한국식품위생안전성학회지 (Journal of Food Hygiene and Safety)

  • 제25권3호
  • /
  • Pages.203-208
  • /
  • 2010
  • /
  • 1229-1153(pISSN)
  • /
  • 2465-9223(eISSN)
한국식품위생안전성학회 (The Korean Society of Food Hygiene and Safety)
권호 표지

폴리스티렌 식품용기로부터 증류수로 용출되는 휘발성유기화합물의 분석

Migration Measurement of Volatile Organic Compounds (VOCs) from Polystyrene-made Food Containers into Distilled Water

  • 김남훈 (서울특별시 보건환경연구원) ;
  • 김애경 (서울특별시 보건환경연구원) ;
  • 조태희 (서울특별시 보건환경연구원) ;
  • 박경애 (서울특별시 보건환경연구원) ;
  • 곽재은 (서울특별시 보건환경연구원) ;
  • 김지영 (서울특별시 보건환경연구원) ;
  • 김일영 (서울특별시 보건환경연구원) ;
  • 채영주 (서울특별시 보건환경연구원) ;
  • 김민영 (서울특별시 보건환경연구원)
  • Kim, Nam-Hoon (Seoul Metropolitan Government Research Institute of Public Health and Environment) ;
  • Kim, Ae-Kyeong (Seoul Metropolitan Government Research Institute of Public Health and Environment) ;
  • Cho, Tae-Hee (Seoul Metropolitan Government Research Institute of Public Health and Environment) ;
  • Park, Kyung-Ai (Seoul Metropolitan Government Research Institute of Public Health and Environment) ;
  • Kwak, Jae-Eun (Seoul Metropolitan Government Research Institute of Public Health and Environment) ;
  • Kim, Ji-Young (Seoul Metropolitan Government Research Institute of Public Health and Environment) ;
  • Kim, Il-Young (Seoul Metropolitan Government Research Institute of Public Health and Environment) ;
  • Chae, Young-Joo (Seoul Metropolitan Government Research Institute of Public Health and Environment) ;
  • Kim, Min-Young (Seoul Metropolitan Government Research Institute of Public Health and Environment)
  • 투고 : 2010.05.13
  • 심사 : 2010.08.11
  • 발행 : 2010.09.30
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

21종류의 폴리스티렌 용기를 대상으로 용출조건에 따른 용기내 증류수로 용출되는 5종의 VOCs(톨루엔, 스티렌, 에틸벤젠, 이소프로필벤젠 및 n-프로필벤젠)를 Purge&Trap 장치를 연결하여GC-FID로 분석하였다. 각 표준물질은 1~50 ng/mL의 농도범위에서 직선성($r^2$ =0.9976~0.9995)을 나타냈으며, 검출한계는 0.041~0.092 ng/mL, 정량한계는 0.135~0.304 ng/mL 이었다. 용출조건은 첫째, $60^{\circ}C$에서 30분, 둘째, $95^{\circ}C$에서 30분, 셋째, 실생활에서 컵라면 섭취시를 고려하여 끓은 물을 부은 후 뚜껑을 덮고 3분간 유지한 다음 뚜껑을 열고 5분 동안 개방하여 용출시키는 것으로 설정하였다. 톨루엔, 에틸벤젠, 이소프로필벤젠 및 n-프로필벤젠은 평균용출량이 모든 조건에서 5 ng/mL 이하로 검출되었으며 스티렌의 경우는 $60^{\circ}C$에서 평균용출량이 4.02 ng/mL, $95^{\circ}C$에서는 52.71 ng/mL, 컵라면 섭취시의 조건에서는 17.23 ng/mL로 검출되었다.

In this study, the level of migration of 5 kinds of volatile organic compounds (VOCs) (toluene, styrene, ethylbenzene, isopropylbenzene and n-propylbenzene) into distilled water from polystyrene-made food containers was measured using Purge&Trap combined with GC/FID. The contents of the VOCs which have regulatory limits in Korea food code only for material specification were determined under three exposure conditions which were 30 min at $60^{\circ}C$, 30 min at $95^{\circ}C$ and actual situation of instant noodle intake. The calibration curve of 5 compounds showed good linearity ($^r2$ = 0.9976~0.9995) within the concentration range of 1~50 ng/mL. The limit of detection (LOD) and limit of quantification (LOQ) were validated at range of 0.041~0.092 and 0.135~0.304 ng/mL, respectively. The average migration contents of 5 compounds were below 5 ng/mL except for styrene. The average contents of styrene were highly detected at $95^{\circ}C$ for 30 min exposure (52.71 ng/mL). Under actual condition at instant noodle intake, the average contents of styrene was 17.23 ng/mL. The results demonstrated that the migration rate of VOCs was related to storage temperature and time.

