Macromolecular Research

  • 제17권10호
  • /
  • Pages.725-728
  • /
  • 2009
  • /
  • 1598-5032(pISSN)
  • /
  • 2092-7673(eISSN)
한국고분자학회 (The Polymer Society of Korea)
권호 표지

Synthesis of New Sulfonated Polyimide and Its Photo-Crosslinking for Polymer Electrolyte Membrane Fuel Cells

  • Liu, Hui (Department of Polymer/Nano Science and Technology, Chonbuk National University) ;
  • Lee, Myong-Hoon (Department of Hydrogen and Fuel Cells Engineering, Specialized Graduate School, Chonbuk National University) ;
  • Lee, Jun-Ho (Department of Hydrogen and Fuel Cells Engineering, Specialized Graduate School, Chonbuk National University)
  • 발행 : 2009.10.25
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참고문헌

  1. (a) H. B. Park, C. H. Lee, J. Y. Sohn, Y. M. Lee, B. D. Freeman, and H. J. Kim, J. Membr. Sci., 285, 432 (2006). (b) K. Nakabayashi, K. Matsumoto, Y. Shibasaki, and M. Ueda, Polymer, 48, 5878 (2007). (c) G. Y. Moon and J. W. Rhim, Macromol. Res., 15, 379 (2007). (d) J. Choi, I. T. Kim, S. C. Kim, and Y. T. Hong, Macromol. Res., 13, 514 (2005) https://doi.org/10.1016/j.memsci.2006.09.026
  2. (b) K. Nakabayashi, K. Matsumoto, Y. Shibasaki, and M. Ueda, Polymer, 48, 5878 (2007) https://doi.org/10.1016/j.polymer.2007.08.008
  3. (c) G. Y. Moon and J. W. Rhim, Macromol. Res., 15, 379 (2007) https://doi.org/10.1007/BF03218802
  4. J. Choi, I. T. Kim, S. C. Kim, and Y. T. Hong, Macromol. Res., 13, 514 (2005) https://doi.org/10.1007/BF03218489
  5. N. Miyake, J. S. Wainright, and R. F. Savinell, J. Electrochem. Soc., 148, 898 (2001) https://doi.org/10.1149/1.1383071
  6. Q. Guo, P. N. Pintauro, H. Tang, and S. O'Connor, J. Membr. Sci., 154, 175 (1999) https://doi.org/10.1016/S0376-7388(98)00282-8
  7. (a) M. Walker, K. M. Baumgartner, M. Kaiser, J. Kerres, A. Ullrich, and E. Rauchle, J. Appl. Polym. Sci., 74, 67 (1999). (b) L. Jorissen, V. Gogel, J. Kerres, and J. Garche, J. Power Sources, 105, 267 (2002). (c) J. Kerres, W. Cui, R. Disson, and W. Neubrand, J. Membr. Sci., 139, 211 (1998) https://doi.org/10.1002/(SICI)1097-4628(19991003)74:1<67::AID-APP7>3.0.CO;2-2
  8. (b) L. Jorissen, V. Gogel, J. Kerres, and J. Garche, J. Power Sources, 105, 267 (2002) https://doi.org/10.1016/S0378-7753(01)00952-1
  9. (c) J. Kerres, W. Cui, R. Disson, and W. Neubrand, J. Membr. Sci., 139, 211 (1998) https://doi.org/10.1016/S0376-7388(97)00253-6
  10. J. Kerres, W. Cui, and M. Junginger, J. Membr. Sci., 139, 227 (1998). (b) J. Kerres, W. Zhang, A. Ullrich, C.-M. Tang, M. Hein, V. Gogel, T. Frey, and L. Jorissen, Desalination, 147, 173 (2002). (c) W. Zhang,V. Gogel, K. A. Friedrich, and J. Kerres, J. Power Sources, 155, 3 (2006). (d) S. Mikhailenko, K.Wang, S. Kaliaguine, P. Xing, G. Robertson, and M. Guiver, J. Membr. Sci., 233, 93 (2004). (e) S. Yang, W. Jang, C. Lee, Y. Shul, and H. Han, J. Polym. Sci. Part B: Polym. Phys., 43, 1455 (2005). (f) C. H. Lee, H. B. Park, Y. S. Chung, Y. M. Lee, and B. D. Freeman, Macromolecules, 39, 755 (2006). (g) Y. Yin, S. Hayashi, O. Yamada, H. Kita, and K. Okamoto, Macromol. Rapid Commun., 26, 696 (2005) https://doi.org/10.1016/S0376-7388(97)00254-8
