Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Phosphoric Acid Modified Nb2O5: A Selective and Reusable Catalyst for Dehydration of Sorbitol to Isosorbide

  • Tang, Zhen-Chen (College of chemistry and chemical engineering, Nanjing University of Technology) ;
  • Yu, Ding-Hua (College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology) ;
  • Sun, Peng (College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology) ;
  • Li, Heng (College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology) ;
  • Huang, He (College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology)
  • Received : 2010.09.01
  • Accepted : 2010.10.11
  • Published : 2010.12.20
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Abstract

Niobium oxide ($Nb_2O_5$) and phosphated $Nb_2O_5$ were synthesized and used as catalysts for sorbitol dehydration to isosorbide. The characterization results of $N_2$ adsorption, XRD and $NH_3$-TPD revealed that the phosphoric acid modification could well prevent the crystallization of $Nb_2O_5$. And the amorphous phosphated $Nb_2O_5$ catalysts kept the relatively large surface area and stable acidity at high calcination temperature. The catalytic results showed that the selectivity to isosorbide could be dramatically enhanced over phosphated $Nb_2O_5$. The excellent catalytic performance with 100.0% sorbitol conversion and 62.5% isosorbide selectivity were obtained over the 0.8P/NBO-400 catalyst. Comparing with $Nb_2O_5$ catalysts, phosphated $Nb_2O_5$ catalysts regenerated through a simple calcination process showed no significant activity loss after recycling three runs.

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References

  1. Gohil, R. M. Polym. Eng. Sci. 2009, 49, 544. https://doi.org/10.1002/pen.20840
  2. Kricheldorf, H. R.; Behnken G.; Sell, M. J. Macromol. Sci., PureAppl. Chem. 2007, 44, 679. https://doi.org/10.1080/10601320701351128
  3. Chatti, S.; Kricheldorf, H. R. J. Macromol. Sci., Pure Appl. Chem.2006, 43, 967. https://doi.org/10.1080/10601320600740397
  4. Chatti, S.; Bortolussi, M.; Loupy, A.; Blais, J. C.; Bogdal, D.; Majdoub,M. Eur. Polym. J. 2002, 38, 1851. https://doi.org/10.1016/S0014-3057(02)00071-X
  5. Kricheldorf, H. R. Polym. Rev. 1997, 37, 599. https://doi.org/10.1080/15321799708009650
  6. Bhatia, K. K. US Patent #6407266, 2002.
  7. Hartmann, L. A. US Patent #3484459, 1969.
  8. Malone, M. F.; Doherty, F. Ind. Eng. Chem. Res. 2000, 39, 3953. https://doi.org/10.1021/ie000633m
  9. Iizuka, T.; Ogasawara, K.; Tanabe, K. Bull. Chem. Soc. Jpn. 1983,56, 2927. https://doi.org/10.1246/bcsj.56.2927
  10. Carlini, C.; Giuttari, M.; Galletti, A. M. R.; Sbrana, G.; Armaroli,T.; Busca, G. Appl. Catal. A 1999, 183, 295. https://doi.org/10.1016/S0926-860X(99)00064-2
  11. Armaroli, T.; Busca, G.; Carlini, C.; Giuttari, M.; Galletti, A. M.R.; Sbrana, G. J. Mol. Catal. A: Chem. 2000, 151, 233. https://doi.org/10.1016/S1381-1169(99)00248-4
  12. Okazaki, S.; Wada, N. Catal. Today 1993, 16, 349. https://doi.org/10.1016/0920-5861(93)80074-B
  13. Okumura, K.; Yamashita, K.; Hirano, M.; Niwa, M. J. Catal. 2005,234, 300. https://doi.org/10.1016/j.jcat.2005.06.033
  14. Chai, S. H.; Wang, H. P.; Liang, Y.; Xu, B. Q. J. Catal. 2007, 250,342. https://doi.org/10.1016/j.jcat.2007.06.016
  15. Okazaki, S.; Kurimata, M.; Iizuka, T.; Tanabe, K. Bull. Chem. Soc.Jpn. 1987, 60, 37. https://doi.org/10.1246/bcsj.60.37
  16. Kurosaki, A.; Okuyama, T.; Okazaki, S. Bull. Chem. Soc. Jpn. 1987,60, 3541. https://doi.org/10.1246/bcsj.60.3541
  17. Nowak, I.; Ziolek, M. Chem. Rev. 1999, 99, 3603. https://doi.org/10.1021/cr9800208
  18. Montassier, C.; Menezo, J. C.; Naja, J.; Granger, P.; Barbier, J.;Sarrazin, P.; Didillon, B. J. Mol. Catal. A: Chem. 1994, 91, 119. https://doi.org/10.1016/0304-5102(94)00022-0
  19. Kurszewska, M.; Skorupowa, E.; Madaj, J.; Konitz, A.; Wojnowski,W.; Wiśniewski, A. Carbohydr. Res. 2002, 337, 1261. https://doi.org/10.1016/S0008-6215(02)00129-5
  20. West, R. M.; Tucker, M. H.; Braden, D. J.; Dumesic, J. A. Catal.Commun. 2009, 10, 1743. https://doi.org/10.1016/j.catcom.2009.05.021
  21. Jehng, J. M.; Wachs, I. E. Catal. Today 1990, 8, 37. https://doi.org/10.1016/0920-5861(90)87006-O
  22. Burke, P. A.; Ko, E. I. J. Catal. 1991, 129, 38. https://doi.org/10.1016/0021-9517(91)90007-Q
  23. Montassier, C.; Menezo, J. C.; Moukolo, J.; Naja, J.; Hoang, L.C.; Barbier, J.; Boitiaux, J. P. J. Mol. Catal. A: Chem. 1991, 70, 65. https://doi.org/10.1016/0304-5102(91)85006-N

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