Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis of Cyclohexene Derivatives from 1,5-Enynes via Gold-Catalysis and Iodocyclization: A Comparative Study and Applications in the Synthesis of 7/5- or 8/5-Fused Rings and Biaryls

  • Lee, Young-Un (Department of Chemistry and Institute for Natural Sciences, Hanyang University) ;
  • Lim, Choong-Min (Department of Chemistry and Institute for Natural Sciences, Hanyang University) ;
  • Kim, Sung-Hwan (Department of Chemistry, Kyungpook National University) ;
  • Shin, Seung-Hoon (Department of Chemistry and Institute for Natural Sciences, Hanyang University)
  • Published : 2010.03.20
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Abstract

A comparative study on the Au(I)-catalyzed and IBr-promoted tandem cyclization of 1,5-enyne was reported. This study provides a meaningful mechanistic insight to the concerted nature of this tandem reaction and also provides interesting applications in the synthesis of 7/5- or 8/5-fused bicycles and biaryls.

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References

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