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Phase Transformation and Microstructure of FeSi2 Thermoelectric Compounds Manufactured by Powder Metallurgy

분말야금법으로 제조된 FeSi2 열전특성 화합물의 열처리 시간에 따른 미세조직과 상변화

  • Park, Kyoung-Tae (Graduate School of Green Energy Technology, Chungnam National University) ;
  • Shin, Jin-Gyo (Agency for Depense development) ;
  • Hong, Soon-Jik (Division of Advanced Materials Engineering & Institute for Rare Metals Kongju National University) ;
  • Chun, Byong-Sun (Department of metallurgical engineering, Chungnam National University)
  • 박경태 (충남대학교 녹색에너지기술전문대학원) ;
  • 신진교 (국방과학연구소) ;
  • 홍순직 (공주대학교 신소재공학부 및 희소금속연구소) ;
  • 천병선 (충남대학교 나노소재공학원)
  • Received : 2010.11.08
  • Accepted : 2010.12.20
  • Published : 2010.12.28

Abstract

In this study, $FeSi_2$ as high temperature performance capable thermoelectric materials was manufactured by powder metallurgy.The as-casted Fe-Si alloy was annealed for homogenization below $1200^{\circ}C$ for 3 h. Due to its high brittleness, the cast alloy transformed to fine powders by ball-milling, followed by subsequent compaction (hydraulic pressure; 2 GPa) and sintering ($1200^{\circ}C$, 12 h). In order to precipitate ${\beta}-FeSi_2$, heat treatment was performed at $850^{\circ}C$ with varying dwell time (7, 15 and 55 h). As a result of this experiment thermoelectric phase ${\beta}-FeSi_2$ was quickly transformed by powder metallurgical process. There was not much change in powder factor between 7h and 55h specimens.

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