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A study on the crystalline orientation and electric properties of sol-gel PZT thin film for piezoelectric sensors

졸겔 법으로 제조한 압전 센서용 PZT 박막의 결정 배향 및 전기적 특성 연구

  • Byun, Jin-Moo (Department of Advanced Materials Engineering, Korea Polytechnic University) ;
  • Lee, Ho-Nyun (Department of Advanced Materials Engineering, Korea Polytechnic University) ;
  • Lee, Hong-Kee (Heat Treatment & Plating Technology Service Center, Korea Institute of Industrial Technology) ;
  • Lee, Seong-Eui (Heat Treatment & Plating Technology Service Center, Korea Institute of Industrial Technology) ;
  • Lee, Hee-Chul (Department of Advanced Materials Engineering, Korea Polytechnic University)
  • 변진무 (한국산업기술대학교 신소재공학과) ;
  • 이호년 (한국생산기술연구원 열.표면기술지원센터) ;
  • 이홍기 (한국생산기술연구원 열.표면기술지원센터) ;
  • 이성의 (한국산업기술대학교 신소재공학과) ;
  • 이희철 (한국산업기술대학교 신소재공학과)
  • Received : 2009.12.16
  • Accepted : 2010.04.13
  • Published : 2010.05.31

Abstract

This study examined the dependency of crystalline orientation and electric properties of sol-gel PZT film on hydrolysis, a $PbTiO_3$ seed layer and a concentration of sol-gel solution. The PZT thin films were prepared by using 2-Methoxyethanol-based sol-gel method and spin-coating on Pt/Ti/$SiO_2$/Si substrates. The 1-${\mu}m$-thick PZT films were coated and then fired in a furnace by direct insert method. The highly (111) oriented PZT film of pure perovskite structure could be obtained. We could control the degree of orientation by various parameters such as hydrolysis, a $PbTiO_3$ seed layer and a concentration of sol-gel solution. The highest measured remanent polarization, dielectric constant and piezoelectric coefficient are $24.16\;{\mu}C/cm^2$, 2808, and 159 pC/N, respectively.

Keywords

References

  1. B. Morten, G. D. Cicco, and M. Prudenziati, “Resonant pressure sensor based on piezo-electric properties”, Sensor and Actuators A, vol. 31, pp. 153-158, 1992. https://doi.org/10.1016/0924-4247(92)80096-L
  2. K. Yao and W. Zhu, “Improved preparation procedure and properties for a multilayer piezoelectric thick-film actuator”, Sensors and Actuators A, vol. 71, pp. 139-143, 1998. https://doi.org/10.1016/S0924-4247(98)00162-9
  3. G.-S Chung, J.-M. Kim, S.-J. Yoon, S.-J. Jeong, and J.-S. Song, “MEMS & sensor systems; Design, fabrication and characteristics of a MCA valve”, J. Kor. Sensors. Soc., pp. 230-235, 2004.
  4. J.-H Lee and S,-Y Choi, “Bonding technology for PZT and connection board using a high frequency heating machine”, J. Kor. Sensors. Soc., pp. 89-94, 1998.
  5. G. A. Smolenskii and A. T. Agranovskaya, “Dielectric polarization of a number of complex compounds”, Soviet Phys. Solid state, vol. 1, no. 10, pp. 1429-1437, 1999.
  6. Y.-J Kim, Y,-C Lee, D,-H Kwon, and B,-K Shon, “Fabrication and characteristics of FET-type pressure sensor using piezoelectric PZT thin film”, J. Kor. Sensors. Soc., pp. 26-32, 2001.
  7. W.-J. Yoon, M.-Y. Lim, and K.-W. Koo, “Sensor materials & processes : the characteristics thin film made by sol - gel method”, J. Kor. Sensors. Soc., pp. 75-80, 1995.
  8. Piekarz, R. “Lead zirconate titanate(PZT) sol-gel thin film preparation, deposition and testing”, MD, ARL-02-02, 2002.
  9. P. Muralt, “Ferroelectric thin films for micro-sensors and actuators: a review”, J. Micromech. Micrieng, vol. 10, pp. 136-146, 2000. https://doi.org/10.1088/0960-1317/10/2/307
  10. J. Zeng, M. Zhang, L. Wang, and C. Lin, “Influence of lead titanate seed layer on orientation behaviour and ferroelectric characteristics of sol-gel detrived PZT thin films”, J. Phys.: Condens. Matter, vol. 11, pp. 1139-1146, 1999. https://doi.org/10.1088/0953-8984/11/4/021
  11. K. Ishikawa, K. Sakura, D. Fu, S. Yamada, H. Suzuki, and T. Hayashi, “Effect of $PbTiO_3$ seeding layer on the growth of sol-gel-derived $Pb(Zr_{0.53}Ti_{0.47})O_3$ thin film”, Jpn. J. Appl. Phys., vol. 37, pp. 5128-5131, 1998. https://doi.org/10.1143/JJAP.37.5128
  12. L. Wang, J. Yu, and Y. Wang, “Effect of excess Pb in $PbTiO_3$ precursors on ferroelectric and fatigue property of sol-gel derived $PbTiO_3/PbZr_{0.3}Ti_{0.7}O_3/PbTiO_3$ thin films”, J. Mater. Sci.: Mater Electron, vol. 19, pp. 1191-1196, 2008. https://doi.org/10.1007/s10854-007-9524-x
  13. G. Wen, J,-F. Li, X. Chu, Z. Gui, and L. Li, “Preparation of (100)- and (111)- Textured $Pb(Zr,Ti)O_3$ piezoelectric films and direct measurement of their piezoelectric constants”, Jpn. J. Appl. Phys. vol. 42, pp. 1459-1461, 2003. https://doi.org/10.1143/JJAP.42.L1459
  14. H.-C. Lee and W.-J. Lee, “Preparation and chracterization of $Pb(Zr,Ti)O_3$ films deposited on $Pt/RuO_2$ hybrid electrode for ferroelectric randon access memory devices”, Jpn. J. Appl. Phys. vol. 40, pp. 6566-6573, 2001. https://doi.org/10.1143/JJAP.40.6566

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