Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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A Study on the NiO-doped Willemite Pigments

Ni-doped Willemite계 청색안료에 관한 연구

  • Lee, Chi-Youn (Department of Material Science & Engineering, Myongji University) ;
  • Lee, Hyun-Soo (Department of Ceramic Art, Han Yang Women's University) ;
  • Lee, Byung-Ha (Department of Material Science & Engineering, Myongji University)
  • 이지연 (명지대학교 신소재공학과) ;
  • 이현수 (한양여자대학 도예과) ;
  • 이병하 (명지대학교 신소재공학과)
  • Received : 2011.12.31
  • Accepted : 2011.01.25
  • Published : 2011.03.31
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Abstract

To study the effect of color development of Ni-doped willemite blue pigments, five batches of compositions were prepared and fired at $1350^{\circ}C$/hold for 1 h. When Ni was substituted for ZnO by 0.03 mole the optimum result were obtained. Then they were fired at $1300^{\circ}C$ and held for 1, 2, 4 and 6 h respectively for the purpose sake. XRD, Raman spectroscopy, FT-IR, UV-vis were used to analyze the results of experiment. The substitution of 0.03mole Ni for Zn was most optimum and which produced good willemite at the temperature of $1300^{\circ}C$, holding for 6 h. In ceramic arts, cobalt has been used for blue coloring, in most cases, despite of its high cost. If the low cost Ni-doped willemite blue pigments supplies for them with stable and multiple shades of blue pigment, using NiO at high temperature, it would provide various blues for ceramic wares.

Keywords

References

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