  11. (b) J. Kerres, W. Zhang, A. Ullrich, C.-M. Tang, M. Hein, V. Gogel, T. Frey, and L. Jorissen, Desalination, 147, 173 (2002) https://doi.org/10.1016/S0011-9164(02)00530-1
  12. (c) W. Zhang,V. Gogel, K. A. Friedrich, and J. Kerres, J. Power Sources, 155, 3 (2006) https://doi.org/10.1016/j.jpowsour.2004.12.082
  13. (d) S. Mikhailenko, K.Wang, S. Kaliaguine, P. Xing, G. Robertson, and M. Guiver, J. Membr. Sci., 233, 93 (2004) https://doi.org/10.1016/j.memsci.2004.01.004
  14. (e) S. Yang, W. Jang, C. Lee, Y. Shul, and H. Han, J. Polym. Sci. Part B: Polym. Phys., 43, 1455 (2005) https://doi.org/10.1002/polb.20448
  15. (f) C. H. Lee, H. B. Park, Y. S. Chung, Y. M. Lee, and B. D. Freeman, Macromolecules, 39, 755 (2006) https://doi.org/10.1021/ma052226y
  16. (g) Y. Yin, S. Hayashi, O. Yamada, H. Kita, and K. Okamoto, Macromol. Rapid Commun., 26, 696 (2005) https://doi.org/10.1002/marc.200500014
  17. C. Zhang, X. Guo, J. Fang, H. Xu, M. Yuan, and B. Chen, J. Power Sources, 170, 42 (2007) https://doi.org/10.1016/j.jpowsour.2007.03.065
  18. (a) J. Fang, X. Guo, S. Harada, T. Watari, K. Tanaka, H. Kita, and K. Okamoto, Macromolecules, 35, 9022 (2002). (b) K. Feng, M. Tsushima, T. Matsumoto, and T. Kurosaki, J. Polym. Sci. Part A: Polym. Chem., 36, 685 (1998) https://doi.org/10.1021/ma020005b
  19. (b) K. Feng, M. Tsushima, T. Matsumoto, and T. Kurosaki, J. Polym. Sci. Part A: Polym. Chem., 36, 685 (1998) https://doi.org/10.1002/(SICI)1099-0518(19980415)36:5<685::AID-POLA2>3.0.CO;2-L
  20. Synthesis of SPI: Copolyimide of NTDA/SODA and NTDA/ 3DAC with 0.5:0.5 mol ratio was synthesized and used throughout the experiments. SODA (0.28 mol), TEA (0.67 mol) and 3DAC (0.28 mol) were added successively to 4,500 mL of mcresol in a 3-neck flask with stirring. After SODA and 3DAC were completely dissolved, NTDA (0.56 mol) and benzoic acid (1.12 mol) were added. The mixture was stirred at 80 $^{\circ}C$ for 20 h and 180 $^{\circ}C$ for 24 h under nitrogen atmosphere and then the reaction mixture was precipitated into ethyl acetate. The fibrous precipitate was filtered and dried at 80 $^{\circ}C$ in vacuo. Preparation of SPI membranes: Firstly, uncrosslinked membranes were prepared by pouring the m-cresol solution of 10% SPI onto a glass plate (4 cm × 10 cm) and dried at room temperature for 3 d in air, 60 ${\circ}$ for 24 h and 140 $^{\circ}C$ for 24 h invacuo, respectively. The crosslinked membranes were obtained from SPI solution in m-cresol containing 10 wt% (to SPI) of 1,6-hexanedithiol (HDT) and 5 wt% (to SPI) of IRGACURE 907${\circledR}$ as a crosslinking agent and photo-initiator, respectively, following the above process with subsequent UV light irradiation (198 mW/cm2) for 30 min. The uncrosslinked and crosslinked membranes were acidified by immersing the membranes of TEA salt form into 1.0 M HCl solution at room temperature for 48 h, and then soaked in methanol and deionized water successively to remove excess acid and any impurity
  21. L. V. Natarajan, C. K. Shepherd, D. M. Brandelik, R. L. Sutherland, S. Chandra, V. P. Tondiglia, D. Tomlin, and T. J. Bunning, Chem. Mater., 15, 2477 (2003) https://doi.org/10.1021/cm021824d
  22. S. Zhong, X. Cui, H. Cai, T. Fu, C. Zhao, and H. Na, J. Membr. Sci., 164, 65 (2007)