Application of Photocatalytic Decomposition of Methylene Blue on N-doped TiO2

질소 도핑 TiO2의 Methylene Blue 광분해 제거에의 적용

  • Baek, Mi-Hwa (Department of Environmental Science and Engineering, Ewha Womans University) ;
  • Choi, Su-A (Department of Environmental Science and Engineering, Ewha Womans University) ;
  • Kim, Dong-Su (Department of Environmental Science and Engineering, Ewha Womans University)
  • 백미화 (이화여자대학교 환경공학과) ;
  • 최수아 (이화여자대학교 환경공학과) ;
  • 김동수 (이화여자대학교 환경공학과)
  • Received : 2010.03.02
  • Accepted : 2010.06.01
  • Published : 2010.07.30

Abstract

Nitrogen-doped $TiO_2$ particles have been successfully prepared using titanium tetraisopropoxide as the Ti source and urea as the nitrogen source. As-prepared nitrogen-doped $TiO_2$ was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer-Emmett-Teller method (BET) and ultraviolet-visible light (UV-vis) absorption spectra techniques. Photocatalytic degradation of Methylene Blue (MB) has been carried out in both solar light (UV-vis) and the visible region (${\lambda}=420nm$). Nitrogen-doped $TiO_2$ exhibits higher activity than the commercial $TiO_2$ photocalyst, particularly under visible-light irradiation because bandgap of nitrogen-doped $TiO_2$ becomes remarkably decreased.

Keywords

References

  1. Asahi, R., Morikawa, T., Obwaki, T., Aoki, K., and Taga, Y. (2001). Visible-light photocatalysis in nitrogen-doped titanium oxides. Science, 293, pp. 269-271. https://doi.org/10.1126/science.1061051
  2. Bacsa, R., Kiwi, J., Ohno, T., Albers, P., and Nadtochenko, V. (2005). Preparation, testing and characterization of doped TiO2 active in the peroxidation of biomclecutes under visible light. J. Phys. Chem. B, 109, pp. 5994-6003. https://doi.org/10.1021/jp044979c
  3. Bulut, Y. and Aydin, H. (2006). A kinetics and thermodynamics study of ethylene blue adsorption on wheat shells. Desalination, 194, pp. 259-267. https://doi.org/10.1016/j.desal.2005.10.032
  4. El-Bahy, Z. M., Ismail, A. A., and Mohamed, R. M. (2009). Enhancement of titania by doping rare earth for photo-degradation of organic dye (Direct Blue). J. Hazard. Mater., 166, pp. 138-143. https://doi.org/10.1016/j.jhazmat.2008.11.022
  5. Hameed, B. H., Din, A. T. M., and Ahmad, A. L. (2007). Adsorption of methylene blue onto bamboo-based activated carbon: Kinetics and equilibrium studies. J. Hazard. Mater., 141, pp. 819-825. https://doi.org/10.1016/j.jhazmat.2006.07.049
  6. Higeshimoro, S., Tanihata, W., Nakagawa, Y., Azuma, M., Ohue, H., and Sakata, Y. (2008). Effective photocatalytic decomposition of VOC under visible-light irradiation of N-doped TiO2 modified by vanadium species. Appl. Catal. A: Gen., 340, pp. 98-104. https://doi.org/10.1016/j.apcata.2008.02.003
  7. Irokawa, Y., Morikawa, T., Aoki, K., Kosaka, S., Ohwaki, T., and Taga, Y. (2006). Photodegradation of toluene over $TiO_2-xN_x$ under visible light irradiation. Phys. Chem. Chem. Phys., 8, pp. 1116-1121. https://doi.org/10.1039/b517653k
  8. Miyauchi, M., Ikezawa, A., Tobimatsu, H., Irie, H., and Hashimoto, K. (2004). Zeta potential and photocatalytic activity of nitrogen doped $TiO_2$ thin films. Phys. Chem. Chem. Phys., 6, pp. 865-870. https://doi.org/10.1039/b314692h
  9. Nosaka, Y., Matsushita, M., Nishino, J., and Notaka, A. Y. (2005). Nitrogen-doped titanium dioxide photocatalysis for visible response prepared by using organic compounds. Sci. Technol. Adv. Mater., 6, pp. 143-148. https://doi.org/10.1016/j.stam.2004.11.006
  10. Ozer, D., Dursun, G., and Oze, A. (2007). Methylene blue adsorption from aqueous solution by dehydrated peanut hull. J. Hazard. Mater., 144, pp. 171-179. https://doi.org/10.1016/j.jhazmat.2006.09.092
  11. Peng, F., Cai, L., Huang, L., Yu, H., and Wang, H. (2008). Preparation of nitrogen-doped titanium dioxide with visible-light photocatalytic activity using a facile hydrothermal method. J. Phy. Chem. Solids, 69, pp. 1657-1664. https://doi.org/10.1016/j.jpcs.2007.12.003
  12. Sakthivel, S. and Kisch, H. (2003). Photocatalytic and photo-electrochemical properties of nitrogen-doped titanium dioxide. Chem. Phys. Chem., 4, pp. 487-490. https://doi.org/10.1002/cphc.200200554
  13. Sano, T., Puzenat, E., Guillard, C., Geanret, C., and Matsuzawa, S. (2008). Degradation of $C_2H_2$ with modified-$TiO_2$ photocatalysts under visible light irradiation. J. Mol. Catal. A: Chem., 284, pp. 127-133. https://doi.org/10.1016/j.molcata.2008.01.014
  14. Wang, W., Zhang, J., Chen, F., He, D., and Anpo, M. (2008). Preparation and photocatalytic properties of $Fe^{3+}$-doped Ag@ $TiO_2$ core-shell nanoparticles. J. Colloid Interface Sci., 323. pp. 182-186. https://doi.org/10.1016/j.jcis.2008.03.043
  15. Wu, Z., Dong, F., Zhao, W., and Guo, S. (2008). Visible light induced electron transfer process over nitrogen doped $TiO_2$ nanocrystals prepared by oxidation of titanium nitride. J. Hazard. Mat., 157, pp. 57-63. https://doi.org/10.1016/j.jhazmat.2007.12.079
  16. Xu, Y., Ji, J., Zhong, D., and Wang, Y. (2009). Degradation of dye wastewater in a thin-film photoelectrocatalytic (PEC) reactor with slant-placed $TiO_2$/Ti anode. Chem. Eng. J., 150, pp. 302-307. https://doi.org/10.1016/j.cej.2009.01.002
  17. Zhang, J., Wang, Y., Jin, Z., Wu, Z., and Zhang, Z. (2008). Visible-light photocatalytic behavior of two different N-doped $TiO_2$. Appl. Surf. Sci., 254, pp. 4462-4466. https://doi.org/10.1016/j.apsusc.2008.01.020