석탄가스화를 위한 중국산 저급 석탄의 광물학적 및 건조 특성

Mineralogical and Drying Characteristics of Chinese Low Rank Coal for Coal Gasification

  • 박종력 (한국지질자원연구원 광물자원연구본부) ;
  • 김병곤 (한국지질자원연구원 광물자원연구본부) ;
  • 전호석 (한국지질자원연구원 광물자원연구본부) ;
  • 김상배 (한국지질자원연구원 광물자원연구본부) ;
  • 박석환 (한국지질자원연구원 광물자원연구본부) ;
  • 이재령 (강원대학교 에너지자원공학과)
  • Park, Chong-Lyuck (Mineral Resources Research division, Korea Institute of Geoscience and Mineral Resources) ;
  • Kim, Byoung-Gon (Mineral Resources Research division, Korea Institute of Geoscience and Mineral Resources) ;
  • Jeon, Ho-Seok (Mineral Resources Research division, Korea Institute of Geoscience and Mineral Resources) ;
  • Kim, Sang-Bae (Mineral Resources Research division, Korea Institute of Geoscience and Mineral Resources) ;
  • Park, Suk-Hwan (Mineral Resources Research division, Korea Institute of Geoscience and Mineral Resources) ;
  • Lee, Jae-Ryeong (Department of Energy & Mineral Resources Engineering, Kangwon National University)
  • 투고 : 2010.09.07
  • 심사 : 2010.09.15
  • 발행 : 2010.09.30

초록

석탄가스화는 청정석탄이용기술의 한 분야로 최근 국제 유가의 급격한 변동과 더불어 매우 각광을 받고 있는 기술이다. 본 연구에서는 중국 내몽고 지역의 저급석탄을 출발물질로 가스화를 위한 광학적 특성, X선 분광특성, X선 회절특성, 광물학적 특성, 건조특성 등을 분석하였다. 분석결과 석탄의 등급은 slagging성과 fouling성이 매우 낮으며 착화온도가 $250^{\circ}C$ 정도인 brown coal인 것으로 조사되었고, 석영, 능철석, 점토광물 등이 주요 불순물로 혼재하는 것을 알 수 있었다. 또한 초기 수분이 28%로 매우 높기 때문에 이를 쉽게 건조하기 위한 방법으로 열풍건조와 마이크로웨이브 건조기술을 적용하여 비교한 결과, 마이크로웨이브를 이용한 건조가 좀 더 효과적인 것을 알 수 있었다.

Coal gasification technology in the sector of domestic clean coal technologies is being into the limelight since recent dramatic rise of international oil price. In this study, we used a low rank coal from Inner Mongolia, China as a starting material for gasification. Various properties including optical, mineralogical, X-ray spectroscopic, X-ray diffraction, and drying property were measured and tested in order to estimate the suitability of the coal to gasification. The coal was identified as a brown coal of lignite group from the measurement of vitrinite reflectance. The coal has very low slagging and fouling potentials, and the ignition temperature is about $250^{\circ}C$. The major impurities consist of quartz, siderite, and clay minerals. Additionally, the coal had moisture content above 28%. Tests for finding effective drying method showed that the microwave drying is more effective than thermal drying.

