Bulletin of the Korean Chemical Society

  • 제31권5호
  • /
  • Pages.1252-1256
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  • 2010
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Preparation of Ag/PVP Nanocomposites as a Solid Precursor for Silver Nanocolloids Solution

  • Hong, Hyun-Ki (Deparment of Nanobiomedical Science and WCU Research Center of Nanobiomedical Science, Dankook University) ;
  • Park, Chan-Kyo (Department of Applied Chemical Engineering, Dankook University) ;
  • Gong, Myoung-Seon (Deparment of Nanobiomedical Science and WCU Research Center of Nanobiomedical Science, Dankook University)
  • 투고 : 2009.10.21
  • 심사 : 2010.03.08
  • 발행 : 2010.05.20
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초록

A polyvinylpyrrolidone (PVP)/Ag nanocomposites was prepared by the simultaneous thermal reduction and radical polymerization route. The in situ synthesis of the Ag/PVP nanocomposites is based on the finding that the silver n-propylcarbamate (Ag-PCB) complex can be directly dissolved in the NVP monomer, and decomposed by only heat treatment in the range of 110 to $130^{\circ}C$ to form silver metal. Silver nanoparticles with a narrow size distribution (5 - 40 nm) were obtained, which were well dispersed in the PVP matrix. A successful synthesis of Ag/PVP nanocomposites then proceeded upon heat treatment as low as $110^{\circ}C$. Moreover, important advantages of the in situ synthesis of Ag/PVP composites include that no additives (e.g. solvent, surface-active agent, or reductant of metallic ions) are used, and that the stable silver nanocolloid solution can be directly prepared in high concentration simply by dissolving the Ag/PVP nanocomposites in water or organic solvent.

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