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Growth parameters and formation of slip plane in ZnWO4 single crystals by the Czochralski method

  • Lim, Chang-Sung (Department of Advanced Materials Science & Engineering, Hanseo University)
  • Received : 2010.09.17
  • Accepted : 2010.10.12
  • Published : 2010.10.31

Abstract

Single crystals of $ZnWO_4$ were grown successfully in the [100], [010] and [001] directions using the Czochralski method. The growth parameters and the formation of slip plane in $ZnWO_4$ crystals were studied. $ZnWO_4$ crystals had a cleavage plane of (010). The dislocation density on the (010) plane at the center of the crystal was lower than that of the edge region. It was inferred that the high density at the edge of the crystals was caused by the thermal gradient during crystal growth. The etch pit arrangement revealed the (100) slip plane to be most active during crystal growth.

Keywords

References

  1. A. Kalinko, A. Kuzmin and R.A. Evarestov, "Ab initio study of the electronic and atomic structure of the wolframite- type $ZnWO_{4}$", Solid State Comm. 149 (2009) 425. https://doi.org/10.1016/j.ssc.2009.01.003
  2. P. Belli, R. Bernabei, F. Cappella, R. Cerulli and F.A. Danevich, "Search for double beta decay of zinc and tungsten with low background $ZnWO_{4}$ crystal scintillators", Nuc. Phys. A826 (2009) 256.
  3. X. Cao, W. Wu, N. Chen, Y. Peng and Y. Liu, "An ether sensor utilizing cataluminescence on nanosized $ZnWO_{4}$", Sensors and Actuators B137 (2009) 83.
  4. C. Yu and J.C. Yu, "Sonochemical fabrication, characterization and photocatalytic properties of Ag/$ZnWO_{4}$ nanorod catalyst", Mat. Sci. Eng. B 164 (2009) 16. https://doi.org/10.1016/j.mseb.2009.06.008
  5. S. Lin, J. Chen, X. Weng, L. Yang and X. Chen, "Fabrication and photocatalysis of mesoporous $ZnWO_{4}$ with PAMAM as a template", Mat. Res. Bull. 44 (2009) 1102. https://doi.org/10.1016/j.materresbull.2008.10.011
  6. M. Itoh, T. Katagiri, T. Aoki and M. Fujita, "Photostimulated luminescence and photo-induced infrared absorption in $ZnWO_{4}$", Radiation Measurements 42 (2007) 545. https://doi.org/10.1016/j.radmeas.2007.01.049
  7. V. Nagirnyi, L. Jonsson, M. Kirm, A. Kotlov, A. Lushchik, I. Martinson, A. Watterich and B.I. Zadneprovski, "Luminescence study of pure and Fe- or Mo-doped $ZnWO_{4}$ crystals", Radiation Measurements 38 (2004) 519. https://doi.org/10.1016/j.radmeas.2004.01.024
  8. G.B. Kumar, K. Sivaiah and S. Buddhudu, "Synthesis and characterization of $ZnWO_{4}$ ceramic powder", Cer. Int. 36 (2010) 199. https://doi.org/10.1016/j.ceramint.2009.07.005
  9. X.G. Huang and Y. Zhu, "Synthesis and photocataytic performance of $ZnWO_{4}$ catalyst", Mat. Sci. Eng. B 139 (2007) 201. https://doi.org/10.1016/j.mseb.2007.02.009
  10. X. Jiang, J. Ma, J. Liu, Y. Ren, B. Lim, J. Tao and X. Zhu, "Synthesis of $ZnWO_{4}$ nano-particles by a molten salt method", Materials Letters 61 (2007) 4595. https://doi.org/10.1016/j.matlet.2007.02.058
  11. T. Dong, Z. Li, Z. Ding, L. Wu, X. Wang and X. Fu, "Characterization and properties of $Eu^{3}$ -doped $ZnWO_{4}$ prepared via a facile self-propagating combustion method", Mat. Res. Bull. 43 (2008) 1694. https://doi.org/10.1016/j.materresbull.2007.07.020
  12. A. Dodd, A. Mckinley, T. Tsuzuki and M. Saunders, "Mechanochemical synthesis of nanoparticulate ZnO-$ZnWO_{4}$ powders and their photocatalytic activity", J. Euro. Cer. Soc. 29 (2009) 139. https://doi.org/10.1016/j.jeurceramsoc.2008.05.027
  13. X. Zhao, W. Yao, Y. Wu, S. Zhang. H. Yang and Y. Zhu, "Fabrication and photo-electrochemical properties of porous $ZnWO_{4}$ film", J. Sol. Stat. Che. 179 (2006) 2562. https://doi.org/10.1016/j.jssc.2006.05.004
  14. F.-S. Wen, X. Zhao, H. Huo, J.-S. Chen, E. Shu-Lin and J.-H. Zhang, "Hydrothermal synthesis and photoluminescent properties of $ZnWO_{4}$ and $Eu^{3+}$-doped $ZnWO_{4}$", Mat. Lett. 55 (2002) 152. https://doi.org/10.1016/S0167-577X(01)00638-3
  15. G. Huang, C. Zhang and Y. Zhu, "$ZnWO_{4}$ photocatalyst with high activity for degradation of organic contaminants", J. Alloys and Compounds 432 (2007) 269. https://doi.org/10.1016/j.jallcom.2006.05.109
  16. H. Fu, J. Lin, L. Zhang and Y. Zhu, "Photocatalytic activities of a novel $ZnWO_{4}$ catalyst prepared by a hydrothermal process", Applied Catalysis A: General 306 (2006) 58. https://doi.org/10.1016/j.apcata.2006.03.040
  17. A. Kornylo, A. Jankowska-Frydel, B. Kuklinski, M. Grinberg, N. Kruyiak, Z. Moroz and M. Pashkowsky, "Growth and spectroscopy of $Ni^{2+}$ in $ZnWO_{4}$ crystal", Radiation Measurement 38 (2004) 707. https://doi.org/10.1016/j.radmeas.2004.03.003
  18. L. Malicsko, A. Peter and W. Erfurth, "Spectroscopic properties of single crystal doped with Fe and Li impurities", J. Crystal Growth 151 (1995) 127. https://doi.org/10.1016/0022-0248(95)00015-1
  19. L. Malicsko, A. Peter and W. Erfurth, "Characterization of $ZnWO_{4}$: Fe single crystals by optical and scanning electron microscopic methods", J. Crystal Growth 151 (1995) 127. https://doi.org/10.1016/0022-0248(95)00015-1