Effect of Sludge Formation on the Thickness of Die Soldering Reaction Layer in Al-9Si-0.3Mg Casting Alloy

Al-9Si-0.3Mg 주조용 합금에서 Sludge 형성이 금형소착 반응층 두께에 미치는 영향

  • Kim, Heon-Joo (Dept. of Metallurgical Eng., Pukyong National Univ.)
  • 김헌주 (부경대학교 공과대학 금속공학과)
  • Received : 2010.03.30
  • Accepted : 2010.04.14
  • Published : 2010.04.30

Abstract

Effect of reaction time and sludge formation on the thickness of die soldering reaction layer has been studied in Al-9Si-0.3Mg casting alloy. Ternary ${\alpha}_{bcc}-Al_8Fe_2Si$ and ${\alpha}_{hcp}-Al_8Fe_2Si$ intermetallic compounds formed at the interface of SKD61 tool steel by interaction diffusion of Al, Fe and Si atoms after 0.5hr and 6hr immersion time, respectively. Binary ${\eta}-Fe_2Al_5$ additionally formed at the interface of SKD61 tool steel after 10hr immersion time. Thickness of soldering reaction layer in die surface increased as immersion time increased from 0.5hr to 24hr. Sludge formation was ascertained in the samples which were immersed in the melts more than 10hr. Reaction of die soldering after sludge formation was more accelerated than that of before sludge formation due to a decrease in Fe content, followed by higher diffusion rate of Al in the melt by sludge formation.

Keywords

References

  1. J. L. Jorstad, "Future technology in Aluminum die casting", Die Casting Engineer, Vol. 9 (2006) 18-25.
  2. H. Koch, U. Hielsher, H. Sternau and A. J. Franke, "Silafont- 36, the new low iron high-pressure die-casting alloy", TMS (1995) 1011-1018.
  3. L. A. Naraynan, F. H. Samuel and J. E. Gruzleski, "Dissolution of iron intermetallics in AI-Si alloys through nonequilibrium heat treatment", Metall. Mater. Trans. A, Vol. 26A (2004) 2161-2174.
  4. Mascre, C. "Influence of iron and manganese on type A-S13 (Alpax) alloys", Fonderie, Vol. 108 (1995) 4330-4336.
  5. Couture, A. "Iron in aluminum casting alloys-A literature survey", AFS Int. Cast. Metals Journal, Vol. 6 (1981) 9-17.
  6. S. Shankar and D. Apelian, "The role of aluminum alloy chemistry and die material in die soldering", NADCA transactions, Vol. 83 (1999) 285-292.
  7. Q. Han and S. Viswanathan, "Analysis of the mechanism of die soldering in aluminum die casting", Metallurgical and Materials Transactions A, Vol, 34A (2003) 139-146.
  8. S. Shankar and D. Apelian, "Mechanism and preventive measures for die soldering during Al casting in a ferrous mold", JOM, Vol. 54, No. 8 (2002) 47-54. https://doi.org/10.1007/BF02711867
  9. Adam Kopper and Dr. Raymond Donahue, "Solder Resistance Mechanisms of Novel Al-Sr-Si Die Casting Alloys", TMS, (2006) 801-805.
  10. Lyman, Taylor. Boyer, Howard E. Metals Handbook, 8th Edition, "Metallography, Structures and Phase Diagrams", Vol. 8 (1973) 392-393.
  11. Makhlouf M. Makhlouf and D. Apelian, "Casting Characteristics of Aluminum Die Casting Alloys", ACRC, Feb. (2002) Paper No. DEFC07-99ID13716
  12. Sandhya Gopal, Anup Lakare and Rajiv Shivpuri, "Soldering in Die Casting: Aluminum Alloy and Die Steel Interactions", Die Casting Engineer, May/June (2000) 70-79.
  13. D.T. Fraser, Z.W. Chen and M.Z. Jahedi, "Structures of intermetallic phases formed during immersion of H13 tool steel in an Al-11Si-3Cu die casting alloy melt", Mater. Sci. and Eng., A260 (1999) 188-196.
  14. S. Shankar and D. Apelian, "Die Soldering: Effect of process parameters and alloy characteristics on soldering in the pressure die casting process", Int. J. Cast Metals Res., Vol. 15 (2002) 103-116. https://doi.org/10.1080/13640461.2002.11819469
  15. S. Shankar and D. Apelian, "Die Soldering: Mechanism of the Interface Reaction between Molten Aluminum Alloy and Tool Steel", Metallurgical and Materials Transactions B, Vol. 33B (2002) 465-476.
  16. Heon-Joo Kim, Chi-Man Cho and Chang-Yeol Jeong, "Effect of Fe, Mn contents of Al-9Si-0.3Mg alloys on the thickness of die soldering reaction layer for SKD61 die steel", Journal of the Korean Foundrymen's Society, Vol. 29, No. 4 (2009) 169-175.
  17. L. Anantha Narayanan, F. H. Samuel and J. E. Gruzleski, "Crystallization Behavior of Iron-Containing Intermetallic Compounds in 319 Aluminum Alloy", Metall. Mater. Trans. A, Vol. 25A (1994) 1761-1773.
  18. Malgorzata Warmuzek, Wiktoria Ratuszek, Grazyna Sek-Sas, "Chemical inhomogeneity of intermetallic phases precipitates formed during solidification of Al-Si alloys", Materials Characterization, Vol. 54 (2005) 31-40. https://doi.org/10.1016/j.matchar.2004.10.001
  19. J.L. Jorstad, "Understanding Sludge", Proc. of the 14th SDCE International Die Casting Congress and Exposition, Toronto. ont, Canada, May 11-14 (1987) Paper No. G-T87-011.
  20. Yeou-Li, Patrick S. Cheng and Rajiv Shivpuri, "Soldering Phenomenon in Aluminum Die Casting: Prossible Causes and Cures", NADCA transactions, October 18-21 (1993) 361-371.
  21. P. N. Crepeau, B. L. Tiwari, and K. M. Rahmoeller, "Characterization of Oxide Sludge, Dross and Inclusions in Aluminum Melting and Holding Furnaces", Proc. Of the 3rd international Conference on Molten Aluminum Processing, Orlando, Fl, November (1992) 51-57.
  22. H. R. Shahverdi, M. R. Ghomashchi, S. shabestari and J. Hejazi, "Kinetics of interfacial reaction between solid iron and molten aluminium", Journal of materials science 37 (2002) 1061-1066. https://doi.org/10.1023/A:1014324603763
  23. E. A. Brandes and G. B. Brook, Smithells Metals Reference Book, 7th edition, (1992) 13-10
  24. The Japan Institude of Metals, Metal Data Book, 4th Edition (1993) 20
  25. S.G. Shabestari, "The effect of iron and manganese on the formation of intemetallic componds in aluminum-silicon alloys", Materials science and engineering A, Vol 383 (2004) 289-298. https://doi.org/10.1016/S0921-5093(04)00832-9