, C. (2009) Mineralogy and crystal chemistry of ''garnierites'' in the Goro lateritic nickel deposit, New Caledonia. Eur. J. Mineral., 21, 467-483. https://doi.org/10.1127/0935-1221/2009/0021-1910

피인용 문헌

  1. Occurrence of Nickel in Bauxite Ore from Samar Island, Philippines vol.26, pp.4, 2013, https://doi.org/10.9727/jmsk.2013.26.4.313
  2. A Study on Classification of Limonite and Saprolite from Nickel Laterite Ores vol.25, pp.1, 2016, https://doi.org/10.7844/kirr.2016.25.1.40