Analytical Science and Technology (분석과학)

The Korean Society of Analytical Sciences (한국분석과학회)
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Determination of polycyclic aromatic hydrocarbons in processed foods

가공식품 중 다환방향족탄화수소 분석

  • Hu, Soo-Jung (Food Safety Evaluation Department, National Institute of Food and Drug Safety Evaluation) ;
  • Jin, Sun-Hee (Food Safety Evaluation Department, National Institute of Food and Drug Safety Evaluation) ;
  • Lee, Kwang-Ho (Food Safety Evaluation Department, National Institute of Food and Drug Safety Evaluation) ;
  • Choi, Dong-Mi (Food Safety Evaluation Department, National Institute of Food and Drug Safety Evaluation)
  • 허수정 (식품의약품안전평가원 식품위해평가부) ;
  • 진선희 (식품의약품안전평가원 식품위해평가부) ;
  • 이광호 (식품의약품안전평가원 식품위해평가부) ;
  • 최동미 (식품의약품안전평가원 식품위해평가부)
  • Received : 2010.01.07
  • Accepted : 2010.03.02
  • Published : 2010.04.25
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Abstract

In this study, the following concentrations of some PAHs (Polycyclic Aromatic Hydrocarbons) were investigated; [benzo(a)anthracene, chrysene, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(a)pyrene, dibenzo(a,h)anthracene, benzo(g,h,i)perylene, indeno(1,2,3-c,d)pyrene] in processed foods (n=165) and cooked meats (n=45) and established the analytical method by characteristics of processed foods. The methodology involved extraction (alkali digestion, liquid-liquid extraction, microwave extraction), clean-up on Sep-Pak Florisil Cartridges and determination by HPLC/FLD (High Performance Liquid Chromatography/Fluorescence Detector). The recovery of overall method for 8 PAHs spiked into these products ranged from 92 to 103%. The mean level of detected foods was found to be benzo(b)fluoranthene $0.9\;{\mu}g/kg$ in smoked salmon, benzo(b)fluoranthene $1.0\;{\mu}g/kg$, benzo(k)fluoranthene $0.3\;{\mu}g/kg$, benzo(a)pyrene $0.9\;{\mu}g/kg$ in dried banana, benzo(b)fluoranthene $0.2\;{\mu}g/kg$, benzo(k)fluoranthene $0.1\;{\mu}g/kg$, benzo(a)pyrene $0.2\;{\mu}g/kg$ in smoked chicken, benzo(b)fluoranthene $1.3\;{\mu}g/kg$, benzo(k)fluoranthene $0.3\;{\mu}g/kg$, benzo(a)pyrene $0.9\;{\mu}g/kg$ in charcoal grilled pork, respectively.

가공식품의 특성에 따른 PAHs (Polycyclic Aromatic Hydrocarbons, 다환방향족탄화수소) 분석방법 확립 및 실태 파악을 위하여 가공식품 24종 165건 및 조리육류 6종 45건 총 210건을 분석하였다. 가공식품의 특성에 따라 식육 어육가공품, 유가공품, 조리육류 등은 알칼리분해방법, 음료류는 액-액 추출방법, 견과류가공품, 과채가공품은 초음파 추출방법으로 추출하고 Sep-Pak Florisil Cartridge로 정제하여 HPLC/FLD (High Performance Liquid Chromatography/Fluorescence Detector)로 동시 정량 분석하였다. 각각의 PAHs에 대한 회수율은 약 92~103%였고 검출한계는 PAH에 따라 차이가 있었으며 $0.1\sim1.0\;{\mu}g/kg$ 수준이었다. 대상식품 총 30종 중 26종에서 8종의 PAHs가 모두 불검출이었으며 검출된 식품 중 PAHs의 평균농도는 훈제연어에서 benzo(b)fluoranthene $0.9\;{\mu}g/kg$, 건바나나에서 benzo(b)fluoranthene $1.0\;{\mu}g/kg$, benzo(k)fluoranthene $0.3\;{\mu}g/kg$, benzo(a)pyrene $0.9\;{\mu}g/kg$, 훈제치킨에서 benzo(b)fluoranthene $0.2\;{\mu}g/kg$, benzo(k)fluoranthene $0.1\;{\mu}g/kg$, benzo(a)pyrene $0.2\;{\mu}g/kg$, 돼지고기 숯불석쇠구이에서 benzo(b)fluoranthene $1.3\;{\mu}g/kg$, benzo(k)fluoranthene $0.3\;{\mu}g/kg$, benzo(a)pyrene $0.9\;{\mu}g/kg$이었다.

Keywords

References

  1. Joint FAO/WHO Expert Committee on Food Additives(FECFA),ALINORM 08/31/41 APPENDI.
  2. C. Smith, T. Perfetti, M. Rumple, A. Rodgman, D. Doolittle, Food Chem. Toxicol., 38, 371-386(2000). https://doi.org/10.1016/S0278-6915(99)00156-8
  3. IARC Monographs on the evaluation of carcinogenic risks to humans, 92, 2006.
  4. Reports on tasks for scientific cooperation, Report of participating in Task 3.2.12 October 2004.
  5. W. D. Miller, Fleischwirtschaft, 71, 61-67(1991).
  6. P. Karl, E. Gertrud, Fleischwitschaft, 66, 1261-1268(1986).
  7. H. G. Kang, M. S. Lee, K. H. Lee, C. H. Kim, KOREAN J. Food SCI. ANI. RESOUR., 18(1), 42-49(1998).
  8. H. G. Kang, K. H. Lee, H. S. Hong, S. J. Park, C. H. Kim, KOREAN J. FOOD SCI. ANI. RESOUR., 18(3), 203-208(1998).
  9. 보건복지부, 제3기 국민건강영양조사, 2006.
  10. Commission. Directive 2005/10/EC of 4 February 2005.
  11. U.S. EPA, U.S. EPA Method TO-13A Polycyclic Aromatic Hydrocarbons, 1999.
  12. A. V. T. Silvia, F. T. Cecilia, Food Control, 18, 948-952(2007). https://doi.org/10.1016/j.foodcont.2006.05.012
  13. K. Noaya, W. Mitsuhiro, K. Naotaka, A. Syuzo, N. Kenichiro, Journal of Chromatography B, 789, 257-264(2003). https://doi.org/10.1016/S1570-0232(03)00066-7
  14. L. Daohui, J. Youying, Z. Lizhong, Food and Chemical Toxicology, 43, 41-48(2005). https://doi.org/10.1016/j.fct.2004.08.010
  15. H. P. David, Mutation Research, 443, 139-149(1999). https://doi.org/10.1016/S1383-5742(99)00016-2
  16. Report on for scientific cooperation, Report of experts participating in Task 3.2.12, October 2004.

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