Journal of Korean Society on Water Environment (한국물환경학회지)

Korean Society on Water Environment (한국물환경학회)
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Treatment Characteristics of Plating Wastewater Containing Freecyanide, Cyanide Complexes and Heavy Metals (II) - Effect of Aldehyde Compounds and Polysulfide -

도금폐수내 유리시안과 착염시안 및 중금속의 처리특성 (II) - aldehyde와 polysulfide첨가에 따른 영향 -

  • Jung, Yeon-Hoon (Department of Energy and Environmental Eng, Graduate School of Energy and Environment Seoul National University of Technology) ;
  • Lee, Soo-Koo (Department of Environmental Engineering, Seoul National University of Technology)
  • 정연훈 (서울산업대학교 에너지환경대학원 에너지환경공학과) ;
  • 이수구 (서울산업대학교 환경공학과)
  • Received : 2010.04.23
  • Accepted : 2010.07.01
  • Published : 2010.07.30
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Abstract

The objective of this study is to investigate the effect of aldehyde compounds and ploysulfide as accelerating agents on removal of heavy metals and CN in plating wastewater. As a results of the experiments, the removal efficiency of cyanide using the formaldehyde type of aldehydes was the highest at pH 9. Next types were sodium formaldehyde bisulfite addut> paraldehyde> paraformaldehyde. Also, optimum pH and dosage for treating the residual heavy metals by using polysulfide were pH 9 and 30 mg/L, respectively. The removal efficiencies of cyanide, chromium, zinc and copper were above 96.7% at optimum condition.

Keywords

References

  1. 김광진(1985). 산화환원제에 의한 도금폐수의 처리효과에 관한 연구. 환경과학대학원 석사학위논문, 한양대학교.
  2. 김준래, 조순행, 이건모(1996). 액상 polysulfide를 이용한 도금폐수 처리. 대한환경공학회지, 18(1), pp. 55-65.
  3. 김효진, 조훈제, 박은주, 정진호(2005). 도금폐수의 독성원인 물질 확인. 공동추계학술발표회논문집, 대한상하수도학회.한국물환경학회, pp. 312-315.
  4. 엄경숙, 송민영, 정재춘, 정용(1987). 수은, 납, 카드뮴, 크롬이온이 송사리 (Apiochilus latipes)에 미치는 독성에 관한 연구. J.KS WPRC, 3(2), pp. 53-62.
  5. 이현준, 김효진, 오현주, 조기종, 김정규, 정진호(2007). 폐광산 배수와 퇴적물의 중금속 오염과 생물독성 평가. 수질보전 한국물환경학회지, 23(2), pp. 287-293.
  6. 정연훈, 이수구(2009). 도금폐수내 유리시안과 착염시안 및 중금속의 처리특성(I). 수질보전 한국물환경학회지, 25(6), pp. 979-983.
  7. 정원중, 조순행(1999). 중금속-시안 착염을 함유한 도금폐수의 처리. 대한환경공학회지, 21(6), pp. 1095-1107.
  8. Barriga-Ordonez, F., Neva-Alonso, F., and Uribe-Salas, A. (2006). Cyanide oxidation by ozone in a steady-state flow bubble column. Minerals Engineering, 19, pp. 117-122. https://doi.org/10.1016/j.mineng.2005.09.001
  9. Patterson, J. W.(1985). Industrial Wastewater Treatment Technology, 2nd Ed., Butterworth Publishers, Boston.
  10. Sarla, M., Pandit, M., Tyagi, D. K., and Kapoor, J. C. (2004). Oxidation of cyanide in aqueous solution by chemical and photochemical process. J. of Hazardous Materials, B116, pp. 49-56.
  11. Shen, C. Y. and Nordquist, P. E. R. (1974). Cyanide removal from aqueous waste by polymerization. Ind. Eng. Chem. Prod. Res. Dev., 13(1), pp. 70-75. https://doi.org/10.1021/i360049a014
  12. Sirianuntapiboon, S. and Chuamkaew, C. (2007). Packed cage rotating biological contaetor system for treatment of cyanide wastewater. Bioresource Technol., 98, pp. 266-272. https://doi.org/10.1016/j.biortech.2006.01.014
  13. Torphy, M. F. and Runke, H. M. (1978). Electroplating and cyanide wastes. J. of WPCF, Literature Review, 50(6), pp. 1270-1277.