Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
권호 표지

Dye-resist Properties of Poly(MAn-co-VAc) in Reactive Dyeing of Cotton

Poly(MAn-co-VAc)를 이용한 면섬유의 반응성 염색에 대한 방염효과

  • Yoon, Kee-Jong (Department of Fiber System Engineering, College of Engineering, Dankook University) ;
  • Kim, Kyu-Oh (Department of Fiber System Engineering, College of Engineering, Dankook University) ;
  • Seo, Young-Sam (Department of Fiber System Engineering, College of Engineering, Dankook University)
  • 윤기종 (단국대학교 공과대학 파이버시스템공학과) ;
  • 김규오 (단국대학교 공과대학 파이버시스템공학과) ;
  • 서영삼 (단국대학교 공과대학 파이버시스템공학과)
  • Published : 2009.06.30
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Abstract

Poly(maleic anhydride-co-vinyl acetate) copolymers were prepared by copolymerization in toluene, using AIBN as initiator. Cotton knit fabric was treated with poly(MAn-co-VAc) and the changes in the dye resist property with molecular weight, concentration and curing time was studied. The dye resist ability was evaluated by colorimetric analysis. Higher molecular weight copolymers were more efficient in blocking the dye. This appears to be due to the preferential reaction of the copolymer on the surface of cotton fabric, where the longer chains are more efficient in blocking the penetration of the dye into the fiber, due to the hydrophobic nature of the vinyl acetate comonomer. The blocking effect increased with concentration of the blocking agent padding bath, but yellowing occurred at concentrations above 30 wt%. Although dye resist effect was best when curing time of poly(MAn-co-VAc) was 2 min 30 see, the cotton fabric turned yellowish. Therefore, curing time should be less than 2 min 15 sec in order to avoid yellowing effect and obtain good dye resist property.

Keywords

References

  1. C. Q. Yang and X. Wang, 'Infrared Spectroscopy Studies of the Cyclic Anhydride as the Intermediate for the Ester Crosslinking of Cotton Cellulose by Polycarboxylic Acids. III. Molecular Weight of a Crosslinking Agent', J Polym Sci:Part A: Polym Chem, 1997, 35, 557-564 https://doi.org/10.1002/(SICI)1099-0518(199702)35:3<557::AID-POLA21>3.0.CO;2-M
  2. C. Q. Yang and X. Wang, and Y. Lu, 'Infrared Spectroscopy Studies of Cyclic Anhydrides as Intermediates for Ester Crosslinking of Cotton Cellulose by Polycarboxylic Acids. IV. In Situ Free Radical Copolymerization of Maleic Acid and Itaconic Acid on Cotton', J Appl Polym Sci, 2000, 75, 327-336 https://doi.org/10.1002/(SICI)1097-4628(20000110)75:2<327::AID-APP15>3.0.CO;2-F
  3. Q. Yang and X. Wang, 'Formation of Five-membered Cyclic Anhydride Intermediates by Polycarboxylic Acids: Thermal Analysis and Fourier Transform Infrared Spectroscopy', J Appl Polym Sci, 1998, 70, 2711-2718 https://doi.org/10.1002/(SICI)1097-4628(19981226)70:13<2711::AID-APP16>3.0.CO;2-Z
  4. D. M. Lewis and B. Voncina, 'Durable Press Finishing of Cotton with Polycarboxylic Acids. I. Preparation of Thiosuccinyl-s-triazine', J Appl Polym Sci, 1997, 66, 1465- 1474 https://doi.org/10.1002/(SICI)1097-4628(19971121)66:8<1465::AID-APP7>3.0.CO;2-C
  5. Q. Yang and X. Wang, 'Infrared Spectroscopy Studies of the Cylic Anhydride as the Intermediate for the Ester Crosslinking of Cotton Cellulose by Polycarboxylic Acids. II. Comparison of Different Poly Caboxylic Acids', J Polym Sci, Part A, Polym Chem, 1996, 34, 1573-1580 https://doi.org/10.1002/(SICI)1099-0518(199606)34:8<1573::AID-POLA22>3.0.CO;2-4
  6. C. Walling, E. Briggs, K. Wolfstirn, and F. R. Mayo, 'Copolymerization. X. The Effect of Meta- and Parasubstitution on the Reactivity of the Styrene Double Bond', J Am Chem Soc, 1948, 70, 1537-1544 https://doi.org/10.1021/ja01184a072
  7. R. J. Samuels, 'A Quantitative Evaluation of the Structure and Properties of the Methyl Ester of Divinyl Ether - Maleic Anhydride 1:2 Copolymer', Polymer, 1977, 18, 452-460 https://doi.org/10.1016/0032-3861(77)90161-6
  8. J. M. G. Cowie, Ed., 'Altemating Copolymers', Plenum Press, New York, 1985
  9. I. L. Stoyachenko, G. S. Georgiev, V. B. Golubev, V. P. Zubov, and V. A. Kabanov, 'Study of the Mechanism of 'Altemating' Copolymerization of Maleic Anhydride with Dimethylbutadiene', Polym Sci, USSR, 1973, 15, 2142- 2149 https://doi.org/10.1016/0032-3950(73)90432-2
  10. C. Caze and C. Loucheux, 'Mechanism of Altemating Copolymerization of Vinyl Acetate and Maleic Anhydride', J Marcromol Sci Chem, 1975, A9, 29-43
  11. R. Amaud, C. Caze, and J. Fossey, ' Studies of Radical Altemating Copolymerization. I. Quantitative Determination of the Relative Reactivities between Free Comonomers and a Complex between Them: A Theoretical Treatrnent in TeffilS of Frontier Molecular Orbital Interactions. Application to Radical Maleic Anhydride-Vinyl Acetate Altemating Copolymerization', J Macromol Sci Chem, 1980, A14, 1269-1284
  12. N. Fujimori and A. S. Brown, ' Overall Rate of Alternating Copolymerization of Vinyl Acetate with Maleic Anhydride in Methyl Ethyl', Polym Bull, 1986, 15, 223-226 https://doi.org/10.1007/BF00255066
  13. K. J. Yoon, J. H. Woo, and Y. S. Seo, 'Formaldehyde Free Cross-linking Agents Based on Maleic Anhydride Copolymers', Fiber Polym, 2003, 4, 182-187 https://doi.org/10.1007/BF02908276
  14. H. S. Park, M. H. Kee, and Y. H. Kim, ' Causes of Yellowing in Cotton/Spandex Knit Fabrics', J Korean Fiber Soc, 1999, 36, 565-571