The Measurement and Investigation of Fire and Explosion Properties for Acetone

아세톤의 화재 및 폭발 특성치 측정 및 고찰

  • Ha, Dong-Myeong (Department of Occupational Health and Safety Engineering, Semyung University)
  • 하동명 (세명대학교 보건안전공학과)
  • Received : 2010.04.20
  • Accepted : 2010.07.23
  • Published : 2010.08.31

Abstract

For the safe handling of acetone, the flash point, the explosion limit at $25^{\circ}C$ and the temperature dependence of the explosion limits were investigated. And the AIT for acetone were experimented. By using the literatures data, the lower and upper explosion limits of acetone recommended 2.5 vol% and 13.0 vol%, respectively. In this study, the lower flash points of acetone recommended $-20^{\circ}C$. This study was determined relationship between the AITs and the ignition delay times by using ASTM E659-78 apparatus for acetone, and the experimental AIT of acetone was $565^{\circ}C$. The new equations for predicting the temperature dependence of the explosion limits of acetone is proposed. The values calculated by the proposed equations were a good agreement with the literature data.

Keywords

References

  1. F.P. Lees, "Loss Prevention in the Process Industries", Vol. 2, 2nd ed., Butterworth-Heinemann, 1996.
  2. A.A. Kline, C.R. Szydlik, T.N. Rogers and M.E. Mullins, "An Overview of Compiling, Critically Evaluating, and Delivering Reliable property Data AIChE DIPPER Project 911 and 912", Fluid Phase Equilibria, Vol. 150-151, pp. 421-428,1998. https://doi.org/10.1016/S0378-3812(98)00342-2
  3. NFPA, "Fire Hazard Properties of Flammable Liquid, Gases, and Volatile Solids", NFPA 325M, NFPA, 1991.
  4. SFPE, "SFPE Handbook of Fire Protection Engineering", 2nd ed., SFPE, 1995.
  5. V. Babrauskas, "Ignition Handbook", Fire Science Publishers, SFPE, 2003.
  6. L.G. Britton, "Two Hnndred Years of Flammable Limits", Process Safety Progress, Vol. 21, No.1, pp. 1-11, 2002. https://doi.org/10.1002/prs.680210104
  7. H.K Abdel-Aal et aI., "A New Approach to Utilize Hydrogen as a Safe Fuel", International J. of Hydrogen Energy, Vol. 30, pp. 1511-1515, 2005. https://doi.org/10.1016/j.ijhydene.2005.07.007
  8. 하동명, "메탄의 화재 및 폭발 위험성평가', 한국가스학회지, 제9권, 제2호, pp. 1-7, 2005.
  9. 하동명,"프로판가스의화재 및 폭발특성치에 관한 연구." 한국가스학회지, 제 10권, 제2호, pp. 33-39, 2006.
  10. 하동명, "안전한수소 이용을 위한 연소특성치 고찰" 한국가스학회지, 제 12 권, 제2호, pp. 1 -6, 2008.
  11. 하동명,"MEK의 연소특성 고찰을통한 MSDS의 적정성", 한국안전학회지, 제23 권, 제3 호, pp. 36-41 , 2008.
  12. 柳生昭三, "薰氣の爆發限界", 安全工學協會, 1979.
  13. D.R. Lide, "CRC Handbook of Chemistry and Physics", 75th ed., CRC Press, 1994.
  14. G.M. Zabetakis, "Flammability Characteristics of Combustible Gases and Vapors", US Bureau of Mines, Bulletin, 1965.
  15. J.E. Hustad and O.K. Sonju, "Experimental Studies of Lower Flammability Limits of Gases and Mixtures of Gases at Elevated Temperature", Combustion and Flame, Vol. 71, pp. 283-294, 1988. https://doi.org/10.1016/0010-2180(88)90064-8
  16. 하동명, "파라핀족 탄화수소의 폭발한계의 온도 의존성 예측", 한국안전학회지, 제15권, 제3호, pp. 71-77 , 2000.
  17. K.L Cashdollar, "Overview of Dust Explosibility Characteristics", J . of Loss Prevention in the Process Industries, Vol. 13, No. 3-5, pp. 183-199,2000. https://doi.org/10.1016/S0950-4230(99)00039-X
  18. R. E. Lcnga and K. L. Votoupal, "The Sigma Aldrich Library of Regulatory and Safety Data, Volume I -Ill", Sigma Chemical Company and Aldrich Chemical Company Inc., 1993.
  19. M. Sheldon, "Understanding Auto-ignition Temperature", Fire Engineering J., June, pp. 27-32, 1984.
  20. G.S. Scott, G.W. Jones and F.E. Scott, "Determination of Ignition Temperature of Combustible Liquids and Gases", Analytical Chemistry, Vol. 20, No.3, pp. 238-241,1948. https://doi.org/10.1021/ac60015a015
  21. C. Marsdon, "Solvent Guide", 2nd, ed., London, Cleavor-Hume,1963.
  22. J. Gmehing, U. Onken and W. Arlt, "Vapor-Liquid Equilibrium Data Collection", I, Part 1-7, DECHEMA, 1980.
  23. P.E. Cote, "Fire Protection Handbook", 17th ed., NFPA, Quincy, Massachusetts, 1991.
  24. N.N. Semenov, "Some Problems in Chemical Kinetics and Reactivity, Vol. 2", Princeton University Press, princeton, N.J., 1959.