Bulletin of the Korean Chemical Society

  • 제32권2호
  • /
  • Pages.489-497
  • /
  • 2011
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
DOI QR코드

DOI QR Code

Determination of Cadmium, Chromium and Lead in Polymers by ICP-OES Using a High Pressure Asher (HPA)

  • 투고 : 2010.09.26
  • 심사 : 2010.11.30
  • 발행 : 2011.02.20
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

The proposed method for an effective assay of Cd, Cr and Pb in several polymer samples has been validated. The determination was carried out using ICP-OES after a high pressure asher (HPA) digestion at pressure and temperatures up to 13 MPa and $320^{\circ}C$, respectively. Polymer based materials were totally oxidized with nitric acid in a HPA chamber and determined by ICP-OES. Validation parameters such as linearity, matrix effect, limit of dectection (LOD), limit of quantitation (LOQ), accuracy and precision (repeatibility, intermediate precision and reproducibility) were assessed. The LOD and LOQ in the sample were ranged from 0.98 to 1.18 mg $kg^{-1}$ and 2.93 to 3.55 mg $kg^{-1}$, respectively, relying on the analyte. The proposed method had a good accuracy and precision for repeatability, intermediate precision with respect to days and analysts and reproducibility expressed as inter-laboratory study. The developed method was simple to use, suitable and applicable to various kinds of polymers.

키워드

참고문헌

  1. http://www.rohs.eu/; http://www.rohs.gov.uk.
  2. Gardner, M.; Comber, S. Analyst 2002, 127, 153. https://doi.org/10.1039/b109374f
  3. Soylak, M.; Tuzen, M.; Narin, I.; Sari, H. J. Food Drug Anal. 2004,12, 254.
  4. Mitra, S. John Wiley & Sons, Inc. 2003, 5, 229.
  5. Settle, F. Prentice Hall PTR 1997, 3, 62.
  6. Kumar, S. J.; Ostapczuk, P.; Emons, H.; Fresunius, J. Anal. Chem.1997, 350, 171.
  7. Maichin, B.; Zischka, M.; Knapp, G. Anal. Bioanal. Chem. 2003,376, 715. https://doi.org/10.1007/s00216-003-1962-6
  8. Matusiewicz, H. Anal. Chem. 1999, 71, 3145. https://doi.org/10.1021/ac9901743
  9. Peters, F. T.; Drummer, O. H.; Musshoff, F. Forensic Sci. Int. 2007,165, 216. https://doi.org/10.1016/j.forsciint.2006.05.021
  10. Taverniers, I.; Loose, M. D.; Bockstaele, E. V. Trends Anal. Chem.2004, 23, 535. https://doi.org/10.1016/j.trac.2004.04.001
  11. Guidelines for the Validation and Verification of Chemical Test Methods; National Association of Testing Authorities (NATA), Technical Note, 2006.
  12. Guidelines for the Validation or Analytical Methods for ActiveConstituent, Agricultural and Veterinary Chemical Products; Australian Pesticides & Veterinary Medicines Authority (APVMA),2004.
  13. Validation of Analytical Procedures: Methodology (Final Guidance);Food and Drug Administration Center for Veterinary Medicine,1999.
  14. Guidance for Industry: Bioanalytical Method Validation; U.S. Departmentof Health and Human Services Food and Drug Administration Center for Drug Evaluation and Research (CDER) Center for Veterinary Medicine (CVM), 2001.
  15. Burgess, C. The Royal Society of Chemistry 2000, 2, 6.
  16. A Laboratory Guide to Method Validation and Related Topics;Eurachem Guide: 1998.
  17. Dean, J. R. John Wiley & Sons, Ltd 2005, 1, 12.
  18. Harvey, D. McGraw-Hill 2000, 5, 110.
  19. Harris, D. C. Quantitative Chemical Analysis (5th ed.) 1998, 5, 101.
  20. Hartmann, C.; Smeyers-Verbeke, J.; Massart, D. L.; McDowall,R. D. J. Pharm. Biomed. Anal. 1998, 17, 193. https://doi.org/10.1016/S0731-7085(97)00198-2
  21. Harris, D. C. Quantitative Chemical Analysis (5th ed.) 1998, 4,77.
  22. http://www.kolas.go.kr/english/ (KOLAS).
  23. Plastics - Determination of Cadmium - Wet Decomposition Method;British Standards Institution, 2001.
  24. Determination of Lead in Plastics; Korean Standards Association, 2005.
  25. Microwave Assisted Acid Digestion of Siliceous and Organically Based Matrices; U.S. Environmental Protection Agency, EPA Method 3052, 1996.
  26. Linsinger, T.; Liebich, A.; Przky, E.; Lamberty, A. Institute for Reference Materials and Measurements 2007, 7, 20