키워드

참고문헌

  1. 박종력, 김병곤, 전호석, 최홍일 (2010) 청정석탄개발 및 활용기술에 대한 특허정보 분석. 한국지구시스템공학회지, 47, 214-221.
  2. 이강봉 (2009) 석탄은 과연 석유를 대체할 수 있는가. 사이언스타임즈, http://www.sciencetimes.co.kr/article.do?atidx=0000030118, 2월 11일.
  3. 한국에너지기술평가원 (2009) 녹색성장 실현을 위한 R&D 이정표: 그린에너지 전략로드맵, 3-15.
  4. Annual Book of ASTM Standards (1994) Vol.5.05 Gaseous Fuels; Coal and Coke. ASTM 1916, Race Street, Philadelphia, PA 19103-1187, USA.
  5. Attig, R.C. and Duzy, A.F. (1969) Coal ash depositional studies and application to boiler design. Amer. Power Conf., Chicago, Ill. Illinois Institute of Technology.
  6. Barnard, J.A. and Harwood, B.A. (1974) Physical factors in the study of the spontaneous ignition of hydrocarbons in static systems. Combustion and Flame, 22, 35-42. https://doi.org/10.1016/0010-2180(74)90007-8
  7. Caron, M., Goethals, M., De Smedt, G., Berghmans, J., Vliegen, S., Van't Oost, E., and van den Aarssen, A. (1999) Pressure dependence of the auto-ignition temperature of methane/air mixtures. Journal of Hazardous Materials, 65, 233-244. https://doi.org/10.1016/S0304-3894(99)00004-7
  8. Du, G., Zhuang, X., Querol, X., Izquierdo, M., Alastuey, A., Moreno, T., and Font, O. (2009) Ge distribution in the Wulantuga high-germanium coal deposit in the Shengli Coalfield, Inner Mongolia, Northeastern China. International Journal of Coal Geology, 78, 16-26. https://doi.org/10.1016/j.coal.2008.10.004
  9. Gentzis, T. and Goodarzi, F. (1994) Reflectance suppression in some cretaceous coals from Alberta, Canada. In: Mukhopadhyay, P.K. and Dow, W.G. (eds.), Vitrinite Reflectance as a Maturity Parameter: Applications and Limitations. American Chemical Society Symposium Series, 570, 93-110.
  10. Godley, P.F. and Joseph, L. (1994) Clean coal technology program: model for goverment/industry cooperation. Energy Lay Journal, 1, 439-461.
  11. Goodarzi, F. (1987) Comparison of reflectance data from various macerals from sub-bituminous coals. Journal of Petroleum Geology, 10, 219-226. https://doi.org/10.1111/j.1747-5457.1987.tb00211.x
  12. Gurba, L.W. and Ward, C.R. (1998) Vitrinite reflectance anomalies in the high-volatile bituminous coals of the Gunnedah Basin, New South Wales, Australia. International Journal of Coal Geology, 36, 111-140. https://doi.org/10.1016/S0166-5162(97)00033-5
  13. International Energy Agency (2004) World Energy Outlook. OECD & IEA, Paris.
  14. ISO 7404-5:1984 (1984) Methods for the Petrographic Analysis of Coals, Part 5: Method of Determining Microscopically the Reflectance of Vitrinite. International Organization for Standardization-ISO, Geneva, 11.
  15. Japan Coal Energy Center (2007) Clean Coal Technologies in Japan: Technology Innovation in the Coal Industry. JCOAL, Tokyo, Japan.
  16. Khorasani, G.K. and Michelsen, J.K. (1994) The effects of overpressure, lithology, chemistry and heating rate on vitrinite reflectance evolution, and its relationship with oil generation. Australian Petroleum Exploration Association Journal, 34, 418-435.
  17. Ladislaw, S., Zyla, K., Pershing, J., Verrastro, F., Goodward, J., and Staley, B. (2009) A Roadmap for Secure, Low-carbon Energy Economy. World Resources Institute and Center for Strategic & International Studies, Washington, D.C., USA.
  18. Marland, S., Han, B., Merchant, A., and Rowson, N. (2000) The effect of microwave radiation on coal grindability. Fuel, 79, 1283-1288. https://doi.org/10.1016/S0016-2361(99)00285-9
  19. Morsy, M.H., Ko, Y.S., and Chung, S.H. (1999) Laser-induced ignition using a conical cavity in CH4-air mixtures. Combustion and Flame, 119, 473-482. https://doi.org/10.1016/S0010-2180(99)00060-7
  20. Mukhopadhyay, P.K. and Dow, W.G. (1994). Vitrinite reflectance as a maturity parameter: applications and limitations. American Chemical Society Symposium Series 570, 294.
  21. Price, L.C. and Barker, C.E. (1985) Suppression of vitrinite reflectance in amorphous rich kerogen: a major unrecognised problem. Journal of Petroleum Geology, 8, 59-84. https://doi.org/10.1111/j.1747-5457.1985.tb00191.x
  22. Reid, W.T. and Cohen, P. (1994) The flow characteristics of coal ash slags in the solidification range. Jour. Eng. Power, Trans. ASME Series A, 66, 83.
  23. Richard, J.R., Delbourgo, R., and Laffitte, P. (1964) Spontaneous ignition and combustion of sodium droplets in various oxidizing atmospheres at atmospheric pressure. Symposium (International) on Combustion, 12, 39-48.
  24. Seefeldt, F., Wunsch, M., and Schlesinger, M. (2007) The Future Role of Coal in Europe. EUROCOAL, Berlin & Basel, Germany.
  25. Suarez-Ruiz, I. and Crelling, J. (1975) Applied Coal Petrology: The Role of Petrology in Coal Utilization. Academic Press, New York, USA, 20-36.
  26. Teichmuller, M. (1987) Recent advances in coalification studies and their application to geology. In: Scott, A.C. (ed.), Coal and Coal-Bearing Strata - Recent Advances. Geological Society Special Publication, 32, 127-169.
  27. Winegartner, E.C. (ed.) (1974) Coal Fouling and Slagging Parameters. ASME research Committee on Corrosion and Deposits from Combustion Gases, ASME Pub.
  28. Zhuang, X, Querol, X., Alastuey, A., Juan, R., Plana, F., Lopez-Soler, A., Du, G., and Martynov, V.V. (2006) Geochemistry and mineralogy of the Cretaceous Wulantuga high-germanium coal deposit in Shengli Coal Field, Inner Mongolia, Northeastern China. International Journal of Coal Geology, 66, 119-136. https://doi.org/10.1016/j.coal.2005.06.005