Applied Chemistry for Engineering (공업화학)

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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NH3-based SNCR of NOx : Experimental and Simulation

NH3 SNCR을 이용한 NOx 제거 : 실험 및 모사

  • Cha, Jin Sun (School of Environmental Engineering, University of Seoul) ;
  • Park, Sung Hoon (Department of Environmental Engineering, Sunchon National University) ;
  • Jeon, Jong-Ki (Department of Chemical Engineering, Kongju National University) ;
  • Park, Young-Kwon (School of Environmental Engineering, University of Seoul)
  • 차진선 (서울시립대학교 환경공학부) ;
  • 박성훈 (순천대학교 환경공학과) ;
  • 전종기 (공주대학교 화학공학부) ;
  • 박영권 (서울시립대학교 환경공학부)
  • Received : 2011.05.24
  • Accepted : 2011.07.03
  • Published : 2011.08.10
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Abstract

In this study, effects of temperature, NSR, and oxygen concentration on the $NO_x$ removal efficiency of an SNCR process were investigated experimentally as well as numerically using CHEMKIN-II program. The NO removal efficiency increased with the reactor temperature under oxygen-free condition, whereas when the oxygen concentration was 4%, the NO removal efficiency showed a maximum value at $900{\sim}950^{\circ}C$. The pressure of oxygen was shown to enhance the NO removal at low temperature. Regardless of the oxygen concentration, the NO removal efficiency increased with NSR. The temperature and NSR-dependencies of the NO removal efficiency predicted by CHEMKIN-II simulations were similar to that of the experimental results.

본 연구에서는 SNCR 공정에서 온도, NSR, 산소 농도가 질소산화물 제거 효율에 미치는 영향을 실험과 CHEMKIN-II 프로그램을 사용하여 수치적으로 조사하였다. 산소가 없는 조건에서 NO 제거 효율은 반응기 온도에 따라 증가하였다. 반면 산소농도가 4%일 때, NO 제거 효율은 $900{\sim}950^{\circ}C$에서 최대를 나타내었다. 산소의 존재는 저온에서 NO 제거를 증가시키는 것으로 나타났다. 산소농도와 무관하게 NO 제거 효율은 NSR에 따라 증가하였다. CHEMKIN-II에 의해 예측된 NO 제거 효율의 온도와 NSR-의존성은 실험결과와 유사하였다.

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References

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