Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
권호 표지
DOI QR코드

DOI QR Code

Morphological Properties of Poly(ε-caprolactone) Nano/Microcapsules Prepared by Emulsion-diffusion Method

유화-확산법에 의해 제조된 폴리(ε-카프로락톤) 나노/마이크로캡슐의 형태적 특성

  • Kim, Hea-In (Dept. of Organic Material Science and Engineering, Pusan National University) ;
  • Jeong, Cheon-Hee (Dept. of Organic Material Science and Engineering, Pusan National University) ;
  • Park, Soo-Min (Dept. of Organic Material Science and Engineering, Pusan National University)
  • 김혜인 (부산대학교 유기소재시스템공학과) ;
  • 정천희 (부산대학교 유기소재시스템공학과) ;
  • 박수민 (부산대학교 유기소재시스템공학과)
  • Received : 2010.08.16
  • Accepted : 2010.09.08
  • Published : 2010.09.27
Download PDF
⟨ Previous Next ⟩

Abstract

Poly($\varepsilon$-caprolactone) nano/microcapsules(nmcPCL) containing phytoncide oil were synthesized by emulsion diffusion method using ethyl acetate and poly(vinyl alcohol) (PVA) as an organic solvent and an emulsion stabilizer respectively. The influence of the degree of saponofication of the PVA and the weight ratio of core to wall materials was investigated to design nanocapsules in terms of particle size, morphology, and emulsion stability. The encapsulated nmcPCL were characterized by FT-IR spectrometry, particle size analyzer and scanning electron microscope. Mean size of nanocapsules prepared with PVA with a degree of saponofication of 87% was smaller than those of PVA with a degree of saponofication of 98.5% and the mean particle size of the capsules decreased with increasing core/shell ratio.

