Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis and Spectral Properties of Novel Thionaphtoquinone Dyes

  • Sayil, Cigdem (Istanbul University, Faculty of Engineering, Department of Chemistry) ;
  • Ibis, Cemil (Istanbul University, Faculty of Engineering, Department of Chemistry)
  • Received : 2009.09.04
  • Accepted : 2010.03.05
  • Published : 2010.05.20
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Abstract

2,3-Dichloro-1,4-naphtoquinone 1 compound was reacted with octadecanethiol 2 in two different mole ratio. Compound 3 was obtained from the reaction of 1 and 2 in 1:2 mole/mole ratio. Compounds 7 and 8 were obtained from reaction of 1 and 2 in 1:1 mole/mole ratio and known compound 9 was synthesized as by-product in this reaction. Novel compounds 5a-e were obtained from reaction of 1 and related thiols 4a-e. Known compounds 6c and 6e were synthesized as by-product in this reaction. The structures of the compounds were characterized by elemental analysis, UV-vis, FTIR, $^1H$-NMR, $^{13}C$-NMR and Mass spectroscopies.

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