방사성폐기물학회지 (Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT))

  • 제8권2호
  • /
  • Pages.107-113
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  • 2010
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  • 1738-1894(pISSN)
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  • 2288-5471(eISSN)
한국방사성폐기물학회 (Korean Radioactive Waste Society)
권호 표지

카올리나이트에 대한 휴믹산 및 아메리슘 흡착거동 연구

A Study of Adsorption Behaviour of Humic Acid and Americium on the Kaolinite

  • 투고 : 2010.02.18
  • 심사 : 2010.05.03
  • 발행 : 2010.06.30
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초록

본 연구에서는 pH 변화에 따른 카올리나이트-휴믹산, 카올리나이트-아메리슘 및 휴믹산-아메리슘 등의 이성분계 흡착반응을 조사하였다. 카올리나이트의 물리화학적 특성을 조사한 후, 휴믹산농도, 이온강도 및 pH 변화에 따른 카올리나이트에 휴믹산의 흡착실험을 하였다. pH 및 HA 농도가 증가함에 따라 KA에 대한 HA의 흡착율이 감소하였으나, 이온강도가 증가함에 따라 HA의 흡착율이 증가하였다. 또한 pH 변화에 따른 카올리나이트와 아메리슘과 흡착반응 및 아메리슘과 휴믹산과의 흡착반응도 연구하였다. 산성 및 중성영역에서는 Am이 HA에 쉽게 흡착되었으나, 염기성 영역에서는 정전기적 반발력으로 HA에 대한 Am 흡착이 감소되었다. 본 연구 결과는 수환경에서 휴믹산에 의한 아메리슘 흡착거동 특성을 이해하는데 활용이 가능하다.

In this study, the adsorption reactions in the binary component system such as kaolinite-humic acid, kaolinite-americium and humic acid-americium were investigated. After performing the basic physico-chemical properties of the kaolinite, the adsorption reactions of the humic acid on the kaolinite were carried out with varying concentration of humic acid and ion strength, and pH. With increasing HA concentration and pH, the sorption of HA onto KA decreased, while the sorption of HA onto KA increased with increasing ionic stre ngth. Also, with varying pH, the adsorption reactions of the americium-kaolinite and americium-humic acid were studied. In the acid and neutral region, Am easily adsorbed on the HA, while the sorption of Am on the HA in the alkali region decreased because of electrostatic repulsion. The results from these studies make it possible to understand the characteristics of adsorption behaviour of the americium by the humic acid in the water environment.

키워드

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