Bulletin of the Korean Chemical Society

  • 제31권2호
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  • Pages.401-405
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  • 2010
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Copper(II) Selective PVC Membrane Electrodes Based on Schiff base 1,2-Bis (E-2-hydroxy benzylidene amino)anthracene-9,10-dione Complex as an Ionophore

  • Jeong, Eun-Seon (Department of Chemistry and Institute of Basic Science, Chonnam National University) ;
  • Lee, Hyo-Kyoung (Department of Chemistry and Institute of Basic Science, Chonnam National University) ;
  • Ahmed, Mohammad Shamsuddin (Department of Biotechnology and Food Science, Mongolia International University) ;
  • Seo, Hyung-Ran (Department of Chemistry and Institute of Basic Science, Chonnam National University) ;
  • Jeon, Seung-Won (Department of Chemistry and Institute of Basic Science, Chonnam National University)
  • 발행 : 2010.02.20
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초록

The Schiff base 1,2-bis(E-2-hydroxy benzylidene amino)anthracene-9,10-dione has been synthesized and explored as ionophore for preparing PVC-based membrane sensors selective to the copper ($Cu^{2+}$) ion. Potentiometric investigations indicate high affinity of these receptors for copper ion. The best performance was shown by the membrane of composition (w/w) of ionophore: 1 mg, PVC: 33 mg, DOP: 66 mg and KTpClPB as additive were added 50 mol % relative to the ionophore in 1 ml THF. The proposed sensor's detection limit is $2.8{\times}10^{-7}$ M over pH 5 at room temperature (Nernstian slope 31.76 mV/dec.) with a response time of 15 seconds and showed good selectivity to copper ion over a number of interfering cations.

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참고문헌

  1. Ardakani, M. M.; Dehghani, H.; Jalayer, M.; Zari, H. R. Anal. Sci. 2004, 20, 1667. https://doi.org/10.2116/analsci.20.1667
  2. Bobacka, J.; Ivaska, A.; Lewenstam, A. Electroanalysis 2003, 15, 366. https://doi.org/10.1002/elan.200390042
  3. Buck, R. Ion-Selective Electrodes in Analytical Chemistry; Plenum Press: New York, 1978.
  4. Lindfors T.; Ivaska, A. Anal. Chim. Acta 2000, 404, 111. https://doi.org/10.1016/S0003-2670(99)00686-8
  5. Goldcamp, M. J.; Ashley, K.; Edison, S. E.; Pretty, J.; Shumakerc, J. Electroanalysis 2005, 17, 1015. https://doi.org/10.1002/elan.200403196
  6. Ohki, A.; Lu, J. P.; Bartsch J. P. Anal. Chem. 1994, 66, 651. https://doi.org/10.1021/ac00077a011
  7. Daunert, S.; Bachas, L. G. Anal. Chem. 1990, 62, 1428. https://doi.org/10.1021/ac00213a016
  8. Moody, G. J.; Saad, B. B.; Thomas, J. D. R. Sel. Electrode Rev. 1988, 10, 71.
  9. Ito, T. Anal. Sci. 1998, 14, 89. https://doi.org/10.2116/analsci.14.89
  10. Mashhadizadeh, M. H.; Shamsipur, M. Anal. Chim. Acta 1999, 381, 111. https://doi.org/10.1016/S0003-2670(98)00672-2
  11. Mahajan, R. K.; Kumar, M.; Sharma, V.; Kaur, T. Analyst 2001, 126, 505. https://doi.org/10.1039/b008944n
  12. Perez-Marin, L.; Lopez-Valdivia, H.; Avila-Perez, P.; Otazo-Sanchez, E.; Macedo-Miranda, G.; Gutierrez-Lozano, O.; Alonso, J.; De Torres-Orazco, J.; Carapia-Morales, L. Analyst 2001, 126, 501. https://doi.org/10.1039/b004532m
  13. Isildak1, I.; Yolcu, M.; Isildak, O.; Demirel, N.; Topal, G.; Hosgoren, H. Microchim. Acta 2004, 144, 177. https://doi.org/10.1007/s00604-003-0072-7
  14. Tavakkoli, N.; Shamsipur, M. Anal. Lett. 1996, 29, 2269. https://doi.org/10.1080/00032719608002251
  15. Shamsipur, M.; Poursaberi, T; Rouhani, S.; Nicham, K.; Sharghi, H.; Ganjali, M. R. Anal Sci. 2000, 17, 1049.
  16. Jeong, D. C.; Lee, H. K.; Jeon, S. Bull. Korean Chem. Soc. 2006, 27, 1593. https://doi.org/10.5012/bkcs.2006.27.10.1593
  17. Kamata, S.; Yamasaki, K.; Higo, M.; Bhale, A.; Fukanaga, Y. Analyst 1988, 113, 45. https://doi.org/10.1039/an9881300045
  18. Casabo, J.; Mestres, L.; Escriche, L.; Texidor, F.; Perez-Jimenez, C. Chem. Soc., Dalton Trans. 1991, 1961.
  19. Kamata, S.; Bhale, A.; Fukanaga, Y.; Murata, H. Anal. Chem. 1988, 60, 2464. https://doi.org/10.1021/ac00173a006
  20. Kamata, S.; Murata, H.; Kubo, Y.; Bhale, A. Analyst 1989, 114, 1029. https://doi.org/10.1039/an9891401029
  21. Bazooka, Z. Analyst 1988, 113, 1893.
  22. Cobber, P. L. H. M.; Gherkin, R. J. M.; Boomer, J. B.; Barged, P.; Vroom, W.; Reinhoudt, D. N. J. Am. Chem. Soc. 1992, 114, 10573. https://doi.org/10.1021/ja00052a063
  23. Jeong, T.; Lee, H. K.; Jeong, D. C.; Jeon, S. Talanta 2005, 65, 543. https://doi.org/10.1016/j.talanta.2004.07.016
  24. Alizadeh, N.; Ershad, S.; Naeimi, H.; Sharghi, H.; Shamsipur, M.; Fresenius' J. Anal. Chem. 1999, 365, 511. https://doi.org/10.1007/s002160051514
  25. Gupta, K. C.; D'Arc, M. J. Anal. Chim. Acta 2001, 437, 199. https://doi.org/10.1016/S0003-2670(01)00995-3
  26. IUPAC Analytical Chemistry Division, Commission on Analytical Nomenclature. Pure Appl. Chem. 1976, 48, 127. https://doi.org/10.1351/pac197648010127

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