Study on 1,200 N-class bipropellant rocket engine using decomposed $H_2O_2$ and kerosene

분해된 과산화수소와 케로신을 이용한 1,200 N 급 이원추진제 로켓 엔진의 연구

  • 조성권 (KAIST 항공우주공학과) ;
  • 안성용 (한국원자력안전기술원 신형로평가실) ;
  • 김종학 ((주)스페이스솔루션 개발팀) ;
  • 윤호성 ((주)스페이스솔루션 개발팀) ;
  • 권세진 (KAIST 항공우주공학과)
  • Received : 2010.05.31
  • Accepted : 2010.10.05
  • Published : 2010.12.30

Abstract

As part of preliminary study for development of 1,200 N-class bipropellant rocket engine with the concentrated hydrogen peroxide, bipropellant engine elements were designed and experimentally tested. The catalysts of $MnO_2$ and $MnO_2$ added Pb as an additive were compared to achieve high decomposition performance and the catalytic reactor with $MnO_2$ added Pb was designed and its decomposition efficiency of 97.2% was achieved. The autoignition tests of kerosene by decomposed hydrogen peroxide were carried out under various equivalence ratios to ignite without additional ignition sources. Autoignition were achieved in all experimental conditions and $C^*$ efficiencies at each condition were at or above 90%. From the measured thrust results, the highest value was 830 N which is in corresponds with 1,035 N at vacuum level assuming $C^*$ efficiency equals $I_{sp}$ efficiency.

고농도 과산화수소를 이용하는 1,200 N 급 이원추진제 로켓 엔진 개발을 위한 선행 연구의 일환으로 이원추진제 엔진 요소를 설계하고 실험적으로 연구하였다. 공급된 과산화수소의 분해 성능을 비교하기 위해, $MnO_2$와 Pb가 첨가된 $MnO_2$ 촉매들에 대한 실험을 하였다. 실험결과를 바탕으로, 촉매 반응기를 설계하였으며, 97.2%의 분해 효율을 얻었다. 별도의 점화원이 없이 자연점화를 이용하기 위해, 다양한 당량비에 대해 자연점화 실험을 수행하였다. 모든 실험조건에서 자연 점화를 확인하였으며, $C^*$ 효율은 90% 혹은 그 이상을 보였다. 추력측정 결과, 가장 높은 추력은 830 N을 보였으며, $C^*$ 효율과 $I_{sp}$ 효율을 같다고 가정했을 때, 진공 추력 1,035 N으로 계산되었다.

Keywords

References

  1. M. Ventura, G. Garboden, "A Brief History of Concentrated Hydrogen Peroxide Uses," 35th AIAA/ASME/SAE/ASEE Joint Propulsion Conference & Exhibit, AIAA 1999-2739
  2. Andrews, D., Sunley, H., "The Gamma Rocket Engines for Black Knight," Journal of the British Interplanetary Society, Vol. 43, Jul. 1990, pp.301-310
  3. Ventura, M., Mullens, P., "The Use of Hydrogen Peroxide for Propulsion and Power," 35th AIAA/ASME/SAE/ASEE Joint Propulsion Conference & Exhibit, AIAA 1999-2880
  4. 임하영, 안성용, 권세진, "친환경추진제 "과산화수소"의 특성과 응용," 한국추진공학회춘계학술회의, 2006, pp.283-287
  5. 안성용, 권세진, "액체추력기 촉매베드 크기 결정을 위한 실험적 방법," 한국추진공학회지, 제12권, 제3호, 2008, pp.24-33
  6. 하성업, 권민찬, 서견수, 한상엽 "발사체 추진제로서 과산화수소의 과거와 미래전망," 한국항공우주학회지, 제37권, 제7호, 2009, pp.717-728 https://doi.org/10.5139/JKSAS.2009.37.7.717
  7. Coxhill, I., Richardson, G., and Sweeting, M., "An Investigation of a Low Cost HTP/Kerosene 40N Thruster for Small Satellites," AIAA Paper 2002-4155, July 2002
  8. 박근홍, 임하영, 권세진, "촉매 분해된 과산화수소 제트에 분사된 케로신의 자연발화 특성," 제14차 유도무기학술대회, 2007, pp.677-681
  9. Sisco, J. C., Austin, B. L., Mok, J. S., and Anderson, W. E., "Autoignition of Kerosene by Decomposed Hydrogen Peroxide in a Dump-Combustor Configuration," Journal of Propulsion and Power, Vol. 21, No. 3, 2005, pp.450-459 https://doi.org/10.2514/1.5287
  10. 조성권, 권세진, "분해된 과산화수소를 이용한 케로신의 자연점화특성 조사," 한국추진공학회 추계학술대회, 2008, pp.397-400
  11. Jo, S., Kwon, S., "An investigation for autoignition by spray jet injection of fuel in the $H_2O_2$/Kerosene bipropellant thruster," 9th Asia-Pacific Conference on Combustion, 2009
  12. Cong, Y., Zhang, T., Li, T., Sun, J., Wang, X., Ma, L., Liang, D., Lin, L., "Propulsive Performance of a Hypergolic $H_2O_2$/Kerosene Bipropellant," Journal of Propulsion and Power, Vol. 20, No. 1, 2004, pp.83-86 https://doi.org/10.2514/1.9189
  13. Wernimont, E. J., "Hydrogen Peroxide Catalyst Beds: Lighter and Better Than Liquid Injectors," 35th AIAA/ASME/SAE/ ASEE Joint Propulsion Conference & Exhibit, AIAA-2005-4455
  14. Hydrogen peroxide handbook, Air Force Rocket Propulsion Laboratory, AFRPL-TR-67-144, USA, 1967
  15. "Liquid Rocket Engine Injectors, NASA Space Vehicle Design Criteria (Chemical Propulsion)," NASA SP-8089, Mar. 1976
  16. An, S., and Kwon, S., "Scaling and Evaluation of $Pt/Al_2O_3$ Catalytic Reactor for Hydrogen Peroxide Monopropellant Thruster," Journal of Propulsion and Power, Vol. 25, No. 5, 2009, pp.1041-1045 https://doi.org/10.2514/1.40822
  17. 조성권, 권세진, "케로신/과산화수소 이원추진제 추력기에서 산화제의 재순환을 이용한 연료희박 조건에서의 자연점화," 한국연소학회 추계학술대회, 2009, pp.129-132
  18. 안성용, 박대종, 정승미, 권세진, "인젝터 방식 및 촉매 알갱이 크기에 따른 과산화수소 단일추진제 추력기의 응답 특성," 한국추진공학회지, 제13권, 제1호, 2009, pp.19-26
  19. An, S., Brahmi, R., Kappenstein, C., Kwon, S., "Transient Behavior of $H_2O_2$ Thruster: Effect of Injector Type and Ullage Volume," Journal of Propulsion and Power, Vol. 25, No. 6, 2009, pp.1357-1360 https://doi.org/10.2514/1.46731
  20. Tian, H., Zhang, T., Sun, X., Liang, D., Lin, L., "A Novel Mixed Metal Oxide Catalyst for the Decomposition of Hydrogen Peroxide," 2nd International Hyrogen Peroxide Propulsion Conference, 1999, pp.199-208
  21. 전학제, 서곤, 촉매개론, 제4판, 한림원, 2002
  22. Gordon, S., and McBride, B. J., "Computer Program for Calculation of Complex Chemical Equilibrium Compositions and Applications," NASA Reference Publication 1311, 1994