전기화학회지 (Journal of the Korean Electrochemical Society)

  • 제13권3호
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  • Pages.181-185
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  • 2010
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  • 1229-1935(pISSN)
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  • 2288-9000(eISSN)
한국전기화학회 (The Korean Electrochemical Society)
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폴리아닐린-이온성 액체 복합체의 물리적전기화학적 특성

Physical and Electrochemical Properties of Polyaniline-Ionic Liquid Composite

  • Bang, Joo-Yong (Probiond Co., Ltd.) ;
  • Jeong, Woo-Sung (Probiond Co., Ltd.) ;
  • Park, Hyung-Soon (Probiond Co., Ltd.) ;
  • Chung, Kyung-Ho (Department of Advanced Applied Science & Department of Advanced Technology Fusion, Konkuk University) ;
  • Nath, Narayan Chandra Deb (Department of Advanced Applied Science & Department of Advanced Technology Fusion, Konkuk University) ;
  • Lee, Jae-Joon (Department of Advanced Applied Science & Department of Advanced Technology Fusion, Konkuk University) ;
  • Cha, Eun-Hee (Research Center for Convergence Technology, Hoseo University) ;
  • Lee, Jae-Kwan (Research Center for Convergence Technology, Hoseo University)
  • 투고 : 2010.07.14
  • 심사 : 2010.07.29
  • 발행 : 2010.08.28
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초록

전도성 고분자로 널리 알려진 폴리아닐린과 액체전해질의 핵심 재료인 이온성 액체와의 복합체를 형성시키고 이들의 물리적, 전기화학적인 특성을 조사되었다. 이미다졸늄 이온성 액체 (1-methyl-3-propylimidazolium iodide, PMI-I)에 비전도성 폴리아닐린 (Emeraldine Base)을 30 wt%이상 첨가하였을 때 준고형화 현상이 나타났고, 이온성 액체의 이미다졸늄 양이온의 방향족 고리와 폴리아닐린의 벤족기와의 ${\pi}-{\pi}$ 자기상호조립에 의한 약한 도핑작용을 통해 섬유상 구조를 나타내었으며, 전도도의 변화율은 80%이상 유지하였다.

Polyaniline-ionic liquid composite was prepared and investigated its physical and electrochemical properties. The quasi-solidification was presented in imidazolium-based ionic liquid (1-methly-3-propylimidazolium iodide, PMI-I) containing above 30 wt% of polyaniline (emeraldine base), which exhibited around 80% decrease of conductivity compared to pristine ionic liquid, resulting in fibril structure trough ${\pi}-{\pi}$ self-assembled of imidazolium aromatic ring of ionic liquid on polyaniline framework.

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참고문헌

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