Quantitative Evaluation of Scratch Behavior for Polymeric Materials

고분자 소재의 스크래치 거동의 정량적 평가

  • Baek, Ki-Wan (Chemical Materials Information Bank, Research Institute of Chemical Technology) ;
  • Lee, Sung-Goo (Chemical Materials Information Bank, Research Institute of Chemical Technology) ;
  • Lee, Jae-Heung (Chemical Materials Information Bank, Research Institute of Chemical Technology) ;
  • Choi, Kil-Yeong (Reliability Assessment Center of Chemical Materials, Research Institute of Chemical Technology) ;
  • Weon, Jong-Il (Reliability Assessment Center of Chemical Materials, Research Institute of Chemical Technology)
  • 백기완 (한국화학연구원 화학소재정보은행) ;
  • 이성구 (한국화학연구원 화학소재정보은행) ;
  • 이재홍 (한국화학연구원 화학소재정보은행) ;
  • 최길영 (한국화학연구원 신뢰성평가센터) ;
  • 원종일 (한국화학연구원 신뢰성평가센터)
  • Published : 2009.07.25

Abstract

Recent research issues on the scratch behaviors of polymeric materials has been investigated. In this study, the scratch characterization of polymeric materials with respect of experimental parameters, such as nature of the material, temperature, applied load, test speed, surface treatment, scratch number of times, polymer structure/functional groups, degree of cross-linking, and crystallinity, are reviewed. In addition, the testing standards and methodologies which could quantify the scratch behaviors are introduced and the current international standards are compared and summarized. The latest technical approaches for evaluating the scratch behaviors and improving the scratch resistance of polymers are also discussed.

고분자소재의 표면 특성 중의 하나인 스크래치 거동에 관한 최근의 연구 결과와 현황을 광범위하게 고찰하였다. 본 고찰에서는 고분자 소재의 스크래치 특성에 영향을 주는 실험인자들, 즉 소재재질, 온도, 작용하중, 실험속도, 표면처리, 스크래치 횟수, 고분자 구조 및 관능기, 가교정도 그리고 결정화도에 따른 스크래치 특성을 조사하였다. 또한, 고분자 소재의 스크래치 특성을 정량적으로 평가할 수 있는 접근 방법을 소개하였고, 현존하는 관련 국제시험법을 비교 조사하였다. 고분자 소재의 스크래치 거동을 정확히 평가할 수 있는 방법과 내스크래치성을 향상시킬 수 있는 방법에 관한 최근의 기술적 접근 방법에 대해 토의하였다.

