Food Science and Biotechnology

  • 제18권4호
  • /
  • Pages.895-899
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  • 2009
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  • 1226-7708(pISSN)
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  • 2092-6456(eISSN)
한국식품과학회 (Korean Society of Food Science and Technology)
권호 표지

Determination of Acrylamide in Foods by Solid Phase Microextraction-Gas Chromatography

  • Chen, Liangbi (Department of Chemistry and Environment Engineering, Wuyi University) ;
  • Liu, Haizhu (Key Laboratory of Analysis and Detection Technology for Food Safety (Fuzhou University), Ministry of Education, Department of Chemistry, Fuzhou University ) ;
  • Yu, Ping (Key Laboratory of Analysis and Detection Technology for Food Safety (Fuzhou University), Ministry of Education, Department of Chemistry, Fuzhou University ) ;
  • Zhao, Jinyun (Department of Chemistry and Environment Engineering, Wuyi University) ;
  • Chen, Xi (Key Laboratory of Analysis and Detection Technology for Food Safety (Fuzhou University), Ministry of Education, Department of Chemistry, Fuzhou University)
  • 발행 : 2009.08.31
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초록

A new approach for the determination of acrylamide (AM) in foods by solid phase microextraction-gas chromatography (SPME-GC) was established. AM was bromized and transformed to 2-bromoacrylamide (2-BAM). 2-BAM was then extracted by a commercial SPME fiber, $75-{\mu}m$ Car/PDMS fiber, for GC detection. The influence of extraction and desorption parameters such as extraction temperature and time, stirring rate, desorption temperature, and time were studied and optimized. The mass concentration was proportional to the peak area of 2-BPA from 1.0 to 8,000 ${\mu}g/L$. The detection limit of the SPME-GC for 2-BAM was found to be 0.1 ${\mu}g/L$, and the recoveries and relative standard deviations for different food samples were 74.5 to 102.0%, and 4.2 to 9.1%, respectively. The presented method was applied to the determination of AM in fried foods.

