Journal of the Korean Magnetic Resonance Society (한국자기공명학회논문지)

Korean Magnetic Resonance Society (한국자기공명학회)
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Application of CRAMPS for a Phase Transition in H+-ion irradiated TlH2PO4

  • Kim, Se-Hun (Faculty of Science Education, Jeju National University) ;
  • Han, J.H. (Department of Physics and Institute for Nano Science, Korea University) ;
  • Lee, Cheol-Eui (Department of Physics and Institute for Nano Science, Korea University) ;
  • Lee, Kwang-Sei (Department of Nano Systems Engineering, Center for Nano Manufacturing, Inje University) ;
  • Kim, Chang-Sam (Advanced Battery Center, Korea Institute of Science and Technology) ;
  • Dalal, N.S. (Department of Chemistry and NHMFL, Florida State University) ;
  • Han, Doug-Young (Analytical Research Group-Seoul Center, Korea Basic Science Institute)
  • Received : 2010.10.29
  • Accepted : 2010.12.09
  • Published : 2010.12.20
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Abstract

We studied the hydrogen-bonded $TlH_2PO_4$ (TDP) ferroelectrics treated with the proton-beam bombardment. The TDP material was irradiated with 1-MeV proton beam at a dose of $10^{15}/cm^2$. In order to analyze the hydrogen environment in TDP, we carried out the $^1H$ high resolution nuclear magnetic resonance (NMR) - i.e., Combined Rotation And Multiple Pulse Spectroscopy (CRAMPS) measurement. The isotropic chemical shift of hydrogen indicates its displacive property is related to the $PO_4$ lattice deformation which occurs throughout the antiferroelectric-, the ferroelastic- and the paraelastic-phase transitions. The temperature dependence of $\sigma_{iso}$ reveals the electronic charge redistribution is induced by the proton-beam irradiation and the elastic property.

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