전기학회논문지 (The Transactions of The Korean Institute of Electrical Engineers)

  • 제59권9호
  • /
  • Pages.1626-1631
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  • 2010
  • /
  • 1975-8359(pISSN)
  • /
  • 2287-4364(eISSN)
대한전기학회 (The Korean Institute of Electrical Engineers)
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구리/NaCl 전해질/아연 전기화학전지의 전류특성

Current characteristics of Cu/NaCl electrolyte/Zn electrochemical cell

  • 투고 : 2010.06.30
  • 심사 : 2010.08.24
  • 발행 : 2010.09.01
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초록

The characteristics of electric current for the voltaic cell are important for electric power applications. In this paper, an electrical equivalent model consist of three resisters and a capacitance for the Cu/NaCl solution/Zn electrochemical cell is proposed. The capacitance which exists in the Zn electrode/electrolytic interface increased according to Zn electrode area, but cannot affect almost in electric current. Complex impedance plot was used to analysis the interface effect for Zn/electrolyte. This result shows that the interface is similar with the electric transmission line. The short current measurements were conducted to investigate the effects of hydrogen peroxide, the watery sulfuric acid and NaCl aqueous solution. As the hydrogen peroxide increased, the electric current increased because the hydrogen gas being converted with the water. Also electric current increased significantly with increase of the hydrogen ion with the watery sulfuric acid and increased with increase of $Na^+$ ion and $Cl^-$ion in the NaCl electrolyte.

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참고문헌

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