Bulletin of the Korean Chemical Society

  • 제31권10호
  • /
  • Pages.2786-2790
  • /
  • 2010
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
DOI QR코드

DOI QR Code

Three New Oleanane-Type Triterpene Saponins from Gladiolus gandavensis

  • Tai, Zhi-Gang (Key Laboratory of Medicinal Chemistry for Nature Resource, Ministry of Education, School of Chemical Science and Technology, Yunnan University) ;
  • Cai, Le (Key Laboratory of Medicinal Chemistry for Nature Resource, Ministry of Education, School of Chemical Science and Technology, Yunnan University) ;
  • Yang, Ya-Bin (Key Laboratory of Medicinal Chemistry for Nature Resource, Ministry of Education, School of Chemical Science and Technology, Yunnan University) ;
  • Liu, Chuan-Shui (Key Laboratory of Medicinal Chemistry for Nature Resource, Ministry of Education, School of Chemical Science and Technology, Yunnan University) ;
  • Xia, Jian-Jun (Key Laboratory of Medicinal Chemistry for Nature Resource, Ministry of Education, School of Chemical Science and Technology, Yunnan University) ;
  • Ding, Zhong-Tao (Key Laboratory of Medicinal Chemistry for Nature Resource, Ministry of Education, School of Chemical Science and Technology, Yunnan University)
  • 투고 : 2010.06.22
  • 심사 : 2010.08.12
  • 발행 : 2010.10.20
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Three new oleanane-type triterpene saponins (1, 2 and 3) were isolated from aerial parts of Gladiolus gandavensis, along with two known compounds (4 and 5). Their structures were elucidated as 29-O-($\beta$-D-glucopyranosyl)-$2{\beta}$,$3{\beta}$-dihydroxyolean-12-en-28-oicacid(1), 3-O-($\beta$-D-xylopyranosyl)-29-O-($\beta$-D-glucopyranosyl)-12-en-28-oic acid (2), and $2{\beta}$,$3{\beta}$,29-trihydroxyolean-12-en-28-oic acid 28-O-[$\beta$-D-glucopyranosyl($1{\rightarrow}2$)-($\alpha$-L-rhamnopyranosyl($1{\rightarrow}6$))-$\beta$-D-glucopyranosyl] ester (3), by spectroscopic methods, and by comparison with known analogues. These oleanane-type triterpene saponins glycosidated at C-29 were not obtained frequently.

키워드

참고문헌

  1. Guo, W. Y.; Liu, Y.; Duan, W. H. Chinese Medicinal Flowers; Science Book and Periodical Press: Beijing, 1989; p 177.
  2. Wang, D. Y.; Ye, Q.; Zhang, G. L.; Li, B. G. Journal of Asian Natural Products Research 2003, 5, 297. https://doi.org/10.1080/1028602031000111950
  3. Chen, B.; Wang, D. Y.; Ye, Q.; Li, B. G.; Zhang, G. L. Journal of Asian Natural Products Research 2005, 7, 197. https://doi.org/10.1080/10286020310001653336
  4. Zhang, T.; Ye, Q.; Feng, C.; Chen, Y. M. Chinese Journal of Applied & Environmental Biology 2007, 13, 635.
  5. Fumiko, A.; Tatsuo, Y.; Hirotaka, S.; Isao, K. Phytochemistry 1996, 42, 809. https://doi.org/10.1016/0031-9422(96)00003-9
  6. Li, W.; Fu, H. W.; Bai, H.; Sasaki, T.; Kato, H.; Koike, K. J. Nat. Prod. 2009, 72, 1755. https://doi.org/10.1021/np900237a
  7. Feng, W. S.; Wang, Y. S.; Zheng, X. K. Structure Analysis for Chemical Constituents of Chinese Medicinal Herbs; Science Publishing House: Beijing, 2007; p 425.
  8. Calis, I.; Kirmizibekmez, H.; Tasdemir, D.; Rueedi, P. Helv. Chim. Acta 2004, 87, 611. https://doi.org/10.1002/hlca.200490059
  9. Gong, H. Y.; Ding, L. S. $^{13}C$-NMR Analysis for Natural Products; Yunnan Science and Technology Press: Kunming, 2006; p 397.
  10. Shao, Y.; Zhou, B. N.; Ma, K.; Wu, H. M. J. Nat. Prod. 1995, 58, 837. https://doi.org/10.1021/np50120a003
  11. Masazumi, M.; Asazumi, M.; Susumu, I.; Hirotoshi, S.; Yasuaki, H.; Junzo, S.; Yoshiteru, I. Phytochemistry 1997, 46, 1255. https://doi.org/10.1016/S0031-9422(97)80022-2
  12. Giuseppina, C.; Fabrizio, D. P.; Antonio, V.; Fabio, V.; Paolo, D. C.; Francesco, D. S.; Nunziatina, D. T. J. Nat. Prod. 2008, 71, 1000. https://doi.org/10.1021/np8000464
  13. Mencherini, T.; Picerno, P.; Gaudio, P. D.; Festa, M.; Capasso, A.; Aquino, R. J. Nat. Prod. 2010, 73, 247. https://doi.org/10.1021/np900466x
  14. Shao, Y.; Zhou, B. N.; Gao, J. H.; Lin, L. Z.; Cordell, G. A. Phytochemistry 1995, 38, 675. https://doi.org/10.1016/0031-9422(94)00716-7
  15. Alley, M. C.; Scudiero, D. A.; Monks, A.; Hursey, A. M.; Czerwinski, M. J.; Fine, D. L. Cancer Research 1988, 48, 589.

피인용 문헌

  1. Triterpenoids vol.29, pp.7, 2012, https://doi.org/10.1039/c2np20027a
  2. Recent Studies on Anti-Depressant Bioactive Substances in Selected Species from the Genera Hemerocallis and Gladiolus : A Systematic Review vol.12, pp.4, 2010, https://doi.org/10.3390/ph12040172