Journal of the Korean Crystal Growth and Crystal Technology (한국결정성장학회지)

The Korea Association of Crystal Growth (한국결정성장학회)
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Anti-bacterial effects of the Na2O-TiO2-P2O5 glass-ceramics added Ag+ ion

은이온을 함유한 Na2O-TiO2-P2O5 glass-ceramic의 항균 특성

  • Received : 2011.09.21
  • Accepted : 2011.10.07
  • Published : 2011.10.31
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Abstract

Glass-ceramics composed of $5Na_2O-36CaO-10TiO_2-xP_2O_5$ could be obtained with $P_2O_5$ content as following procedure: 1) leaching out $Ca_3(PO_4)_2$ crystals between $Ca_3(PO_4)_2$ and $NaTi_2(PO_4)_3$ selectively in 1 N HCl solution for 2 days, and 2) exchanging $Na^+$ ion to $Ag^+$ ion in Ag($NO_3$) solution for 1 day. Scanning electron microscope (SEM) and X-rat diffractometer (XRD) were measured to verify the proper synthesis of glass-ceramics. And anti-bacteria test was accomplished using Staphylococus aureus bacteria. In the results of anti-bacteria test, the bacteria were died perfectly after 3 hours.

$P_2O_5$ 함량에 따른 $5Na_2O-36CaO-10TiO_2-xP_2O_5$으로 구성된 glass-ceramic을 다음과 같은 방법으로 제조하였다: 1) 1 N HCl 용액 내에서 $Ca_3(PO_4)_2$와 $NaTi_2(PO_4)_3$ 간의 $Ca_3(PO_4)_2$ 결정을 2일간 추출하여 제거함. 2) Ag($NO_3$) 용액에서 1일간 $Na^+$ 이온을 $Ag^+$ 이온으로 이온 교환시킴. Glass-ceramic의 합성 여부를 SEM 및 XRD를 이용하여 확인하였다. Staphylococus aureus를 이용한 박테리아 실험 결과 3시간 이후에는 완전하게 박테리아가 제거됨을 확인할 수 있었다.

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References

  1. J.Y. Kim, S.E. Kim, J.E. Kim, J.C. Lee and J.Y. Yoon, "The biocidal activity of nano-sized silver particles silver particles comparing with silver ion", J. of KSEE 27(7) (2005).
  2. L.M. Sheppard, "Porous ceramics: Processing and applications", Ceramic Transactions Vol. 31, Edited by K. Ishizakietal, Am. Ceram. Soc. (1992), p. 3.
  3. T. Yazawa and H. Tanaka, Porous Materials, ed. K. Ishizaki, Am. Ceram. Soc. (1993) 213.
  4. M. Uo, M. Numata, M. Suzuki, I. Karube and A. Makishima, J. Ceram. Soc. Jpn. 100 (1992) 430. https://doi.org/10.2109/jcersj.100.430
  5. T. Kanazawa, "Inorganic phosphate materials", Chapter 6 & 7 (Elsevier, 1990).
  6. B.H. Kim et al., "Multi porous glass and shape splitting", Science and Technology of Ceramic Materials 4 (1991) 259.
  7. H. Hosono and Y. Abe, J. Non-crystalline Solids 190 (1995) 185. https://doi.org/10.1016/0022-3093(95)00309-6
  8. N. Simonetti, G. Simonetti, F. Bougnol and M. Scalzo, Appl. Environ. Microbiol. 58 (1992) 3834.
  9. M.G. Park and W.H. Kang "Pore-size in $LiTi_{2}(PO_{4})_{3}$ glass-ceramics" J. the New Material Technology 6 (1996) 25.
  10. Y.J. Yoon, Y.S. Lee and W.H. Kang "Antibacterial effect of porous glass ceramics as Ag ion exchange in phosphate system", J. the Korean Ceramic Society 38 (2001) 1055.