Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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γ-ray Radiation Induced Synthesis and Characterization of α-Cobalt Hydroxide Nanoparticles

  • Kim, Sang-Wook (Radiation Research Division for Biotechnology, Korea Atomic Energy Research Institute (KAERI)) ;
  • Kwon, Bob-Jin (Advanced Functional Nanohybrid Material Laboratory, Department of Chemistry, Dongguk University-Seoul Campus) ;
  • Park, Jeong-Hoon (Radiation Research Division for Biotechnology, Korea Atomic Energy Research Institute (KAERI)) ;
  • Hur, Min-Goo (Radiation Research Division for Biotechnology, Korea Atomic Energy Research Institute (KAERI)) ;
  • Yang, Seung-Dae (Radiation Research Division for Biotechnology, Korea Atomic Energy Research Institute (KAERI)) ;
  • Jung, Hyun (Advanced Functional Nanohybrid Material Laboratory, Department of Chemistry, Dongguk University-Seoul Campus)
  • Published : 2010.04.20
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Abstract

A novel synthetic route has been developed to prepare $\alpha$-cobalt hydroxide with intercalated nitrate anions. It was successfully synthesized by $\gamma$-ray irradiation under simple conditions, i.e., air atmosphere, without base. Under $\gamma$-ray irradiation, it leads to the formation of layered cobalt hydroxynitrate compounds which have small crystalline size and have the role of a generator of hydroxyl anion. Structural and morphological characterizations were performed by using power X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and high resolution transmission electron microscopy (HR-TEM). The component and thermal stability of the sample were respectively measured by Fourier transform infrared (FT-IR) spectroscopy, elemental analysis, and thermal analyses, including thermogravimetry (TG) and differential thermal analysis (DTA).

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