Keywords

References

  1. S. J. Park, S. H. Im, J. R. Lee, and J. M. Rhee, Polymer (Korea), 30, 385 (2006)
  2. U. Biskup and T. Engbert, in Proceedings of the 4th Nurnberg Congress, 57, 7 (2007)
  3. U. Schulz, V. Wachtendorf, T. Klimmasch, and P. Alers, Progress in Organic Coatings, 42, 38 (2001) https://doi.org/10.1016/S0300-9440(01)00148-5
  4. P. Betz and A. Bartelt, Prog. Org. Coat., 22, 27 (1993) https://doi.org/10.1016/0033-0655(93)80013-Z
  5. J. L. Courter and E. A. Kamenetzky, Eur. Coat. J., 7, 24 (1999)
  6. K. Adamsons, G. Blackman, B. Gregorovich, L. Lin, and R. Matheson, Prog. Org. Coat., 34, 64 (1998) https://doi.org/10.1016/S0300-9440(98)00022-8
  7. R. A. Ryntz, B. D. Abell, G. M. Pollano, L. H. Nguyen, and W. C. Shen, J. Coating Technol., 72, 47 (2000) https://doi.org/10.1007/BF02698019
  8. ASTM D6279 (2005)
  9. ASTM D2486 (2003)
  10. M. J. Chen, F. D. Osterholtz, E. R. Pohl, P. E. Ramdatt, A. Chaves, and V. Bennett, J. Coating Technol., 69, 43 (1997)
  11. C. Xiang, H.-J. Sue, J. Chu, and B. Coleman, J. Polym. Sci. Part B: Polym. Phys., 39, 47 (2001) https://doi.org/10.1002/1099-0488(20010101)39:1<47::AID-POLB50>3.0.CO;2-2
  12. M. Wong, G. T. Lim, A. Moyse, J. N. Reddy, and H.-J. Sue, Wear, 256, 1214 (2004) https://doi.org/10.1016/j.wear.2003.10.027
  13. H.-J. Sue, H. Jiang, G. T. Lim, J. N. Reddy, and J. D. Whitcomb, J. Polym. Sci.: Part B: Polym. Phys., 45, 1435 (2007) https://doi.org/10.1002/polb.21169
  14. ASTM G171 (2003)
  15. ASTM C1624 (2005)
  16. ASTM D7027 (2005)
  17. R. L. Browning, G. T. Lim, A. Moyse, L. Sun, and H.-J. Sue, Polym. Eng. Sci., 46, 601 (2006) https://doi.org/10.1002/pen.20507
  18. ISO/FDIS 19252 (2007)
  19. K. Maeda, A. Bismarck, and B. J. Briscoe, Wear, 259, 651 (2005) https://doi.org/10.1016/j.wear.2005.02.046
  20. L. Robert, Browning, H. Jiang, A. Moyse, H.-J. Sue, Y. Iseki, K. Ohtani, and Y. Ijichi, J. Mater. Sci., 43, 1357 (2008) https://doi.org/10.1007/s10853-007-2283-5
  21. V. Jardret and P. Morel, Prog. Org. Coat., 48, 322 (2003) https://doi.org/10.1016/j.porgcoat.2003.02.002
  22. E. Moghbelli, R. L. Broening, W. J. Boo, S. F. Hahn, L. J. E. Feick, and H.-J. Hue, Tribol. Int., 41, 425 (2008) https://doi.org/10.1016/j.triboint.2007.09.008
  23. S. K. Sinha and B. J. Lim, Wear, 260, 751 (2006) https://doi.org/10.1016/j.wear.2005.04.018
  24. T. Koch and D. Machl, Polym. Test., 26, 927 (2007) https://doi.org/10.1016/j.polymertesting.2007.06.006
  25. R. Bagheri, S. Zokaei, R. Lesan, and M. Khosh, Mater. Sci. Eng. A, 445, 526 (2007) https://doi.org/10.1016/j.msea.2006.09.080
  26. H. Jiang, R. Browning, J. Fincher, and A. Gasbarro, Appl. Surf. Sci., 254, 4494 (2008) https://doi.org/10.1016/j.apsusc.2008.01.067
  27. S. K. Sinha, W. L. M. Chong, and S. C. Lim, Wear, 262, 1038 (2007) https://doi.org/10.1016/j.wear.2006.10.017
  28. J. J. Rajesh and J. Bijwe, Wear, 259, 661 (2005) https://doi.org/10.1016/j.wear.2004.12.018
  29. J. Lin, J. Zhu, D. R. Swanson, and L. Milco, Langmuir, 12, 6676 (1996) https://doi.org/10.1021/la960563h
  30. C. Xiang and H. -J. Sue, Polym. Eng. Sci., 41, 23 (2001) https://doi.org/10.1002/pen.10705
  31. K. S. K. Karuppiah, A. L. Bruck, S. Sundararajan, J. Wang, Z. Lin, Z. H. Xu, and X. Li, Acta Biomaterialia, 4, 1401 (2008) https://doi.org/10.1016/j.actbio.2008.02.022
  32. M. D. Bermu´dez, W. Brostow, F. J. Carrio´n-Vilches, J. J. Cervantes, and D. Pietkiewicz, Polymer, 46, 347 (2005) https://doi.org/10.1016/j.polymer.2004.11.003
  33. E. Felder and J. L. Bucaille, Tribol. Int., 39, 70 (2006) https://doi.org/10.1016/j.triboint.2005.04.005
  34. H. Pelletier, C. Mendibide, and A. Riche, Prog. Org. Coat., 62, 162 (2008) https://doi.org/10.1016/j.porgcoat.2007.10.009
  35. L. Lin, G. S. Blackman, and R. R. Matheson, Mat. Sci. Eng. A, 317, 163 (2001) https://doi.org/10.1016/S0921-5093(01)01159-5
  36. H. Pelletier, C. Gauthier, and R. Schirrer, J. Engineering Tribology, 222, 221 (2008) https://doi.org/10.1243/13506501JET334
  37. J. S. S. Wong, H.-J. Sue, K. Y. Zeng, R. K. Y. Li, and Y. W. Mai, Acta Materialia, 52, 431 (2004) https://doi.org/10.1016/j.actamat.2003.09.028
  38. R. L. Browning, G. T. Lim, A. Moyse, H.-J. Sue, H. Chen, and J. D. Earls, Surf. Coat. Tech., 201, 2970 (2006) https://doi.org/10.1016/j.surfcoat.2006.06.007