Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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Fabrication of Porous Calcium Phosphate by Using a Pre-Form of Nature Material

자연물의 미세구조를 활용한 다공성 인산칼슘 제조

  • Lee, Sang-Jin (Department of Advanced Materials Science and Engineering, Mokpo National University) ;
  • Lee, Hoon-Cheol (Department of Advanced Materials Science and Engineering, Mokpo National University)
  • 이상진 (국립목포대학교 신소재공학과) ;
  • 이훈철 (국립목포대학교 신소재공학과)
  • Received : 2010.03.19
  • Accepted : 2010.05.10
  • Published : 2010.05.31
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Abstract

Porous calcium phosphates were successfully fabricated by using a cuttlefish bone. The cuttlefish bone, which is composed of $CaCO_3$, showed a special porous microstructure containing uniform-sized voids. In this study, the pre-forms infiltrated distilled phosphoric acid were sintered at $1200^{\circ}C$ in an air atmosphere. The porous microstructure of the pre-forms was kept their original pattern after sintering with a synthesis of calcium phosphate. The obtained porous calcium phosphate, sintered at $1200^{\circ}C$ for 3 h at 17% concentration of phosphoric acid, showed uniform open pores of 150 ${\mu}m$ in size and $\beta$-TCP phase in the XRD patterns. Above 16% concentration, CaO phase, derived from the decomposition of $CaCO_3$, decreased gradually in the sintered samples, and the measured Ca/P ratios of the samples prepared from 16% and 18% concentration were 1.67 and 1.43, which are close to stoichiometric HA (1.66) and $\beta$-TCP (1.50).

Keywords

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