Keywords

References

  1. B. Kiskan and Y. Yagci, Synthesis and Characterization of Naphthoxazine Functional Poly($\varepsilon$-caprolactone), Polymer, 46(25), 11690-11697(2005). https://doi.org/10.1016/j.polymer.2005.09.061
  2. S. M. Lee, S. O. Sohn, Y. M. Kim, H. Y. Lee, M. K. Kim, J. H. Choi and H. D. Ghim, Preparation of Aromatic Polystyrene Nanoparticles Using Emulsification-Diffusion Technique: Characteristics and Release Behaviors, Journal of the Korean Fiber Society, 44(1), 9-15(2007).
  3. S. O. Sohn, S. M. Lee, Y. M. Kim and H. D. Ghim, Characteristics and Release Behaviors of Aromatic Poly(vinyl acetate) Nanoparticles Prepared by Emulsification-Diffusion Technique, Polymer(Korea), 31(3), 177-183(2007).
  4. H. I. Kim and S. M. Park, Preparation and Properties of Microcapsule with EVA core-PU Shell Structure, Journal of Applied Polymer Science, 103(2), 893-902(2007). https://doi.org/10.1002/app.25227
  5. L. T. M. Hoa, N. T. Chi, N. M. Triet, L. N. T. Nhan and D. M. Chien, Preparation of Drug Nanoparticles by Emulsion Evaporation Method, Journal of Physics: Conference Series, 187(1), 1-4(2009).
  6. M. Lee, Y. W. Cho, J. H. Park, H. Chung, S. Y. Jeong, K. Choi, D. H. Moon, S. Y. Kim, I. S. Kim and I. C. Kwon, Size Control of Self-assembled Nanoparticles by an Emulsion/Solvent Evaporation Method, Colloid & Polymer Science, 284(5), 506-512(2006). https://doi.org/10.1007/s00396-005-1413-3
  7. M. Jacques, M. Kobisch, M. Belanger, and F. Dugal, Virulence of Capsulated and Noncapsulated Isolates of Pasteurella Multocida and Their Adherence to Porcine Respiratory Tract Cells and Mucus, Infection and Immunity, 61(11), 4785-4792(1993).
  8. U. Bilati, E. Allemann and E. Doelker, Development of a Nanoprecipitation Method Intended for the Entrapment of Hydrophilic Drugs into Nanoparticles, European Journal of Pharmaceutical Sciences, 24(1), 67-75(2005). https://doi.org/10.1016/j.ejps.2004.09.011
  9. M. Y. Lee, S. G. Min, S. Bourgeoisa and M. J. Choi, Development of a Novel Nanocapsule Formulation by Emulsion-diffusion Combined with High Hydrostatic Pressure, Journal of Microencapsulation, 26(2), 122-129(2009). https://doi.org/10.1080/02652040802193006
  10. M. Hassou, F. Couenne, Y. I. Gorrec and M. Tayakout, Modeling and Simulation of Polymeric Nanocapsule Formation by Emulsion Diffusion Method, AIChE Journal, 55(8), 2094-2105(2009). https://doi.org/10.1002/aic.11809
  11. Z. B. Zhanga, Z. G. Shena, J. X. Wanga, H. X. Zhanga, H. Zhaoa, J. F. Chenb and J. Yunc, Micronization of Silybin by the Emulsion Solvent Diffusion Method, International Journal of Pharmaceutics, 376(6), 116-122(2009). https://doi.org/10.1016/j.ijpharm.2009.04.028
  12. M. Antonietti and S. Forster, Vesicles and Liposomes: A Self-Assembly Principle Beyond Lipids, Advanced Materials, 15(16), 1323-1333 (2003). https://doi.org/10.1002/adma.200300010
  13. S. H. Seo, J. Y. Chang and G. N. Tew, Angewandte, Self-Assembled Vesicles from an Amphiphilic ortho-Phenylene Ethynylene Macrocycle, Angewandte Chemie International Edition, 45, 7526-7530(2006). https://doi.org/10.1002/anie.200600688
  14. M. I. Rea and B. Biscans, Preparation of Microspheres of Ketoprofen with Acrylic Polymers by a Quasi-emulsion Solvent Diffusion Method, Powder Technology, 101(2), 120-133(1999). https://doi.org/10.1016/S0032-5910(98)00163-6
  15. T. Toyota, K. Takakura, J. Kose and T. Sugawara, Hierarchical Dynamics in the Morphological Evolution from Micelles to Giant Vesicles Induced by Hydrolysis of an Amphiphile, ChemPhysChem, 7(7), 1425-1427(2006). https://doi.org/10.1002/cphc.200600176
  16. D. Quintanar-Guerreroa, H. Fessib, E. Allemannc and E. Doelker, Influence of Stabilizing Agents and Preparative Variables on the Formation of Poly(-lactic acid) Nanoparticles by an Emulsification-diffusion Technique, International Journal of Pharmaceutics, 143(2), 133-141(1996). https://doi.org/10.1016/S0378-5173(96)04697-2
  17. K. Hong and S. Park, Morphologies and Release Behavior of Polyurea Microcapsules from Different Polyisocyanates, Journal of Materials Science, 34(13), 3161-3164(1999). https://doi.org/10.1023/A:1004621620955
  18. H. I. Kim, Y. H. Hong and S. M. Park, Development and Applications of Frame Retardant Nano and Microcapsule, Textile Coloration and Finishing(J. Korean Soc. Dyers & Finishers), 20(4), 31-42(2008). https://doi.org/10.5764/TCF.2008.20.4.031
  19. M. Nakamae, K. Yuki, T. Sato and H. Maruyama, Preparation of Polymer Emulsions Using a Poly(vinyl alcohol) as Protective colloid, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 153, 367-372(1999). https://doi.org/10.1016/S0927-7757(98)00458-0
  20. S. I. Song and B. C. Kim, Characteristic Rheological Features of PVA Solutions in Watercontaining Solvents with Different Hydration States, Polymer, 45(7), 2381-2386(2004). https://doi.org/10.1016/j.polymer.2004.01.057
  21. S. Guinebretiere, S. Briancon, J. Lieto, C. Mayer and H. Fessi, Study of the Emulsion- Diffusion of Solvent: Preparation and Characterization of Nanocapsules, Drug Development Research, 57(1), 18-33(2002). https://doi.org/10.1002/ddr.10054
  22. Z. B. Zhang, Z. G. Shen, J. X. Wang, H. X. Zhang, H. Zhao, J. F. Chen and J. Yun, Micronization of Silybin by the Emulsions Solvent Diffusion Method, International Journal of Pharmaceutics, 376, 116-122(2009). https://doi.org/10.1016/j.ijpharm.2009.04.028
  23. H. I. Kim, J. Xuan-Zhen, H. W. Choi and S. M. Park, Preparation of Polyurea Microcapsules Containing Phase Change Material and their Application on Fiber Composites, Textile Coloration and Finishing(J. Korean Soc. Dyers & Finishers), 19(1), 37-44(2007).
  24. C. Jorge, B. Ramireza, H. O. Jorge and A. G. Virgilio, Kinetics of Styrene Minisuspension Polymerization Using a Mixture PVA-SDS as Stabilizer, Polymer, 47(10), 3336-3343(2006). https://doi.org/10.1016/j.polymer.2006.03.029

Cited by

  1. Preparation and characterization of melamine-formaldehyde microcapsules containing Citrus unshiu essential oil vol.15, pp.1, 2014, https://doi.org/10.1007/s12221-014-0035-0