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Investigation of pollution level for PFOA and PFOS in ambient air using LC/MS/MS

LC/MS/MS를 이용한 대기 중 PFOA 및 PFOS의 오염 수준 조사

  • Kim, Kyoung-Soo (Department of Environmental Engineering, Chonbuk National University) ;
  • Shin, Park-Min (Division of Mass Spectrometry, Korea Basic Science Institute) ;
  • Yeon, Jin-Mo (Chemical Behavior Research Division, National Institute of Environmental Research) ;
  • Ka, Jae-Jong (Department of Environmental Engineering, Cheongju University) ;
  • Kim, Yong-Jun (Department of Environmental Engineering, Cheongju University) ;
  • Cho, Chon-Rae (Risk Assessment Division, National Institute of Environmental Research)
  • 김경수 (전북대학교 환경공학과) ;
  • 신박민 (한국기초과학지원연구원 질량분석연구부) ;
  • 연진모 (국립환경과학원 화학물질거동연구과) ;
  • 가재정 (청주대학교 환경공학과) ;
  • 김용준 (청주대학교 환경공학과) ;
  • 조천래 (국립환경과학원 위해성평가과)
  • Received : 2009.09.28
  • Accepted : 2009.12.25
  • Published : 2010.02.25

Abstract

To investigate pollution level of PFOA and PFOS in ambient air, Cheongju city, gaseous and particulate samples were collected at industrial, residential/commercial, and rural region, respectively. Samples were collected in winter, spring, and summer season in order to examine seasonal variation of PFOA and PFOS. The concentration range of PFOA and PFOS was presented as N.D.~8.02 pg/$m^3$ with an average of 2.33 pg/$m^3$, 1.68~6.94 pg/$m^3$ with an average of 3.12 pg/$m^3$. These levels were lower than or similar to those of other countries.

본 연구에서 청주지역 대기 중 PFOA 및 PFOS의 오염수준을 조사하기 위해 공단, 주거/상업 및 농촌지역에서 각각 가스상 및 입자상 시료를 채취하였다. 또한 계절적 변화를 조사하기 위해 겨울철, 봄철 및 여름철에 각각 채취하였다. 대기 중 PFOA 및 PFOS의 농도는 각각 불검출~8.02 pg/$m^3$ (평균 2.33 pg/$m^3$)과 1.68~6.94 pg/$m^3$ (평균 3.12 pg/$m^3$)으로 검출되었다. 이들 농도는 외국과 유사하거나 낮은 수준을 보였다.

Keywords

References

  1. 3M, "Environmental and health assessment of perfluorooctane sulfonic acid and its salt", prepared by 3M company, 2003.
  2. C. Caliebe, W. Gerwinski, H. Huhnerfuss and N. Theobald, Organohalogen Compounds, 66, 4074-4078(2004).
  3. K. Kannan, J. Koistinen, K. Beckmen, T. Evans, J. F. Gorzelany, K. J. Hansen, P. D. Jones, E. Helle, M. Nyman, and J. P. Giesy, Environ. Sci. Technol., 35(8), 1593-1598(2001). https://doi.org/10.1021/es001873w
  4. G. M. Rusch, W. E. Rinehart, and C. A. Bozak, Acute inhalation toxicity study of T-2306 CoC in the rat. project no. 78-7185, Bio/dynainics Inc., 1979.
  5. F. D. Gilliland, and J. S. Mandel, American jeournal of industrial medicine, 29(5), 560-568(1996). https://doi.org/10.1002/(SICI)1097-0274(199605)29:5<560::AID-AJIM17>3.0.CO;2-Z
  6. W. P. Dean, D. C. Jessup, G. Thompson, G. Romig, D. Powell, Fluorad fluorochemical surfactant FC-95 acute oral toxicity (LD50) study in rats. Study no. 137-083. International Research and Development Cooperation, 1978.
  7. 3M, "Screening studies in the aqueous photolytic degradation of perfluotooctanoic acid", USEPA administrative record AR226-1030 photolysis E00-2192, 2001.
  8. J. P. Giesy and K. Kannan, Environ. Sci. Technol., 35, 1339-1342(2001). https://doi.org/10.1021/es001834k
  9. N. Yamashita, K. Kannan, S. Taniyasu, Y. Horii, G. Petrick and T. Gamo, Mar. Pollut. Bull., 51, 658-668(2005). https://doi.org/10.1016/j.marpolbul.2005.04.026
  10. A. Janke, U. Berger, R. Ebinghaus, and C. Temme, Environ. Sci. Technol., 41(9), 3055-3061(2007). https://doi.org/10.1021/es062389h
  11. C. J. Young, VI. Furdui, J. Franklin, R. Koerner, D. C. G. Muir, and S. A. Mabury, Environ. Sci. Technol., 41(10), 3455-3461(2007). https://doi.org/10.1021/es0626234
  12. 신미연, 손현석, 조경덕, 대한환경공학회 추계학술연구발표회 논문집, 대한환경공학회, 1187-1194(2007).
  13. 정재연, 윤해승, 류희영, 원종욱, 팽기정, 김연제, 분석과학, 21(3), 183-190(2008).
  14. 岩手環境保健究センタ, 化學物質と環境 平成15年 化學物質分析法開發調査報告書, 2004.
  15. S. K. Kim and K. Kannan, Environ. Sci. Technol., 41(24), 8328-8334(2007). https://doi.org/10.1021/es072107t
  16. M. Shoeib, T. Harner, B. H. Wilford, K. C. Jones, and J. Zhu, Environ. Sci. Technol., 39(17), 6599-6606(2005). https://doi.org/10.1021/es048340y
  17. C. P. Higgins, J. A. Field, C. S. Criddle, and R. G. Luthy, Environ. Sci. Technol., 39(11), 3946-3956(2005). https://doi.org/10.1021/es048245p
  18. K. Harada, S. Nakanishi, N. Saito, T. Tsutsui, and A. Koizumi, Bull. Environ. Contam. Toxicol., 74, 64-69(2005). https://doi.org/10.1007/s00128-004-0548-0
  19. K. Sasaki, T. Yoshida, K. Ozawa, N. Saito, Y. Jin, A. Koizumi, China-Japan joint symposium on environmental chemistry, Beijing, 2004.
  20. A. Dreyer and R. Ebinghaus, Atmospheric Environment, 43, 1527-1535(2009). https://doi.org/10.1016/j.atmosenv.2008.11.047