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The Lubricity of Biodiesel as Alternative Fuel

대체연료로서 바이오디젤의 윤활성

  • Lim, Young-Kwan (Research Center, Korea Institute of Petroleum Management) ;
  • Lee, Cheon-Ho (Research Center, Korea Institute of Petroleum Management)
  • 임영관 (한국석유관리원 연구센터) ;
  • 이천호 (한국석유관리원 연구센터)
  • Received : 2009.10.06
  • Accepted : 2009.12.25
  • Published : 2010.02.28

Abstract

Biodiesel have been studied as alternative fuel due to solution of air pollution and fossil fuel exhaustion. Biodiesel from animal fat and vegetable oil was known as eco-friendly fuel like low toxicity, biodegradable compare to petrodiesel. In particular, biodiesel have excellent lubricity due to involved ester functional group. This paper shows the biodiesel's lubricity based on worldwide biodiesel research.

Keywords

References

  1. http://www.geni.org/globalenergy/policy/renewableenergy/index.shtml.
  2. Omer, A. M., "Energy, Environment and Sustainable Development," Renewable and Sustainable Energy Reviews, Vol. 12, pp. 2265-2300, 2008. https://doi.org/10.1016/j.rser.2007.05.001
  3. Garcia, G. O., Groiset, E., Douglas, P., Elkamel, A. and Gupta, M., "Modeling the Energy Demands and Greenhouse Gas Emissions of the Canadian Oil Sands Industry," Energy & Fuel, Vol. 21, No. 4, pp. 2098-2111, 2007. https://doi.org/10.1021/ef0700984
  4. Antoni, D., Zverlow, V. V. and Schwarz, W. H., "Biofuels from Microbes," Applied Microbiology and Biotechnology, Vol. 77, pp. 23-55, 2007. https://doi.org/10.1007/s00253-007-1163-x
  5. Bari, I. D., Nanna, F. and Braccino, G., "$SO_{2}-Catalyzed$ Steam Fractionation of Aspen Chips for Bioethanol Production: Optimization of the Catalyst Impregnation," Ind. Eng. Chem. Res., Vol. 44, No. 14, pp. 5353-5363, 2005. https://doi.org/10.1021/ie049157g
  6. Balat, M., Balat, H. and Oz, C., "Progress in Bioethanol Processing," Prog. Energy and Combust. Sci., Vol. 34, No. 6, pp. 551-573, 2008. https://doi.org/10.1016/j.pecs.2007.11.001
  7. Stang, G. D., Macdonald, D. G. and Hill, G. A., "Mass Transfer and Bioethanol Production in an External-Loop Liquid-Lift Bioreactor," Ind. Eng. Chem. Res., Vol. 40, No. 23, pp. 5074-5080, 2001. https://doi.org/10.1021/ie000990x
  8. Cohron, M., Zhao, H., Liu, H and Pan, W., "Synthesis Gas Production with an Adjustable H2/CO Ratio through the Coal Gasfication Process: Effects of Coal Ranks and Methane Addition," Energy & Fuels, Vol. 22, No. 3, pp. 1720-1730, 2008. https://doi.org/10.1021/ef7005707
  9. Koo, K. Y., Roh, H.-S., Seo, Y. T., Seo, D. J., Yoon, W. L. and Park, S. B., "Coke Study on MgO-promoted $Ni/Al_{2}O_{3}$ Catalyst in Combined $H_{2}O$ and $CO_{2}$ Reforming of Methane for Gas to Liquid (GTL) Progress," Applied Catalysis A: General, Vol. 340, No. 2, pp. 183-190, 2008. https://doi.org/10.1016/j.apcata.2008.02.009
  10. Koo, K. Y., Roh, H.-S., Seo, Y. T., Seo, D. J., Yoon, W. L. and Park, S. B., "A-High Effective and Stable Nano-Sized $Ni/MgO-Al_{2}O_{3}$ Catalyst for Gas to Liquids (GTL) Process," Int. J. Hydrogen Energy, Vol. 33, No. 8, pp. 2036-2043, 2008. https://doi.org/10.1016/j.ijhydene.2008.02.029
  11. Holm-Nielsen, J. B., Seadi, T. Al. and Oleskowicz- Popiel, P., "The Future of Anaerobic Digestion and Biogas Utilization," Bioresource Technology, Vol. 100, No. 22, pp. 5478-5484, 2009. https://doi.org/10.1016/j.biortech.2008.12.046
  12. Yeom, K. and Bae, C. S., "Knock Characteristics in Liquefied Petroleum Gas (LPG)-Dimethyl Ether (DME) and Gasoline-DME Homogeneous Charge Compression Ignition Engine," Energy & Fuels, Vol. 23, No. 4, pp. 1596-1964, 2009.
  13. Ying, W., Genbao, L., Wei, Z. and Longbao, Z., "Study on the Application of DME/Diesel Blends in a Diesel Engine," Fuel Processing Technology, Vol. 89, pp. 1272-1280, 2008. https://doi.org/10.1016/j.fuproc.2008.05.023
  14. Sivebaek, I. M. and Jakobsen, J., "The Viscosity of Dimethyl Ether," Tribology International, Vol. 40, pp. 652-658, 2007. https://doi.org/10.1016/j.triboint.2005.11.005
  15. Lim, Y. K., Shin, S. C., Kim, J. R., Yim, E. S., Song, H. O. and Kim, D. K., "Characteristic Analysis of GTL Fuel as an Automobile Diesel," J. Korean Ind. Eng. Chem., Vol. 19, No. 16, pp. 617-623, 2008.
  16. Danping, W. and Spikes, H. A., "The Lubricity of Diesel Fuels," Wear, Vol. 119, pp. 217-235, 1986.