피인용 문헌

  1. Atomic spectrometry update. Industrial analysis: metals, chemicals and advanced materials vol.26, pp.12, 2011, https://doi.org/10.1039/c1ja90047a
  2. Selective Iron(III) ion uptake using CuO-TiO2 nanostructure by inductively coupled plasma-optical emission spectrometry vol.6, pp.1, 2012, https://doi.org/10.1186/1752-153X-6-158
  3. Co3O4 co-doped TiO2 nanoparticles as a selective marker of lead in aqueous solution vol.37, pp.9, 2013, https://doi.org/10.1039/c3nj00298e
  4. Surface selectivity competition of newly synthesized polyarylidene(keto amine) polymers toward different metal ions vol.131, pp.19, 2014, https://doi.org/10.1002/app.40873
  5. Selective Divalent Cobalt Ions Detection Using Ag2O3-ZnO Nanocones by ICP-OES Method for Environmental Remediation vol.9, pp.12, 2014, https://doi.org/10.1371/journal.pone.0114084
  6. A SnO2-Sb2O3 nanocomposite for selective adsorption of lead ions from water samples prior to their determination by ICP-OES vol.182, pp.3-4, 2015, https://doi.org/10.1007/s00604-014-1361-z
  7. Eco-Friendly Polythiophene(keto-amine)s Based on Cyclopentanone Moiety for Environmental Remediation pp.1572-8900, 2017, https://doi.org/10.1007/s10924-017-1023-4
  8. RoHS Regulation: Challenges in the Measurement of Substances of Concern in Industrial Products by Different Analytical Techniques vol.33, pp.3, 2018, https://doi.org/10.1007/s12647-018-0263-7
  9. Exploration of calcium doped zinc oxide nanoparticles as selective adsorbent for extraction of lead ion vol.57, pp.41, 2011, https://doi.org/10.1080/19443994.2015.1109560
  10. Adsorption studies of Cr(VI) and Cu(II) metal ions from aqueous solutions by synthesized Ag and Mg co-doped TiO2 nanoparticles vol.54, pp.18, 2011, https://doi.org/10.1080/01496395.2018.1555594
  11. Highly selective heteroaromatic sulfur containing polyamides for Hg +2 environmental remediation vol.23, pp.1, 2011, https://doi.org/10.1080/15685551.2020.1727172
  12. Hydride generation-flame atomic absorption spectrometric quantification of trace lead after the extraction by fatty acid functionalized Fe3O4 nanoparticles assisted dispersive so vol.35, pp.5, 2011, https://doi.org/10.1039/d0ja00025f
  13. Pennisetum sinese: A Potential Phytoremediation Plant for Chromium Deletion from Soil vol.12, pp.9, 2011, https://doi.org/10.3390/su12093651
  14. A metrologically traceable protocol for the quantification of trace metals in different types of microplastic vol.15, pp.7, 2011, https://doi.org/10.1371/journal.pone.0236120
  15. Modification of Sulfonated Polyethersulfone Membrane as a Selective Adsorbent for Co(II) Ions vol.13, pp.20, 2011, https://doi.org/10.3390/polym13203569