The Annealing Effect of Diamond-like Carbon Films for RF MEMS Switch

  • Received : 2010.11.01
  • Accepted : 2010.11.15
  • Published : 2010.11.30

Abstract

Stiction in microelectromechanical systems (MEMS) has been a major failure mechanism. Especially, in RF MEMS switches, moving parts often suffered in-use and release related stiction problems. Some materials and methods have been used to prevent this problem. Diamond-like carbon (DLC) has not only been used as a protective material owing to its good mechanical properties but also has been used as a hydrophobic material. Its properties could be controlled by post annealing treatment in various conditions. We synthesized DLC films using a radio frequency plasma enhanced chemical vapor deposition (RF PECVD) method on silicon substrates using methane ($CH_4$) and hydrogen ($H_2$) gas. Then, the change of the hydrophobic property of the films was investigated undervarious annealing temperatures in nitrogen and in oxygen ambient. The films, that were annealed above $700^{\circ}C$ in nitrogen ambient, showed a high contact angle of water (> $90^{\circ}$) even though their mechanical property was sacrificed to some degree. The structural variation and the changes of the hydrophobic and mechanical properties of the DLC films were analyzed by Raman spectrum, contact angle measurement, surface profiler, and a nanoindentation test.

Keywords

References

  1. R. Maboudian, R. T. Howe, "Adhesion in surface micro-mechanical sturctures", J. Vac. Sci. Technol., B15, pp.1-20, 1997.
  2. C. H. Mastrangelo, C. H. Hsu, "Mechanical Stability and Adhesion Micorstructure under Capillary Forces", J. Microelectromech. S., 2, pp.33-43, 1993. https://doi.org/10.1109/84.232593
  3. S. M. Ali, J. M. Jennings, L. M. Phinney, "'Temperature dependence for in-use stiction of polycrystalline silicon MEMS cantilevers", Sens. Actuators A, 113, pp.60-70, 2004. https://doi.org/10.1016/j.sna.2004.01.037
  4. N. Takeshimo, K. J. Gabriel, M. Ozaki, J. Takashashi, H. Horiguchi, H. Fujita, "Electrostatic parallelogram actuators", Transducers' 91. International Conference, pp.63-66, 1991.
  5. H. S. Hwang, J. T. Song, "An effective method to prevent stiction problems using a photoresist sacrificial layer" J. Micromech. Microeng., 17, pp.245-259, 2007. https://doi.org/10.1088/0960-1317/17/2/009
  6. M. R. Houston, R. Maboudian, R. T. Howe, "Ultra hydrophobic wetting behavior of amorphous carbon films", Transducers' 95. International Conference, pp.210-213, 1995.
  7. Pornsin-Sirirak T N, Tai Y C, Nassef H and Ho C M, "Flexible parylene actuator for micro adaptive flow control", Proc. IEEE MEMS 2001, pp.511-514, 2001.
  8. B. H. Kim , T. D. Chung, C. H. Oh, K. Chun, "A new organic modifier for anti-stiction", J. Microelectromech. S., 10, pp.33-40, 2001. https://doi.org/10.1109/84.911089
  9. J. Robertson, "Diamond-like amorphous carbon", Mat. Sci. Eng. R., 37, pp.129-281, 2002. https://doi.org/10.1016/S0927-796X(02)00005-0
  10. A. Grill, "Diamond-like carbon: state of the art", Diam. Relat. Mater., 8, pp.428-434, 1999. https://doi.org/10.1016/S0925-9635(98)00262-3
  11. T. I. T. Okpalugo, A. A. Ogwu, P. D. Maguire, J. A. D. McLaughlin, "Platelet adhesion on silicon modified hydrogenated amorphous carbon films", Biomaterials, 25, pp.239-245, 2004. https://doi.org/10.1016/S0142-9612(03)00494-0
  12. H. Nakazawa, T. Kawabata, M. Kudo, M. Mashita, "Structural changes of diamond-like carbon films due to atomic hydrogen exposure during annealing", Appl. Surf. Sci., 253, pp.4188-4196, 2007. https://doi.org/10.1016/j.apsusc.2006.09.017
  13. I. A. Faizrakhmanov, V. V. Bazarov, N. Y. Kurbatova, I. B. Khaibullin, A. L. Stepanov, "Synthesis of New Carbon-Nitrogen Nanoclusters by Annealing Diamond-Like Carbon Films in Nitrogen", Semiconductors, 37, pp.230-234, 2003.
  14. D. H. C. Chua, W. I. Milne, Tay, B. K. P. Zhang, X. Z. Ding, "Microstructural and surface properties of cobalt containing amorphous carbon thin film deposited by a filtered cathodic vacuum arc", J. Vac. Sci. Technol., A21, pp.353-358, 2003.
  15. H. Schulz, M. Leonhardt, H. J. Scheibe, B. Schultrich, "Ultra hydrophobic wetting behavior of amorphous carbon films", Surf. Coat. Tech., 200, pp.1123-1126, 2005 https://doi.org/10.1016/j.surfcoat.2005.02.019
  16. R. Wachter, A. Cordery, "Effects of postdeposition annealing on different DLC films", Diamond Relat. Mater., 8, pp.504-509, 1999. https://doi.org/10.1016/S0925-9635(98)00395-1
  17. G. Q. Yu, B. K. Tay, Z. Sun, L. K. Pan, "Properties of fluorinated amorphous diamond like carbon films by PECVD", Appl. Surf. Sci., 219, pp.228-237, 2003. https://doi.org/10.1016/S0169-4332(03)00644-5
  18. W. S. Choi, J. Heo, I. Chung, B. Hong, "The effect of RF power on tribological properties of the diamond-like carbon films", Thin Solid Films, 475, pp.287-290, 2005. https://doi.org/10.1016/j.tsf.2004.07.033
  19. M. Grischke, K. Bewilogua, K. Trojan, H. Dimigen, "Application-oriented modifications of deposition processes for diamond-likecarbon- based coatings", Surf. Coat. Tech., 74-75, pp.739, 1995. https://doi.org/10.1016/0257-8972(94)08201-4
  20. N. M. J. Conway, A. C. Ferrari, A. J. Flewitt, J. Robertson, W. I. Milne, A. Tagilaferro, W. Beyer, "Defect and disorder reduction by annealing in hydrogenated tetrahedral amorphous carbon", Diamond Relat. Mater., 9, pp.765-770, 2000. https://doi.org/10.1016/S0925-9635(99)00271-X
  21. T. S. Chow, "Wetting of rough surfaces", J. Phys: Condens. Matter, 10, pp.3007-3018, 1998.
  22. L. Y. Ostrovskaya, A. P. Dementiev, I. I. Kulakova, V. G. Ralchenko, "Chemical state and wettability of ion-irradiated diamond surfaces", Diamond Relat. Mater., 14, pp.486-490, 2005. https://doi.org/10.1016/j.diamond.2004.09.010
  23. Meshinis S, Kopustinskas V, Slapikas K, Tamulevicius S, Guobiene A, Gudaitis R and Grigaliunas V, "Ion beam synthesis of the diamond like carbon films for nanoimprint lithography applications", Thin Solid Films, 515, pp.636-639, 2006. https://doi.org/10.1016/j.tsf.2005.12.223
  24. J. K. Luo, Y. Q. Fu, H. R. Le, J. A. Williams, S. M. Spearing, W. I. Milne, "Diamond and diamond-like carbon MEMS, J. Micromech. Microeng., 17, S147-163, 2007. https://doi.org/10.1088/0960-1317/17/7/S12