키워드

참고문헌

  1. 김재원: 사출금형 설계자를 위한 플라스틱 재료, 구민사. pp. 333.
  2. Sung, J. H., Kwon, K. S. and Lee, K. H. : A method for analysis of styrene dimer and trimer in foods and containers. Korean J. Food Sci. Technol., 32, 1234-1243 (2000).
  3. Lee, K. H., Jang, Y. M., Kwak, I. S., Yoo, S. S., Kim, K. M., Choi, B. H. and Lee, C. W. : Analysis of styrene dimer and trimer in cup noodle containers. Korean J. Food Sci. Technol., 31, 931-937 (1997).
  4. Lee, D. S., Song, B. S., Choi, J. O. and Park, W. P. : Migration of low molecular weight substances from expanded polystyrene cup to aqueous food simulant. J. Korean Soc. Food Sci. Nutr., 33, 1056-1062 (2004). https://doi.org/10.3746/jkfn.2004.33.6.1056
  5. Till, D. E., Ehntholt, D. J., Reid, R. C., Schwartz, P. S., Schwope, A. D., Sidman, K. R. and Whelan, R. H. : Migration of styrene monomer from crystal polystyrene to foods and food simulating liquids. Ind. Eng. Chem. Fundam., 21, 161-168 (1982). https://doi.org/10.1021/i100006a010
  6. Durst, G.L. and Laperle, E. A. : Styrene monomer migation as monitored by purge and trap gas chromatography and sensory analysis for polystyrene containers. J. Food Sci., 55, 522-524 (1990). https://doi.org/10.1111/j.1365-2621.1990.tb06800.x
  7. Lickly, T. D., Lehr, K. M. and Welsh, G. C. : Migration of styrene from polystyrene foam food-contact articles. Fd. Chem. Toxic., 33, 475-481 (1995). https://doi.org/10.1016/0278-6915(95)00009-Q
  8. Philo, M. R., Fordham, P. J., Damant, A. P. and Castle, L. : Measurement of styrene oxide in polystyrenes, estimation of migration to foods, and reaction kinetics and products in food simulants. Fd. Chem. Toxic., 35, 821-826 (1997). https://doi.org/10.1016/S0278-6915(97)00054-9
  9. Varner, S. L. and Breder, C. V. : Headspace sampling and gas chromatographic determination of styrene migration from food-contact polystyrene cups into beverages and food simulants. J. Assoc. Offic. Anal. Chem., 64, 1122-1130 (1981).
  10. Murphy, P. G., Macdonald, D. A. and Lickly, T. D. : Styrene migration from general-purpose and high-impact polystyrene into food-simulating solvents. Fd. Chem. Toxic., 30, 225-232 (1992). https://doi.org/10.1016/0278-6915(92)90037-L
  11. Park, S. Y., Kim, K. H., Yang, H. S. Ha, J. Y., Lee, K. H. and Ahn, J. W. : Determination of VOC in aqueous samples by the combination of headspace (HS) and solid-phase microextraction(SPME). Anal. Sci. Tech., 21, 93-101 (2008).
  12. Kim, K. K., Shin, S. K, and Ju, D. W. : Determination of volatile organic compounds in waste using HS/GC/MS analysis. Anal. Sci. Tech., 13, 72-80 (2000).
  13. Shin, H. S. and Ahn, H. S. : The study on the measurement of volatile organic compounds in the air of A and B industrial area. Anal. Sci. Tech., 17, 130-144 (2004).
  14. Ahn, J. W. and Kim, K. H. : Calibration characteristics of VOCs by a gas chromatography with mass spectrometry (GC-MS) in relation to injection approaches. J. Korean Soc. Environ. Anal., 12, 13-24 (2009).
  15. Jung, S. W., Yang, W. H. and Son, B. S. : Health risk assessment by potential exposure of $NO_{2}$ and VOCs in apartments. Kor. J. Env. Hlth., 33, 242-249 (2007).
  16. Sarma, S. N., Kim, Y. J. and Ryu, J. C. : Gene expression profiles of human promyelocytic leukemia cell lines exposed to volatile organic compounds. Toxicology, 271, 122-123 (2010). https://doi.org/10.1016/j.tox.2010.03.014
  17. 식품의약품안전청 : 식품공전 (2009).
  18. Lickly, T. D., Breder, C. V. and Rainey, M. L. : A model for estimating the daily dietary intake of a substance from food-contact articles;Styrene from polystyrene food-contact polymers. Regul. Toxicol. Pharmacol. 21, 406-417 (1995). https://doi.org/10.1006/rtph.1995.1055