키워드

참고문헌

  1. Zhu YH, Li GR, Duan YP, Chen SQ, Zhang C, Li YF. Application of the standard addition method for the determination of acrylamide in heat-processed starchy foods by gas chromatography with electron capture detector. Food Chem. 100: 899-908 (2008)
  2. Olmez H, Tuncay F, Ozcan N, Demirel S. A survey of acrylamide levels in foods from the Turkish market. J. Food. Compos. Anal. 21: 564-568 (2008) https://doi.org/10.1016/j.jfca.2008.04.011
  3. Paleologos EK, Kontominas MG. Determination of acrylamide and methacrylamide by normal phase high performance liquid chromatography and UV detection. J. Chromatogr. A 1077: 128-135 (2005) https://doi.org/10.1016/j.chroma.2005.04.037
  4. Bermudo E, Moyano E, Puignou L. Liquid chromatography coupled to tandem mass spectrometry for the analysis of acrylamide in typical Spanish products. Talanta 76: 389-394 (2008) https://doi.org/10.1016/j.talanta.2008.03.011
  5. Roach JAG, Andrzejewski D, Gay ML, Nortrup D, Musser SMA. A rugged LC-MS/MS survey analysis for acrylamide in foods. J. Agr. Food Chem. 51: 7547-7554 (2003) https://doi.org/10.1021/jf0346354
  6. Martos PA, Pawliszyn J. Sampling and determination of formaldehyde using solid-phase microextraction with on-fiber derivatization. Anal. Chem. 70: 2311-2320 (1998) https://doi.org/10.1021/ac9711394
  7. Rodil R, Carro AM, Lorenzo RA, Torrijos RC. Selective extraction of trace levels of polychlorinated and polybrominated contaminants by supercritical fluid-solid-phase microextraction and determination by gas chromatography/mass spectrometry. Application to aquaculture fish feed and cultured marine species. Anal. Chem. 77: 2259-2265 (2005) https://doi.org/10.1021/ac048994p
  8. Legind CN, Karlson U, Burken JG, Reichenberg F, Mayer P. Determining chemical activity of (semi) volatile compounds by headspace solid-phase microextraction. Anal. Chem. 79: 2869-2876 (2007) https://doi.org/10.1021/ac061880o
  9. Camarasu C, Madichie C, Williams R. Recent progress in the determination of volatile impurities in pharmaceuticals. Trends Anal. Chem. 25: 768-777 (2006) https://doi.org/10.1016/j.trac.2006.05.013
  10. Brazeau L, Gaudreau M. Ballpoint pen inks: The quantitative analysis of ink solvents on paper by solid-phase microextraction. J. Forensic Sci. 52: 209-215 (2007) https://doi.org/10.1111/j.1556-4029.2006.00299.x
  11. Lee YK, Jung SW, Lee SJ, Lee KG. Analysis of residual furan in human blood using solid phase microextraction-gas chromatography/ mass spectrometry (SPME-GC/MS). Food Sci. Biotechnol. 18: 379-383 (2009)
  12. Lambropoulou DA, Albanis TA. Headspace solid-phase microextraction in combination with gas chromatography-mass spectrometry for the rapid screening of organophosphorus insecticide residues in strawberries and cherries. J. Chromatogr. A 993: 197-203 (2003) https://doi.org/10.1016/S0021-9673(03)00397-2
  13. Marostica MR, Mota NO, Baudet N, Pastore GM. Fungal biotransformation of monoterpenes found in agro-industrial residues from orange and pulp industries into aroma compounds: Screening using solid phase microextraction. Food Sci. Biotechnol. 16: 37-42 (2007)
  14. Poole CF. Determination of acrylamide in nerve tissue homogenates by electron capture gas chromatography. J. Chromatogr. 217: 239-245 (1981) https://doi.org/10.1016/S0021-9673(00)88078-4
  15. Castle L, Campos M, Gilbert J. Determination of acrylamide monomer in hyroponically grown tomato fruit by capillary gaschromatography–massspectrometry. J. Sci. Food Agr. 54: 549-555 (1991) https://doi.org/10.1002/jsfa.2740540406
  16. Jelen HH, Obuchowska M, Zawirska-Wojtasiak R, Wasowicz E, Headspace solid-phase microextraction use for the characterization of volatile compounds in vegetable oils of different sensory quality. J. Agr. Food Chem. 48: 2360-2367 (2000) https://doi.org/10.1021/jf991095v
  17. Lord H, Pawliszyn J. Evolution of solid-phase microextraction technology. J. Chromatogr. A 885: 153-193 (2000) https://doi.org/10.1016/S0021-9673(00)00535-5
  18. Zeng JB, Chen JM, Lin ZQ, Chen WF, Chen X, Wang XR. Development of polymethylphenylsiloxane-coated fiber for solidphase microextraction and its analytical application of qualitative and semi-quantitative of organochlorine and pyrethroid pesticides in vegetables. Anal. Chim. Acta 619: 59-66 (2008) https://doi.org/10.1016/j.aca.2008.02.013
  19. Zeng JB, Yu BB, Chen X. Application of ceramic/carbon composite as a novel coating for solid-phase microextraction. J. Chromatogr. A 1180: 26-33 (2008)
  20. Zhang Y, Donga Y, Renb YP, Zhang Y. Rapid determination of acrylamide contaminant in conventional fried foods by gas chromatography with electron capture detector. J. Chromatogr. A 1116: 209-216 (2006) https://doi.org/10.1016/j.chroma.2006.03.042
  21. Zhu YH, Li GR, Duan YP, Chen SQ, Zhang C, Li YF. Application of the standard addition method for the determination of acrylamide in heat-processed starchy foods by gas chromatography with electron capture detector. Food Chem. 109: 899-908 (2008) https://doi.org/10.1016/j.foodchem.2008.01.020
  22. Mottram DS, Wedzicha BL, Dodson AT. Acrylamide is formed in the Maillard reaction. Nat. 419: 448-449 (2002) https://doi.org/10.1038/419448a
  23. Stadler RH, Blank I, Varga N, Robert F, Hau J, Guy PA, Robert MC, Riediker S. Acrylamide from Maillard reaction products. Nature 419: 449-450 (2002) https://doi.org/10.1038/419449a