Bulletin of the Korean Chemical Society

  • 제31권6호
  • /
  • Pages.1509-1514
  • /
  • 2010
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
DOI QR코드

DOI QR Code

Synthesis of Novel Y-type Nonlinear Optical Polyester with Enhanced Thermal Stability of Second Harmonic Generation for Electro-Optic Applications

  • Cho, You-Jin (Institute of Basic Science, Department of Chemistry, Inje University) ;
  • Lee, Ju-Suk (Institute of Basic Science, Department of Chemistry, Inje University) ;
  • Lee, Ju-Yeon (Institute of Basic Science, Department of Chemistry, Inje University)
  • 투고 : 2009.09.25
  • 심사 : 2010.04.14
  • 발행 : 2010.06.20
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Methyl 3,4-di-(2'-hydroxyethoxy)benzylidenecyanoacetate (3) was prepared and condensed with terephthaloyl chloride to yield novel Y-type polyester (4) containing 3,4-dioxybenzylidenecyanoacetate groups as NLO-chromophores, which constituted parts of the polymer main chains. The resulting polymer 4 is soluble in common organic solvents such as acetone and N,N-dimethylformamide. Polymer 4 shows thermal stability up to $280^{\circ}C$ in thermogravimetric analysis with glass-transition temperature obtained from differential scanning calorimetry near $105^{\circ}C$. The second harmonic generation (SHG) coefficient ($d_{33}$) of poled polymer films at the 1064 nm fundamental wavelength is around 2.42 pm/V. The dipole alignment exhibits high thermal stability up to near $T_g$, and there is no SHG decay below $100^{\circ}C$ due to the partial main-chain character of polymer structure, which is acceptable for NLO device applications.

키워드

참고문헌

  1. Marks, T. J.; Ratner, M. A. Angew. Chem. Int. Ed. Engl. 1995, 34, 155. https://doi.org/10.1002/anie.199501551
  2. Lee, C.; Park, S.-K.; Yang, M.; Lee, N.-S.; Kim, N. J. Bull. Korean Chem. Soc. 2007, 28, 447. https://doi.org/10.5012/bkcs.2007.28.3.447
  3. Lee, S. K.; Cho, M. J.; Jin, J.-I.; Choi, D. H. J. Polym. Sci. Part A: Polym. Chem. 2007, 45, 531. https://doi.org/10.1002/pola.21887
  4. Yoon, Z. S.; Easwaramoorthi, S.; Kim, D. Bull. Korean Chem. Soc. 2008, 29, 197. https://doi.org/10.5012/bkcs.2008.29.1.197
  5. Jin, F.-L.; Park, S.-J. Bull. Korean Chem. Soc. 2008, 29, 2521. https://doi.org/10.5012/bkcs.2008.29.12.2521
  6. Li, Z.; Dong, S.; Li, P.; Li, Z.; Ye, C; Qin, J. J. Polym. Sci. Part A: Polym. Chem. 2008, 46, 2983. https://doi.org/10.1002/pola.22634
  7. Han, K. S.; Park, S. K.; Shim, S. Y.; Jahng, W. S.; Kim, N. J. Bull. Korean Chem. Soc. 1998, 19, 1165.
  8. Cho, B. R.; Kim, Y. H.; Son, K. W.; Khalil, C.; Kim, Y. H.; Jeon, S.-J. Bull. Korean Chem. Soc. 2002, 23, 1253. https://doi.org/10.5012/bkcs.2002.23.9.1253
  9. Kim, T.-D.; Luo, J.; Tian, Y.; Ka, J.-W.; Tucker, N. M.; Haller, M.; Kang, J.-W.; Jen, A. K.-Y. Macromolecules 2001, 39, 1676. https://doi.org/10.1021/ma052087k
  10. Liu, Y.-L.; Hsieh, C.-Y. J. Polym. Sci. Part A: Polym. Chem. 2006, 44, 905. https://doi.org/10.1002/pola.21184
  11. Moon, J. R.; Kim, B. S.; Kim, J.-H. Bull. Korean Chem. Soc. 2006, 27, 981. https://doi.org/10.5012/bkcs.2006.27.7.981
  12. Chen, T.; Jen, A. K. Y.; Cai, Y. Macromolecules 1996, 29, 535. https://doi.org/10.1021/ma9512566
  13. Saadeh, H.; Gharavi, A.; Yu, D.; Yu, L. Macromolecules 1997, 30, 5403. https://doi.org/10.1021/ma970530o
  14. Tsutsumi, N.; Morishima, M.; Sakai, W. Macromolecules 1998, 31, 7764. https://doi.org/10.1021/ma9803436
  15. Liu, J.-G.; Nakamura, Y.; Shibasaki, Y.; Ando, S.; Ueda, M. J. Polym. Sci. Part A: Polym. Chem. 2007, 45, 5606. https://doi.org/10.1002/pola.22308
  16. Hoang, M, A.; Kim, M. H.; Cho, M. J.; Kim, K. H.; Kim, K. N.; Jin, J.-I.; Choi, D. H. J. Polym. Sci. Part A: Polym. Chem. 2008, 46, 5064. https://doi.org/10.1002/pola.22834
  17. Ryu, S.; Kim, J. H.; Lee, S. H.; Lee, M.-H. Bull. Korean Chem. Soc. 2008, 29, 1689. https://doi.org/10.5012/bkcs.2008.29.9.1689
  18. Lee, J.-H.; Lee, K.-S. Bull. Korean Chem. Soc. 2000, 21, 847.
  19. Lee, S.-H.; Kim, Y.-K.; Won, Y.-H. Macromolecules 1999, 32, 342. https://doi.org/10.1021/ma9807421
  20. Ambrosanio, P,; Centore, R.; Concilio, S.; Panunzi, B.; Sirigu, A.; Tirelli, N. Polymer 1999, 40, 4923. https://doi.org/10.1016/S0032-3861(98)00720-4
  21. Lee, J.-Y.; Jung, W.-T.; Lee, W.-J. Polym. Int. 2006, 55, 248. https://doi.org/10.1002/pi.1965
  22. Lee, J.-Y.; Kim, J.-H.; Jung, W.-T. Bull. Korean Chem. Soc. 2007, 28, 329. https://doi.org/10.5012/bkcs.2007.28.2.329
  23. Lee, J.-Y.; Kim, J.-H.; Won, D.-S.; Jang, H.-N. Bull. Korean Chem. Soc. 2007, 28, 1433. https://doi.org/10.5012/bkcs.2007.28.8.1433
  24. Walther, F.; Heckl, W. M.; Stark, R. W. Appl. Sur. Sci. 2008, 254, 7290. https://doi.org/10.1016/j.apsusc.2008.05.323
  25. Cisneros, J. I. Appl. Opt. 1998, 37, 5262. https://doi.org/10.1364/AO.37.005262
  26. Herman, W. N.; Hayden, L. M. J. Opt. Soc. Am. B 1995, 12, 416. https://doi.org/10.1364/JOSAB.12.000416

피인용 문헌

  1. Synthesis and Properties of Novel Y-type Nonlinear Optical Polyester Containing Dioxynitroazobenzene Group with Enhanced Thermal Stability of Dipole Alignment vol.32, pp.9, 2011, https://doi.org/10.5012/bkcs.2011.32.9.3361
  2. Synthesis and properties of novel nonlinear optical polyester containing carbomethoxycyanovinylnitrocatecholic group vol.659, pp.1, 2017, https://doi.org/10.1080/15421406.2018.1450931