Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis, Characterization and Structure of DBU-hydrobromide-perbromide: A Novel Oxidizing Agent for Selective Oxidation of Alcohols to Carbonyl Compounds

  • Bakavoli, Mehdi (Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad) ;
  • Rahimizadeh, Mohammad (Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad) ;
  • Eshghi, Hossein (Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad) ;
  • Shiri, Ali (Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad) ;
  • Ebrahimpour, Zahra (Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad) ;
  • Takjoo, Reza (Department of Chemistry, School of Sciences, Islamic Azad University)
  • Published : 2010.04.20
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Abstract

A new and efficient reagent for the conversion of primary and secondary alcohols into their corresponding aldehydes and ketones is introduced. The reagent was easily prepared from the reaction of DBU with molecular bromine in $CHCl_3$. The structure of the reagent as $DBUH^+{Br_3}^-$ was determined by single crystal X-ray diffraction analysis.

Keywords

References

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