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Syntheses and Characterization of Co/Fe3O4 Nanocomposites by Polyol Process

  • Oh, Young-Woo (Department of Nano Engineering, Kyungnam University) ;
  • Go, Geun-Ho (Department of Nano Engineering, Kyungnam University) ;
  • Park, Moon-Su (Department of Nano Engineering, Kyungnam University)
  • 투고 : 2010.05.12
  • 심사 : 2010.06.14
  • 발행 : 2010.07.31

초록

Co, $Fe_3O_4$ and Co/$Fe_3O_4$ nanoparticles were synthesized by a polyol process in order to develop their new applications and improve chemical, magnetic properties. The synthesis involved a polyol process using Fe, Co acetylacetonate as precursors and 1-2 hexadecanediol as the polyol. The synthesized $Fe_3O_4$ and Co/$Fe_3O_4$ nanocomposite particles were monodispersed and self arrayed ranging in size of 8~10 and 10~25 nm, respectively. The Co nanoparticle has a crystallite size of 10~40 nm. The synthesized nanoparticles were characterized by their structural, morphological, compositional and magnetic properties using TEM-EDS, XRD, and PPMS techniques.

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참고문헌

  1. D. K. Lee, Y. H. Kim, X.-L. Zhang, and Y. S. Kang, “Preparation of Monodisperse Co and Fe Nanoparticle Using Precursor of $M^{2+}-oleate_{2}$ (M = Co, Fe),” Current Applied Physics, 6 [4] 786-90 (2006). https://doi.org/10.1016/j.cap.2005.04.040
  2. N. Matoussevitch, A. Gorschinski, W. Habicht, and Jens Bolle, “Surface Modification of Metallic Co Nanoparticles,” J. Magnetism and Magnetic Materials, 311 92-6 (2007). https://doi.org/10.1016/j.jmmm.2006.10.1203
  3. D.W. Elliott and W.X. Zhang, “Field Assessment of Nanoscale Bimetallic Particles for Groundwater Treatment,” Environ. Sci. Technol., 35 4922-26 (2001). https://doi.org/10.1021/es0108584
  4. I.M.L. Billas, A. Chatelain, and W.A. de Heer, “Magnetism From the Atom to the Bulk in Nickel, Cobalt and Iron Clusters,” Science, 265 1682-84 (1994). https://doi.org/10.1126/science.265.5179.1682
  5. S. Behrens, E. Dinjus, and E. Unger, in: “Encyclopedia of Nanoscience and Nanotechnology,” vol. 10, p. 381, H. S. Nalwa (Ed.), American Scientific Publ., Stevenson Ranch, CA, 2004.
  6. E. Katz and I. Willner, “Integrated Nanoparticle-Biomolecule Hybrid Systems: Synthesis, Properties, and Applications,” Angew. Chem. Int. Ed., 43 6042-108 (2004). https://doi.org/10.1002/anie.200400651
  7. H. Zeng, S. Sun, J. P. Liu, and Z.-R. Dai, “Exchange-coupled FePt Nanoparticle Assembly,”Applied Physics Letters, 80 [14] 2583 (2002). https://doi.org/10.1063/1.1467976
  8. N. S. Sobal and U. Ebels, “Synthesis of Core-Shell PtCo Nanocrystals,” J. Phys. Chem. B., 107 7351-54 (2003). https://doi.org/10.1021/jp034200j
  9. J.-S. Lee, E. V. Shevchenko, and D. V. Talapin, “Au-PbS Core-Shell Nanocrystals : Plasmonic Absorption Enhancement and Electrical Doping via Intra-particle Charge Transfer,” J. Am. Chem. Soc., 130 9673-75 (2008). https://doi.org/10.1021/ja802890f
  10. D. Nagao, M. Yokoyama, N. Yamauchi, H. Matsumoto, Y. Kobayashi, and M. Konno, “Synthesis of Highly Monodisperse Particles Composed of a Magnetic Core and Fluorescent Shell,” J. Am. Chem. Soc., 24 9804-08 (2008).
  11. S. Sun and H. Zeng, “Size-controlled Synthesis of Magnetic Nanoparticles,” J. Am. Chem. Soc., 124 8204-05 (2002). https://doi.org/10.1021/ja026501x
  12. Y. W. Oh and J. P. Liu, “Properties of Co-Ferrite Nanoparticles Synthesized by Thermal Decomposition Method,” J. Magnetics, 111 [3] 123-25 (2006).
  13. O. Y. Woo and J.P. Liu, “Properties of Co-Ferrite Nanoparticles Synthesized by Chemical Route,” Papers of Technical Meeting on Magnetics, IEE Japan, 5 [137] 63-6 (2005).
  14. D. J. Kim, H. Z. Liang, J. G. Ahn, J. R. Lee, and H. S. Chung, “Synthesis of Flake Ag Powder by Polyol Process,” Journal of Korean Powder Matallurgy Institute, 11 [6] 447 (2004).
  15. D. J. Kim, “Heterogeneous Nucleations in the Polyol Process for the Preparation of Fine Cobalt Particles,” Journal of the Korean Crystal Growth and Crystal Technology, 12 [2] 73-9 (2002).
  16. S. H. Sun, “Monodisperse $MFe_{2}O_{4}$ (M= Fe, Co, Mn) Nanoparticles,” J. Am. Chem. Soc., 126 273-79 (2004). https://doi.org/10.1021/ja0380852
  17. T.G. Kim, “Biological Crystallization of Self-Aligned Iron Oxide Nanoparticles,” IEEE Transactions on Nanobioscience, 5 [3] 210-13 (2006). https://doi.org/10.1109/TNB.2006.880834