Bulletin of the Korean Chemical Society

  • 제32권12호
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  • Pages.4258-4264
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  • 2011
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Quantification of Total Mercury in Antarctic Surface Snow using ICP-SF-MS: Spatial Variation from the Coast to Dome Fuji

  • 투고 : 2011.07.02
  • 심사 : 2011.10.09
  • 발행 : 2011.12.20
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초록

The total mercury concentration ($Hg_T$) of surface snow samples collected along a ~1500 km transect in east Queen Maud Land was determined using inductively coupled plasma sector field mass spectrometry to address the behavior of Hg on the Antarctic Plateau. Due to the volatile nature of mercury, measures were taken against Hg loss from standard solutions by choosing appropriate container material and stabilizing agents. Glass bottles with Teflon-lined caps were superior to Teflon and polyethylene containers in protecting against Hg loss, but addition of gold chloride ($AuCl_3$) or bromine chloride (BrCl) was necessary to ensure preservation of Hg. As Hg loss was also observed in snowmelt samples, our analysis may underestimate the actual amount of HgT in the snow. Even so, the measured HgT was still very low (< 0.4-10.8 pg $g^{-1}$, n = 44) without a signal of depositional enhancement accompanying photo-oxidation of atmospheric elemental mercury in austral midsummer. Moreover, the dynamic variation along the traverse implies spatial and temporal heterogeneity in its source processes.

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피인용 문헌

  1. Atomic spectrometry update. Environmental analysis vol.28, pp.2, 2013, https://doi.org/10.1039/c2ja90077g
  2. Spatial and temporal variations of total mercury in Antarctic snow along the transect from Zhongshan Station to Dome A vol.66, pp.1, 2014, https://doi.org/10.3402/tellusb.v66.25152
  3. Multi-year record of atmospheric mercury at Dumont d'Urville, East Antarctic coast: continental outflow and oceanic influences vol.16, pp.13, 2016, https://doi.org/10.5194/acp-16-8265-2016