The Characteristics of Disinfection by-products Occurrence and Speciation in D Water Treatment Processes

D 정수처리장에서 소독부산물 발생 및 종분포 특성

  • Kim, Sung-Joon (Department of Environmental Engineering, Chonbuk National University) ;
  • Kim, Jong-Min (Department of Environmental Engineering, Chonbuk National University) ;
  • Jeon, Yong-Tae (Department of Environmental Engineering, Chonbuk National University) ;
  • Park, Jong-Eun (Department of Environmental Engineering, Chonbuk National University) ;
  • Won, Chan-Hee (Department of Environmental Engineering, Chonbuk National University)
  • Received : 2009.10.20
  • Accepted : 2010.04.13
  • Published : 2010.05.30

Abstract

Concentrations and speciations of Trihalomethanes (THMs) and Haloacetic acids ($HAA_5$) that can be formed during chlorine disinfection by-product (DBPs) in full-scale drinking water treatment plants were investigated. Jeon-ju D water treatment plant that adopted conventional water treatment processes was chosen for investigation. SUVA values according to water treatment process changes were observed from 1.3 to 2.1. The process average concentrations of THMs was 7.4 ppb, 9.0 ppb and 14.7 ppb respectively, while the average concentrations of $HAA_5$ by each process which are precipitation water, filterater water, treated water, were 15.5 ppb, 14.9 ppb and 25.8 ppb respectively. DBPs concentrations was lower in the winter than summer. The major species of THMs was chloroform and the second highest was bromodichloromethane (BDCM) and the third highest was dibromochloromethane (DBCM). In case of $HAA_5$, the rate of trichloroacetic acid (TCAA) was detected. The species disribution of THMs is related to the change of SUVA and species disribution of $HAA_5$ is related to the concentrations of bromine and injection position of chlorine and injection quantity.

Keywords

References

  1. 김태규(2007). 팔당댐 원수를 이용하는 정수장의 클로랄하이드레이트 생성특성. 석사학위논문, 서울시립대학교.
  2. 신초롱, 손진식, 정창호, 한지희(2007). 국내 정수장 유출수 소독부산물(THMs와 HAAs)의 상관관계 연구. 공동추계학술발표회 논문집, 대한상하수도학회.한국물환경학회, pp. 202-208.
  3. 이동석, 민병섭, 박선구, 김정화, 류재근(2004). 정수장에서 소독부산물의 생성특성. 수질보전 한국물환경학회지, 20(1), pp. 55-62.
  4. Chang, E. E., Ching, P. C., Ko, Y. W., and Lan, W. H. (2001). Chracteristics of organic precusors and their relationship with disinfection by-products. Chemosphere, 44(5), pp. 1231-1236. https://doi.org/10.1016/S0045-6535(00)00499-9
  5. Karanfil, T., Schlautman. M. A., and Erdogen, I. (2002). Survey of DOC and UV measurement practices with implications for SUVA determination. J. of AWWA, 94(12), pp. 68-80.
  6. Pomes, M. L., Green, W. R., Thurman, E. M., Orem, W. H., and Lerch, H. E. (1999). DBP formation potential of aquatic humic substances. J. of AWWA, 91(3), pp. 103-115.
  7. Zhou, H. and Xie, Y. F. F. (2002). Using BAC for HAA removal-part1 : Batch study. J. Am. Water works Assoc., 94(4), pp. 194-200.