Bulletin of the Korean Chemical Society

  • 제31권9호
  • /
  • Pages.2701-2704
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  • 2010
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Synthesis and Characterization of New Tetraaza Macrocycles Bearing Two or Four N-Methoxyethyl Pendant Arms and Their Copper(II) and/or Nickel(II) Complexes

  • 투고 : 2010.05.26
  • 심사 : 2010.07.22
  • 발행 : 2010.09.20
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초록

This work shows that both L2 and L3 bearing two and four N-$(CH_2)_2OCH_3$ groups, respectively, can be prepared selectively by the reaction of $L^1$ with 1-bromo-2-methoxyethane. The di-N-substituted macrocycle $L^2$ readily forms its copper(II) and nickel(II) complexes. The N-$(CH_2)_2OCH_3$ groups in $[CuL^2]^{2+}$ are coordinated to the metal ion, whereas those in $[NiL^2]^{2+}$ are not involved in coordination. Interestingly, $L^3$ reacts with $Cu^{2+}$ ion to form $[Cu(HL^3)]^{3+}$, in which one tertiary amino group is not involved in coordination.

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피인용 문헌

  1. The use of [Fe(dithiooxalate)2(NO)]2− as a tecton in crystal engineering vol.13, pp.16, 2011, https://doi.org/10.1039/c1ce05309d
  2. Synthesis and Characterization of New Mono-N-functionalized Tetraaza Macrocyclic Nickel(II) and Copper(II) Complexes vol.32, pp.8, 2010, https://doi.org/10.5012/bkcs.2011.32.8.2565
  3. Synthesis of C-meso and/or C-racemic isomers of tetraaza macrocyclic copper(II) and nickel(II) complexes bearing one or two N-CH2OCH3 pendant arms vol.379, pp.1, 2010, https://doi.org/10.1016/j.ica.2011.09.036