Bulletin of the Korean Chemical Society

  • 제31권6호
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  • Pages.1489-1495
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  • 2010
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Microwave Synthesis of a Porous Metal-Organic Framework, Nickel(II) Dihydroxyterephthalate and its Catalytic Properties in Oxidation of Cyclohexene

  • Lee, Ji-Sun (Catalysis Center for Molecular Engineering (CCME), Korea Research Institute of Chemical Technology (KRICT)) ;
  • Halligudi, Shiva B. (Catalysis Center for Molecular Engineering (CCME), Korea Research Institute of Chemical Technology (KRICT)) ;
  • Jang, Nak-Han (Department of Chemistry Education, Kongju National University) ;
  • Hwang, Dong-Won (Catalysis Center for Molecular Engineering (CCME), Korea Research Institute of Chemical Technology (KRICT)) ;
  • Chang, Jong-San (Catalysis Center for Molecular Engineering (CCME), Korea Research Institute of Chemical Technology (KRICT)) ;
  • Hwang, Young-Kyu (Catalysis Center for Molecular Engineering (CCME), Korea Research Institute of Chemical Technology (KRICT))
  • 투고 : 2009.12.03
  • 심사 : 2010.02.25
  • 발행 : 2010.06.20
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초록

A porous coordination solid of nickel(II) dihydroxyterephthalate has been synthesized by the microwave-assisted (MW) method. The synthesized nickel(II) dihyroxylterephthalate was designated by the general formula of [$Ni_2$(dhtp) $(H_2O)_2]{\cdot}8H_2O$ (where, dhtp = 2,5-dihydroxyterephthalate, denoted by Ni-DHTP). The effect of microwave-irradiation temperature and time of irradiation on the porosity and morphological changes in the solids have also been investigated. The catalytic performance of Ni-DHTP synthesized by MW method has been studied in the oxidation of cyclohexene with aqueous $H_2O_2$, which gave cyclohexene oxide as the primary product and 2-cyclohexene-1-ol as a major product.

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