Korean Journal of Soil Science and Fertilizer (한국토양비료학회지)

Korean Society of Soil Science and Fertilizer (한국토양비료학회)
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Monitoring of Heavy Metal Contents from Paddy Soil in Gyeongnam Province

경남지역 논 토양 중금속 함량 변동조사

  • Lee, Young-Han (Gyeongsangnam-do Agricultural Research and Extension Services) ;
  • Lee, Seong-Tae (Gyeongsangnam-do Agricultural Research and Extension Services) ;
  • Heo, Jae-Young (Gyeongsangnam-do Agricultural Research and Extension Services) ;
  • Kim, Min-Geun (Gyeongsangnam-do Agricultural Research and Extension Services) ;
  • Hong, Kang-Pyo (Gyeongsangnam-do Agricultural Research and Extension Services) ;
  • Kim, Eun-Seok (Gyeongsangnam-do Agricultural Research and Extension Services) ;
  • Song, Won-Doo (Gyeongsangnam-do Agricultural Research and Extension Services) ;
  • Rho, Chi-Woong (Gyeongsangnam-do Agricultural Research and Extension Services) ;
  • Lee, Jin-Ho (Department of Bioenvironmental Chemistry, College of Agricultural and Life Sciences, Chonbuk National University) ;
  • Jeon, Weon-Tai (National Institute of Crop Science, RDA) ;
  • Ko, Byong-Gu (National Academy of Agricultural Science, RDA) ;
  • Roh, Kee-An (National Academy of Agricultural Science, RDA) ;
  • Ha, Sang-Keun (National Academy of Agricultural Science, RDA)
  • Received : 2010.05.19
  • Accepted : 2010.06.08
  • Published : 2010.06.30
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Abstract

Monitoring of the heavy metals at paddy rice agriculture is very important for environmental agriculture. A study was carried out of heavy metal concentrations in 260 paddy soil samples every four years from 1999 to 2007 in Gyeongnam Province. Heavy metals such as Cd, Cr, Cu, Ni, Pb, Zn, and As in paddy soils were analyzed. Average concentrations of heavy metal were Cd 0.426 (ranged 0.003-1.379) mg $kg^{-1}$ for Cd, 1.189 (0.003-3.264) mg $kg^{-1}$, for Cr, 9.68 (0.05-22.38) mg $kg^{-1}$ for Cu, 2.64 (0.01-7.36) mg $kg^{-1}$ for Ni, 23.7 (0.7-54.1) mg $kg^{-1}$ for Pb, 20.8 (0.7-131.2) mg $kg^{-1}$ for Zn, and 1.054 (0.001-2.110) mg $kg^{-1}$ for As, respectively. Long-term changes of heavy metals were showed that Cd, Ni, and Zn were significantly increased whereas Cr, Cu, and As were significantly decreased. Principle component analysis (PCA) of heavy metals in paddy soils was obtained with eigenvalues > 1 summing 34.3% of variance for PC1, 17.5% of variance for PC2, and 51.8% of the total variance in soil heavy metals.

경남지역 논 토양의 중금속 관리를 위한 기초 자료를 제공하고자 260 지점을 대상으로 1999년부터 2007년까지 4년 주기로 분석하였다. 논 토양의 중금속 평균 함량은 Cd 0.426 (범위 0.003-1.379) mg $kg^{-1}$, Cr 1.189 (0.003-3.264) mg $kg^{-1}$, Cu 9.68 (0.05-22.38) mg $kg^{-1}$, Ni 2.64 (0.01-7.36) mg $kg^{-1}$, Pb 23.7 (0.7-54.1) mg $kg^{-1}$, Zn 20.8 (0.7-131.2) mg $kg^{-1}$, As 1.054 (0.001-2.110) mg $kg^{-1}$ 였다. 장기적인 변동조사 결과 경남지역 논 토양의 Cd, Ni 및 Zn 함량은 유의적으로 증가한 반면, Cr, Cu 및 As 함량은 유의적으로 감소하였고 Pb 함량은 큰 변화가 없었다. 논 토양 As 함량은 Cu 및 Pb와 고도로 유의적인 정의상관을 보인 반면, Cr 및 Ni 함량과는 유의적인 부의상관을 나타냈다. 경남지역 논 토양 중금속의 주성분 분석결과 고유값이 1.0 이상인 주성분은 3개였고 제 1주성분 (PC1)에 속하는 토양 중금속은 Cd (0.550), Ni (0.490), Zn (0.452) 및 Pb (0.422) 등 4개였으며 제 2주성분 (PC2)에 속하는 토양 중금속은 As (0.760) 및 Cr (-0.375)등 2개였고 제 3주성분 (PC3)에 속하는 토양 중금속은 Cu (0.740) 였다. 논 토양 중금속 함량의 특성은 제 1주성분이 34.3%, 제 2주성분이 17.5%로서 전체 51.8%의 자료를 설명할 수 있는 것으로 나타났다.

Keywords

References

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