  17. Lotero, E., Liu, Y., Lopez, D. E., Suwannakarn, K., Bruce, D. A. and Goodwin Jr, J. G., "Synthesis of Biodiesel Via Acid Catalysis", Ind. Eng. Chem. Res., Vol. 44, No. 14, pp. 5353-5363, 2005. https://doi.org/10.1021/ie049157g
  18. Lim, Y. K., Shin, S. C., Yim, Y. S. and Song, H. O., "The Effective Product Method of Biodiesel," J. Korean Ind. Eng. Chem., Vol. 19, No. 2, pp. 137-144, 2008.
  19. Lim, Y. K., Kim, D. K. and Yim, E. S., "Synthesis of Biodiesel from Vegetable Oil and Their Characteristics in Low Temperature," J. Korean Ind. Eng. Chem., Vol. 20, No. 2, pp. 208-212, 2009.
  20. Lim, Y. K., Jeon, C. H., Kim, S., Yim, E. S., Song, H. O., Shin, S. C. and Kim, D. K., "Determination of Fuel Properties for Blended Biodiesel from Various Vegetable Oil," Korean Chem. Eng. Res., Vol. 47, No. 2, pp. 237-242, 2009.
  21. Moser, B. R., Cermak, S. C. and Isbell, T. A., "Evaluation of Castor and Lesquerella Oil Derivatives as Additives in Biodiesel and Ultralow Sulfur Diesel Fuels," Energy & Fuels, Vol. 22, pp. 1349-1352, 2008. https://doi.org/10.1021/ef700628r
  22. Gryglewicz, S. and Oko, F. A., "Synthesis and Biosynthesis of Oligomeric Sebacates as Lubricant Oils," Ind. Eng. Chem. Res., Vol. 44, No. 6, pp. 1640-1644, 2005. https://doi.org/10.1021/ie049454l
  23. Lacey, P. I., "Wear with Low-lubricity Fuel II. Correlation between Wear maps and Pump Components," Wear, Vol. 160, No. 2, pp. 333-343, 1993. https://doi.org/10.1016/0043-1648(93)90438-R
  24. Cho, I. H., "Lubricity of Diesel," Transportation Fuels Technology, Vol. 27, No. 2, pp. 37-44, 2005.
  25. Lim, Y. K., Kim, D. K. and Yim, E. S., "The Study of Lubricity for Various Biodiesel using HFRR," Journal of the KSTLE, Vol. 25, No. 2, pp. 86-92, 2009.
  26. Drown, D. C., Harper, K. and Frame, E., "Screening Vegetable Oil Alcohol Esters as Fuel Lubricity Enhancers," Journal of American Oil Chemist's Society, Vol. 78, No. 6, pp. 579-584, 2001. https://doi.org/10.1007/s11746-001-0307-y
  27. Goodrum, J. W. and Geller, D. P., "Influence of Fatty Acid Methyl Esters from Hydroxylated Vegetable Oils on Diesel Fuel Lubricity," Bioresource Technology, Vol. 96, pp. 851-855, 2005 https://doi.org/10.1016/j.biortech.2004.07.006
  28. Bhatnagar, A. K., Kaul, S., Ghhibber, V. K. and Gupta, A. K., "HFRR Studies on Methyl Esters of Nonedible Vegetable Oils," Energy & Fuels, Vol. 20, No. 3, pp. 1341-1344, 2006. https://doi.org/10.1021/ef0503818
  29. Wadumesthrige, K., Ara, M., Salley, S. O. and Simon Ng, K. Y., "Investigation of Lubricity Characteristics of Biodiesel in Petroleum and Synthetic Fuel," Energy & Fuels, Vol. 23, No. 4, pp. 2229-2234, 2009. https://doi.org/10.1021/ef800887y
  30. Moser, B. R., "Influence of Blending Canola, Palm, Soybean, and Sunflower Oil Methyl Esters on Fuel Properties of Biodiesel," Energy & Fuels, Vol. 22, No. 6, pp. 4301-4306, 2008. https://doi.org/10.1021/ef800588x
  31. Suarez, P. A. Z., Moser, B. R., Sharma, B. K. and Erhan, S. Z., "Comparing the Lubricity of Biofuels Obtained from Pyrolysis and Alcoholysis of Soybean Oil and Their Blends with Petroleum Diesel," Fuel, Vol. 88, pp. 1143-1147, 2009. https://doi.org/10.1016/j.fuel.2008.11.017
  32. Hu, J., Du, Z., Li, C. and Min, E., "Study on the Lubrication Properties of Biodiesel as Fuel Lubricity Enhancers," Fuel, Vol. 84, pp. 1601-1606, 2005
  33. Kulkarni, M. G., Kalai, A. K. and Bakhshi, N. N., "Transesterificaiton of Canola Oil in Mixed Methanol/ Ethanol System and Used of Esters as Lubricity Additive," Bioresource Technology, Vol. 98, pp. 2027-2033, 2007. https://doi.org/10.1016/j.biortech.2006.08.025
  34. Knothe, G. and Steidley, K. R., "Lubricity of Components of Biodiesel and Petrodiesel. The Origin of Biodiesel Lubricity," Energy & Fuels, Vol. 19, No. 3, pp. 1192-1200, 2005. https://doi.org/10.1021/ef049684c
  35. Vizintin, J., Arnsek, A., and Plou, T., "Lubricating Properties of Rapeseed Oils Compared to Mineral Oils Under a High-Load Oscillating Movement," J. Synth. Lubr., Vol. 17, pp. 201-219, 2000. https://doi.org/10.1002/jsl.3000170304
  36. Fox, N. J., Tyrer, B. and Stachowiak, G. W., "Boundary Lubrication Performance of Free Fatty Acids in Sunflower Oil," Tribol. Lett., Vol. 16, No. 4, pp. 275-281, 1999.